Environmental Science & Technology Research Works

Permanent URI for this collectionhttp://hdl.handle.net/1903/1601

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    Methane and Hydrogen Sulfide Production from Co-Digestion of Gummy Waste with a Food Waste, Grease Waste, and Dairy Manure Mixture
    (MDPI, 2019-11-23) Lansing, Stephanie; Choudhury, Abhinav
    Co-digestion of dairy manure with waste organic substrates has been shown to increase the methane (CH4) yield of farm-scale anaerobic digestion (AD). A gummy vitamin waste (GVW) product was evaluated as an AD co-digestion substrate using batch AD testing. The GVW product was added at four inclusion levels (0%, 5%, 9%, and 23% on a wet mass basis) to a co-digestion substrate mixture of dairy manure (DM), food-waste (FW), and grease-waste (GW) and compared to mono-digestion of the GVW, DM, FW, and GW substrates. All GVW co-digestion treatments significantly increased CH4 yield by 126–151% (336–374 mL CH4/g volatile solids (VS)) compared to DM-only treatment (149 mL CH4/g VS). The GVW co-digestion treatments also significantly decreased the hydrogen sulfide (H2S) content in the biogas by 66–83% (35.1–71.9 mL H2S/kg VS) compared to DM-only (212 mL H2S/kg VS) due to the low sulfur (S) content in GVW waste. The study showed that GVW is a potentially valuable co-digestion substrate for dairy manure. The high density of VS and low moisture and S content of GVW resulted in higher CH4 yields and lower H2S concentrations, which could be economically beneficial for dairy farmers.
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    Evaluation of Hydrogen Sulfide Scrubbing Systems for Anaerobic Digesters on Two U.S. Dairy Farms
    (MDPI, 2019-12-04) Choudhury, Abhinav; Shelford, Timothy; Felton, Gary; Gooch, Curt; Lansing, Stephanie
    Hydrogen sulfide (H2S) is a corrosive trace gas present in biogas produced from anaerobic digestion systems that should be removed to reduce engine-generator set maintenance costs. This study was conducted to provide a more complete understanding of two H2S scrubbers in terms of efficiency, operational and maintenance parameters, capital and operational costs, and the effect of scrubber management on sustained H2S reduction potential. For this work, biogas H2S, CO2, O2, and CH4 concentrations were quantified for two existing H2S scrubbing systems (iron-oxide scrubber, and biological oxidation using air injection) located on two rural dairy farms. In the micro-aerated digester, the variability in biogas H2S concentration (average: 1938 ± 65 ppm) correlated with the O2 concentration (average: 0.030 ± 0.004%). For the iron-oxide scrubber, there was no significant difference in the H2S concentrations in the pre-scrubbed (450 ± 42 ppm) and post-scrubbed (430 ± 41 ppm) biogas due to the use of scrap iron and steel wool instead of proprietary iron oxide-based adsorbents often used for biogas desulfurization. Even though the capital and operating costs for the two scrubbing systems were low (<$1500/year), the lack of dedicated operators led to inefficient performance for the two scrubbing systems.