Institute for Systems Research
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Item A Comparative Study of Reactor Designs for the Production of Graded Films with Applications to Combinatorial CVD(2007) Sreenivasan, Ramaswamy; Adomaitis, Raymond A.; Rubloff, Gary W.; ISRSegmented CVD reactor designs enabling spatial control of across-wafer gas phase composition were evaluated for depositing graded films suitable for combinatorial studies. Specifically two reactor designs were constructed and evaluated with experiments and response surface model (RSM) based analysis to quantify the reactor performance in terms of film thickness uniformity, sensitivity to adjustable reactor operating conditions, range of thickness over which uniformity could be achieved and each reactor ability to control the thickness gradient across the wafer surface. Design features distinguishing the two reactor systems and their influence on gradient control versus deposition rate performance are summarized. RS models relating wafer state properties to process recipes are shown to be effective tools to quantify, qualify and compare different reactor designs.Item A NEW APPROACH TO SPATIALLY CONTROLLABLE CVD(2004) Choo, Jae-Ouk; Adomaitis, Raymond A.; Rubloff, Gary W.; Henn-Lecordier, Laurent; Cai, Yuhong; Adomaitis, Raymond A.; ISRThis paper describes the continuing design evolution of a new approach to spatially controllable chemical vapor deposition for electronic materials manufacturing. Based on the success of a previous prototype reactor, we describe construction of a newer version of the prototype reactor system to assess its performance and identify its key operational characteristics. This new design includes a fully automated feed gas control system, allowing the reprogramming of reactor operation without hardware modifications and a time-shared gas sampling mass spectrometer for spatially resolved across-wafer gas composition analysis.Item Simulator Development for a Spatially Controllable Chemical Vapor Deposition System(2002) Choo, Jae-Ouk; Adomaitis, Raymond A.; Rubloff, Gary W.; Henn-Lecordier, Laurent; Liu, Yijun; ISRMost conventional chemical vapor deposition systems do not have the spatial actuation and sensing capabilities necessary to control deposition uniformity, or to intentionally induce nonuniform deposition patterns for single-wafer combinatorial CVD experiments. In an effort to address this limitation, we began a research program at the University of Maryland focusing on the development of a novel CVD reactor system that can explicitly control the (2-dimensional) spatial profile of gas-phase chemical composition across the wafer surface.This reactor is based on a novel segmented showerhead design in which gas precursor composition can be individually controlled in the gas fed to each segment. Because the exhaust gas is recirculated up through the showerhead though the individual segments, the gas flow pattern created eliminates convective mass transfer between the segment regions. The effect of this design is a CVD system in which across-wafer composition gradients can be accurately predicted and controlled.
This paper discusses the development of a simulator for a three-segment prototype that has recently been constructed as a modification to an Ulvac ERA1000 CVD cluster tool. A preliminary set of experiments has been performed to evaluate the performance of the prototype in depositing tungsten films for a range of wafer/showerhead spacing and segment gas compositions. We discuss the simulation approach taken to developing the simulator for this system focusing on a one-dimensional simulation of transport through the segments and exhaust mixing region, a model valid in the limit of close showerhead/wafer spacing. The use of simulation in the prototype system design, interpreting experimental data, and its ultimate use in controlling the CVD process to achieve true programmable CVD operation all will be discussed. Further information can be found at the project website, http://www.isr.umd.edu/Labs/CACSE/research/progrxr
Item Real-Time Growth Rate Metrology for a Tungsten CVD Process by Acoustic Sensing(2000) Henn-Lecordier, Laurent; Kidder, John N., Jr.; Rubloff, Gary W.; Gogol, C. A.; Wajid, A.; ISRAn acoustic sensor, the Leybold Inficon ComposerTM, was implemented downstream to a production-scale tungsten chemical vapor deposition (CVD) cluster tool for in-situ process sensing. Process gases were sampled at the outlet of the reactor chamber and compressed with a turbo-molecular pump and mechanical pump from the sub-Torr process pressure regime to above 50 Torr as required for gas sound velocity measurements in the acoustic cavity. The high molecular weight gas WF6 mixed with H2 provides a substantial molecular weight contrast so that the acoustic sensing method appears especially sensitive to WF6 concentration.By monitoring the resonant frequency of exhaust process gases, the depletion of WF6 resulting from the reduction by H2 was readily observed in the 0.5 Torr process for wafer temperatures ranging from 300 to 350 C. Despite WF6 depletion rates as low as 3-5%, in-situ wafer-state metrology was achieved with an error less than 6% over 17 processed wafers.
This in-situ metrology capability combined with accurate sensor response modeling suggests an effective approach for acoustic process sensing in order to achieve run-to-run process control of the deposited tungsten film thickness.
Item Influence of Gas Composition on Wafer Temperature Control in a Tungsten Chemical Vapor Deposition Reactor(2000) Chang, Hsiao-Yung; Adomaitis, Raymond A.; Kidder, John N., Jr.; Rubloff, Gary W.; ISRExperimental measurements of wafer temperature in a single-wafer,lamp-heated CVD system were used to study the wafer temperature responseto gas composition. A physically based simulation procedure for theprocess gas and wafer temperature was developed in which a subset ofparameter values were estimated using a nonlinear, iterative parameteridentification method, producing a validated model with true predictivecapabilities.With process heating lamp power held constant, wafertemperature variations of up to 160 degrees K were observed by varying feed gasH_2/N_2 ratio. Heat transfer between the wafer and susceptor wasstudied by shifting the instrumented wafer off the susceptor axis,exposing a portion of the wafer backside to the chamber floor. Modelpredictions and experimental observations both demonstrated that the gasvelocity field had little influence on the observed wafer and predictedgas temperatures.
Item Evaluating the Impact of Process Changes on Cluster Tool Performance(1999) Herrmann, Jeffrey W.; Chandrasekaran, Niranjan; Conaghan, Brian F.; Nguyen, Manh-Quan; Rubloff, Gary W.; Shi, Rock Z.; ISRCluster tools are highly integrated machines that can perform a sequence of semiconductor manufacturing processes. Their integrated nature can complicate analysis when evaluating how process changes affect the overall tool performance.This paper presents two integrated models for understanding cluster tool behavior. The first model is a network model that evaluates the total lot processing time for a given sequence of activities. By including a manufacturing process model (in the form of a response surface model, or RSM), the model calculates the total lot processing time as a function of the process parameter values and other operation times. This model allows one to quantify the sensitivity of total lot processing time with respect to process parameters and times.
In addition, we present an integrated simulation model that includes a process model. For a given scheduling rule that the cluster tool uses to sequence wafer movements, one can use the simulation to evaluate the impact of process changes including changes to product characteristics and changes to process parameter values. In addition, one can construct an integrated network model to quantify the sensitivity of total lot processing time with respect to process times and process parameters in a specific scenario.
The examples presented here illustrate the types of insights that one can gain from using such methods. Namely, the total lot processing time is a function not simply of each operation's process time, but specifically of the chosen process parameter values. Modifying the process parameter values may have significant impacts on the manufacturing system performance, a consequence of importance which is not readily obvious to a process engineer when tuning a process (though in some cases, reducing process times may not change the total lot processing time much).
Additionally, since the cluster tool's maximum throughput depends upon the process parameters, the tradeoffs between process performance and throughput should be considered when evaluating potential process changes and their manufacturing impact.
Item Integrated Dynamic Simulation of Rapid Thermal Chemical Vapor Deposition of Polysilicon(1997) Lu, Guangquan; Bora, Monalisa; Tedder, Laura L.; Rubloff, Gary W.; ISRA physically-based dynamic simulator has been constructed to investigate the time-dependent behavior of equipment process, sensor, and control system for rapid thermal chemical vapor deposition (RTCVD) of polysilicon from SiH4. The simulator captures the essential physics and chemistry of mass transport, heat transfer, and chemical kinetics of the RTCVD process as embodied in equipment. In order to complete the system-level description, reduced-order models are also employed to represent processes involving high complexity of physics. Integration of individual simulator elements for equipment, process, sensors, and control systems enables the evaluation of not only the deposition rate and film thickness, but also of a broad range of dynamic system properties such as equipment performance, gas flow conditions, wafer temperature variation, wafer optical properties (absorptivity/emissivity), gas composition in reactor, total process cycle time, consumables volume, and reactant utilization. This makes the simulator directly applicable to the optimization of process recipe and equipment design, to process control strategy, and to fault classification. This case study of polysilicon RTCVD demonstrates (1) that integrated dynamic simulation is a versatile tool for representing system-level dynamics, and (2) that such representation is pivotal in successful application of modeling and simulation for manufacturing optimization and control.Item Education in Semiconductor Manufacturing Processes through Physically-Based Dynamic Simulation(1997) Lu, G. Brian; Oveissi, Mansour; Eckard, David; Rubloff, Gary W.; ISRWe have developed physically-based dynamic simulators relevant to semiconductor manufacturing processes, which realistically reflect the time-dependent behavior of equipment, process, sensor, and control systems using commercial simulation software (VixSimTm) under Windows. Following on their successful research use for engineering design, we are applying them to manufacturing education and training. Because they reflect quantitatively and visually the detailed response of the system to user-initiated actions in real time, these simulators promise a new paradigm of active learning through ﲨands-on operation of sophisticated, expensive processing equipment. The student experience is open- ended, offering not only guided exercises but also the chance to experiment freely with the virtual equipment. Simulator modules are in development for use by both experienced engineers and manufacturing operators, with enhanced graphical interfaces tailored to the student and application.Item Polysilicon RTCVD Process Optimization for Environmentally- Conscious Manufacturing(1996) Lu, Guangquan; Bora, Monalisa; Rubloff, Gary W.; ISRIn the semiconductor manufacturing industry, optimization of advanced equipment and process designs must include both manufacturing metrics (such as cycle time, consumables cost, and product quality) and environmental consequences (such as reactant utilization and by-product emission). We have investigated the optimization of rapid thermal chemical vapor deposition (RTCVD) of polysilicon from SiH4 as a function of process parameters using a physically-based dynamic simulation approach. The simulator captures essential time-dependent behaviors of gas flow, heat transfer, reaction chemistry, and sensor and control systems, and is validated by our experimental data. Significant improvements in SiH4 utilization (up to 7 x) and process cycle time (up to 3 x) can be achieved by changes in (i) timing for initiating wafer heating relative to starting process gas flow; (ii) process temperature (650 - 750oC ) ; and (iii) gas flow rate (100 - 1000 sccm). Enhanced gas utilization efficiency and reduced process cycle time provide benefits for both environmental considerations and manufacturing productivity (throughput). Dynamic simulation proves to be a versatile and powerful technique for identifying optimal process parameters and for assessing tradeoffs between various manufacturing and environmental metrics.Item Contamination Control for Gas Delivery from a Liquid Source in Semiconductor Manufacturing(1996) Lu, Guangquan; Rubloff, Gary W.; Durham, Jim; ISRGas delivery from a liquid source, common in semiconductor manufacturing, raises contamination control concerns not only due to impurity levels in the source. In addition, the lower vapor pressure of impurity species compared to that of the host (source) species causes impurity concentrations in delivered gas to increase as the source is used up. A physics-based dynamic simulator to describe the time-dependent variation of impurity level in such a gas delivery system has been developed and applied to important case of CHCIF2 impurities in host CHF3 liquid, as routinely used for dry etching processes. For a cylinder of CHF3 liquid with 100 ppm of CHCIF2 at 21.1o C (70o F), the concentration of CHCIF2 in the delivered gas is initially ~ 21 ppm, and rises slowly to ~ 100 ppm with ~ 25% of the initial material remaining. With further usage, the CHCIF2 level increases quickly to ~ 350 ppm when ~ 15% of the initial source material is left; at this point, the source has reached the liquid-dry point, i.e., all the remaining source material is gaseous, and the impurity concentration in delivered gas remains constant at 350 ppm until all material is gone. The time- dependence of CHCIF2 impurity concentration is also dependent on the operating temperature of the liquid source: for higher temperatures, the fast rise in impurity concentration and the liquid-dry point occur earlier, while the final impurity level after this point is lower. The dynamic simulator represents a useful tool for avoiding contamination problems with liquid delivery systems and for optimizing materials usage (for cost and environmental benefits) by structuring source usage procedures consistent with contamination-sensitivity of the process. The results also suggest benefits in materials usage if specific source temperatures (different from room temperature) were imposed. The physical basis of the dynamic simulator allows more general application to other systems.