Atmospheric & Oceanic Science

Permanent URI for this communityhttp://hdl.handle.net/1903/2264

Formerly known as the Department of Meteorology.

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A 20-YEAR CLIMATOLOGY OF GLOBAL ATMOSPHERIC METHANE FROM HYPERSPECTRAL THERMAL INFRARED SOUNDERS WITH SOME APPLICATIONS
(2022) Zhou, Lihang; Warner, Juying; Atmospheric and Oceanic Sciences; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)
Atmospheric Methane (CH4) is the second most important greenhouse gas after carbon dioxide (CO2), and accounts for approximately 20% of the global warming produced by all well-mixed greenhouse gases. Thus, its spatiotemporal distributions and relevant long-term trends are critical to understanding the sources, sinks, and global budget of atmospheric composition, as well as the associated climate impacts. The current suite of hyperspectral thermal infrared sounders has provided continuous global methane data records since 2002, starting with the Atmospheric Infrared Sounder (AIRS) onboard the NASA EOS/Aqua satellite launched on 2 May 2002. The Cross-track Infrared Sounder (CrIS) was launched onboard the Suomi National Polar Orbiting Partnership (SNPP) on 28 October 2011 and then on NOAA-20 on 18 November 2017. The Infrared Atmospheric Sounding Interferometer (IASI) was launched onboard the EUMETSAT MetOp-A on 19 October 2006, followed by MetOp-B on 17 September 2012, then Metop-C on 7 November 2018. In this study, nearly two decades of global CH4 concentrations retrieved from the AIRS and CrIS sensors were analyzed. Results indicate that the global mid-upper tropospheric CH4 concentrations (centered around 400 hPa) increased significantly from 2003 to 2020, i.e., with an annual average of ~1754 ppbv in 2003 and ~1839 ppbv in 2020. The total increase is approximately 85 ppbv representing a +4.8% change in 18 years. More importantly, the rate of increase was derived using satellite measurements and shown to be consistent with the rate of increase previously reported only from in-situ observational measurements. It further confirmed that there was a steady increase starting in 2007 that became stronger since 2014, as also reported from the in-situ observations. In addition, comparisons of the methane retrieved from the AIRS and CrIS against in situ measurements from NOAA Global Monitoring Laboratory (GML) were conducted. One of the key findings of this comparative study is that there are phase shifts in the seasonal cycles between satellite thermal infrared measurements and ground measurements, especially in the middle to high latitudes in the northern hemisphere. Through this, an issue common in the hyperspectral thermal sensor retrievals were discovered that was unknown previously and offered potential solutions. We also conducted research on some applications of the retrieval products in monitoring the changes of CH4 over the selected regions (the Arctic and South America). Detailed analyses based on local geographic changes related to CH4 concentration increases were discussed. The results of this study concluded that while the atmospheric CH4 concentration over the Arctic region has been increasing since the early 2000s, there were no catastrophic sudden jumps during the period of 2008-2012, as indicated by the earlier studies using pre-validated retrieval products. From our study of CH4 climatology using hyperspectral infrared sounders, it has been proved that the CH4 from hyperspectral sounders provide valuable information on CH4 for the mid-upper troposphere and lower stratosphere. Future approaches are suggested that include: 1) Utilizing extended data records for CH4 monitoring using AIRS, CrIS, and other potential new generation hyperspectral infrared sensors; 2). Improving the algorithms for trace gas retrievals; and 3). Enhancing the capacity to detect CH4 changes and anomalies with radiance signals from hyperspectral infrared sounders.
Improving Forecasts of Volcanic Clouds: An Analysis of Observations and Emission Source Term Methods
(2018) Hughes, Eric; Dickerson, Russell R; Krotkov, Nickolay A; Atmospheric and Oceanic Sciences; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)
Volcanic eruptions can occur with little or no warning and explosively inject dense ash and sulfur dioxide (SO2) clouds high into the atmosphere. I investigated different types of observations and analysis methods used to monitor and quantify volcanic ash and SO2 clouds. I begin with an analysis of the 2010 eruption of Eyjafjallajökull, employing ash cloud transport modeling capabilities I developed for the Goddard Earth Observing System, Version 5 (GEOS-5). The emission source terms describing the initial state of the Eyjafjallajökull ash clouds were estimated using radar observations of the ash cloud’s initial injection altitude. Results of the initial simulations agreed with operational ash forecasts from the time of the eruption and with many other published studies, but showed notable disagreement with satellite observations. The emission source term was estimated using an alternative approach, yielding simulations that better matched satellite observations. I used the result to highlight limitations of radar observations not accounted for in previous studies of the Eyjafjallajökull ash clouds. UV satellite observations are often used to monitor and quantify volcanic clouds of ash and SO2. I tested the limitations of the OMPS SO2 satellite observations using an Observing System Simulation Experiment (OSSE). The framework used GEOS-5 simulations of the atmospheric composition in the wake of a Pinatubo-like volcanic eruption to generate synthetic top-of-the-atmosphere (TOA) radiances. The TOA radiances served as input to the OMPS SO2 retrieval. In comparing the OMPS retrieval SO2 to the original GEOS-5 SO2, I found that the sulfate aerosols and ash can cause the OMPS SO2 retrieval to underestimate the total SO2 burden. These effects were amplified at increased satellite viewing angles. I finish my analysis by looking at observations from the satellite-based Cloud-Aerosol Transport System (CATS), where I show that even under the time constraints of an operational forecast, the available CATS observations were able to improve forecasts of volcanic SO2 clouds.
Identification and Quantification of Regional Aerosol Trends and Impact on Clouds over the North Atlantic Ocean
(2017) Jongeward, Andrew; Li, Zhanqing; Atmospheric and Oceanic Sciences; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)
Aerosols and clouds contribute to atmospheric variability and Earth’s radiative balance across local, regional, and global scales. Originating from both natural and anthropogenic sources, aerosols can cause adverse health effects and can interact directly with solar radiation as well as indirectly through complex interactions with clouds. Aerosol optical depth (AOD) has been observed from satellite platforms for over 30 years. During this time, regional changes in emissions, arising from air quality policies and socioeconomic factors, have been suggested as causes for some observed AOD trends. In the United States, the Clean Air Act and amendments have produced improvements in air quality. In this work the impacts of improved air quality on the aerosol loading and aerosol direct and indirect effects over the North Atlantic Ocean are explored using satellite, ground, and model datasets on the monthly timescale during 2002 to 2012. It is established that two trends exist in the total AOD observed by MODIS over the North Atlantic. A decreasing AOD trend between −0.02 and −0.04 per decade is observed over the mid-latitude region. Using the GOCART aerosol model it is shown that this trend results from decreases in anthropogenic species. Ground based aerosol networks (AERONET and IMPROVE) support a decreasing trend in AOD and further strengthen links to anthropogenic aerosol species, particularly sulfate species. This anthropogenic decrease occurs primarily during spring and summer. During the same time period, MODIS also observes an increasing AOD trend of 0.02 per decade located in the sub-tropical region. This trend is shown to occur during summer and is the result of natural dust aerosol. Changes in the North African environment seen in the MERRA reanalysis suggest an accelerated warming over the Saharan Desert leads to changes in the African Easterly Jet, related Easterly Waves, and baroclinicity playing a role in an increase and northward shift in African dust. Both the direct and indirect impacts of the aerosol trends are investigated. Using the SBDART radiative transfer model, estimates of the shortwave direct radiative forcing are calculated. The decrease in anthropogenic AOD produces an increase of 2.0 ± 0.3 W/m2 per decade in the Earth-system absorbance over the mid-latitude site (37.5ºN, −68.5ºE). The increase in natural AOD results in a decrease of −1.1 ± 0.2 W/m2 per decade in the Earth-system absorbance over the sub-tropical site (23.5ºN, −55.5ºE). Evaluation of the first indirect effect demonstrates agreement with Twomey theory when considering the North Atlantic domain on the whole. A regional analysis reveals the existence of counter-Twomey behavior along the U.S. Atlantic coast. Using a daily dataset during summertime with focus on warm, non-precipitating clouds, it is found that aerosol-cloud interaction in this coastal region is sensitive to vertical velocity and aerosol size. Cases experiencing updrafts (ω < 0 Pa/s) and cases of mainly coarse-mode aerosol demonstrate good agreement with Twomey theory. Additionally, cases with low specific humidity near the cloud base show non-Twomey behavior for clouds with low liquid water path.
IMPROVED SATELLITE MICROWAVE RETRIEVALS AND THEIR INCORPORATION INTO A SIMPLIFIED 4D-VAR VORTEX INITIALIZATION USING ADJOINT TECHNIQUES
(2017) Tian, Xiaoxu; Zou, Xiaolei; Atmospheric and Oceanic Sciences; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)
Microwave instruments provide unique radiance measurements for observing surface properties and vertical atmosphere profiles in almost all weather conditions except for heavy precipitation. The Advanced Microwave Scanning Radiometer 2 (AMSR2) observes radiation emitted by Earth at window channels, which helps to retrieve surface and column integrated geophysical variables. However, observations at some X- and K-band channels are susceptible to interference by television signals transmitted from geostationary satellites when AMSR2 is scanning regions including the U.S. and Europe, which is referred to as Television Frequency Interference (TFI). It is found that high reflectivity over the ocean surface is favorable for the television signals to be reflected back to space. When the angle between the Earth scene vector and the reflected signal vector is small enough, the reflected TV signals will enter AMSR2’s antenna. As a consequence, TFI will introduce erroneous information to retrieved geophysical products if not detected. This study proposes a TFI correction algorithm for observations over ocean. Microwave imagers are mostly for observing surface or column-integrated properties. In order to have vertical temperature profiles of the atmosphere, a study focusing on the Advanced Technology Microwave Sounder (ATMS) is included. A traditional AMSU-A temperature retrieval algorithm is modified to remove the scan biases in the temperature retrieval and to include only those ATMS sounding channels that are correlated with the atmospheric temperatures on the pressure level of the retrieval. The warm core structures derived for Hurricane Sandy when it moved from the tropics to the mid-latitudes are examined. Significant improvements have been obtained for the forecasts of hurricane track, but not intensity, especially during the first 6-12 hours. In this study, a simplified four-dimensional variational (4D-Var) vortex initialization model is developed to assimilate the geophysical products retrieved from the observations of both microwave imagers and microwave temperature sounders. The goal is to generate more realistic initial vortices than the bogus vortices currently incorporated in the Hurricane Weather Research and Forecasting (HWRF) model in order to improve hurricane intensity forecasts. The case included in this study is Hurricane Gaston (2016). The numerical results show that the satellite geophysical products have a desirable impact on the structure of the initialized vortex.
RADIATIVE FLUXES AND ALBEDO FEEDBACK IN POLAR REGIONS
(2011) Niu, Xiaolei; Pinker, Rachel T.; Atmospheric and Oceanic Sciences; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)
The Arctic is experiencing an unprecedented increase in surface temperature and decrease in sea ice extent. Discussion as to the causes that contribute to the Arctic warming is still ongoing. The ice-albedo feedback has been proposed as a possible mechanism for polar amplification of such warming. It states that more open water leads to more solar heat absorption, which results in more ice melting and more open water. In order to study this relationship there is a need for accurate information on the solar heat input into the Arctic Oceans. I have developed and improved inference schemes for shortwave radiative fluxes that respond to the needs of Polar Regions utilizing most recent information on atmospheric and surface states. A Moderate Resolution Imaging Spectroradiometer (MODIS) approach has been optimized for Polar Regions and implemented at 1° for 2002-2010 and at 5-km for 2007. A methodology was developed to derive solar fluxes from the Advanced Very High Resolution Radiometer (AVHRR) and implemented at 0.5° for 1983-2006. Evaluation against ground measurements over land and ocean at high latitudes shows that the MODIS shortwave flux estimates are in best agreement with ground observations as compared to other available satellite and model products, with a bias of -3.6 Wm-2 and standard deviation of 23 Wm-2 at a daily time scale. The AVHRR estimates agree with ground observations with a bias of -4.7 Wm-2 and a standard deviation of 41 Wm-2 at a daily time scale. The ice-albedo feedback was evaluated by computing the solar heating into the Arctic Ocean using the improved satellite flux estimates. A growth at a rate of 2 %/year in the trend of solar heating for 2003-09 was found at a 75 % confidence level; the trend for 1984-2002 was only 0.2 %/year at a 99 % confidence level. The ice retreat is correlated to the solar energy into the ocean at 0.7 at a 75 % confidence level. An increase in the open water fraction resulted in a maximum 300 % positive anomaly in solar heating in 2007 located where the maximum sea ice retreat is.
RETRIEVAL OF ICE CLOUD PARAMETERS USING DMSP SPECIAL SENSOR MICROWAVE IMAGER/SOUNDER
(2010) Sun, Ninghai; Li, Zhanqing; Meteorology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)
Clouds exert a profound influence on both the water balance of the atmosphere and the earth's radiation budget (Stephens 2005; Stephens and Kummerow 2007). Among the global distribution, 30% of them are ice clouds (Riedi et al. 2000). It is important to improve our knowledge of the ice cloud properties in order to determine their influence to the global ecosystem. For ice clouds with millimeter-size ice particles, which are generally found in anvil cirrus and deep convections, microwave and millimeter wave length satellite measurements are suitable for the ice cloud microphysical property retrieval because of its strong ability to penetrate deeper into dense ice clouds. For these types of ice clouds, brightness temperatures at the top of the atmosphere are analytically derived as a function of vertically integrated ice water content (i.e. ice water path), effective particle diameter, and bulk volume density. In general, three brightness temperature measurements are needed to retrieve the three ice cloud microphysical parameters. A two-stream radiative transfer theory was applied to data from the Advanced Microwave Sounding Unit (AMSU) and the Moisture Humidity Sensor (MHS) in order to generate global ice water paths operationally. This research further applied the model and theory to derive ice water path (IWP) from the Special Sensor Microwave Imager/Sounder (SSMIS) onboard the Defense Meteorological Satellite Program (DMSP) F-16 satellite. Compared to AMSU/MHS, which have field of views (FOV) varying with scan position, SSMIS scans the Earth's atmosphere at a constant viewing angle of 53o and therefore offers a uniform FOV within each scan. This unique feature allows for improved global mapping and monitoring of ice clouds so that a more accurate and realistic IWP and ice particle effective diameter distribution is expected. A direct application of SSMIS-derived ice water path is its relationship with surface rain rate as derived previously for AMSU and MHS instruments. Here, SSMIS-derived rain rate was compared to the AMSU and MHS rainfall products and hourly synthetic precipitation observations from rain gauges and surface radar. Results show that SSMIS surface precipitation distribution is spatially consistent and does not have apparent artificial boundary near coastal zones as previously seen in other algorithms. Also, the ice water path associated with a severe storm reasonably delineates the strong convective precipitation areas and has a spatial variation consistent with surface precipitation. From retrieved instantaneous surface precipitation, a tropical and subtropical oceanic precipitation anomaly time series is constructed from 5 year's worth (2005-2009) of SSMIS data. This data record is also linked to the previous constructed SSM/I 15-year (1992-2006) data record to provide a longer term climate study by satellite observations. In future studies, refined algorithms for the estimate of ice cloud base temperature and ice particle bulk volume density are going to be developed to improve the accuracy of IWP retrieval under various cloud vertical distributions. Meanwhile, a better inter-sensor cross calibration scheme is the key to make satellite measurements more useful in climate change study.
Assimilation of trace gas retrievals with the Local Ensemble Transform Kalman Filter
(2009) Kuhl, David Derieg; Kalnay, Eugenia; Szunyogh, Istvan; Atmospheric and Oceanic Sciences; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)
Over the 50 year history of Numerical Weather Prediction (NWP), the focus has been on the modeling and prediction of meteorological parameters such as surface pressure, temperature, wind, and precipitation. However, due to concerns over pollution and to recent advancements in satellite technologies, an increasing number of NWP systems have been upgraded to include capabilities to analyze and predict the concentration of trace gases. This dissertation explores some of the specific issues that have to be addressed for an efficient modeling of the concentration of the trace gases. These issues include modeling the effects of convective mixing on the concentration of the trace gases and the multivariate assimilation of space-based observations of the concentration of the trace gases. In this dissertation, we assimilate observations of the concentration of trace gases with an implementation of the Local Ensemble Transform Kalman Filter (LETKF) data assimilation system on the National Centers for Environmental Prediction (NCEP) Global Forecast System (GFS) NWP model. We use a modified version of the NCEP GFS model that was operational in 2004 at resolution T62/L28. We modify the model by adding parameterization for the process of convective mixing of the trace gases. We consider two specific trace gases: ozone (O₃) and carbon monoxide (CO). We incorporate these gases into the model by using 3-dimensional time-dependent O₃ and CO production-loss values from the Real-time Air Quality Modeling System (RAQMS) global chemical model. The O₃ observations we assimilate are from the Solar Backscatter UltraViolet generation 2 (SBUV/2) satellite instrument (version 8) flown on the NOAA 16 and 17 satellites. The CO observations we assimilate are from the Measurements Of Pollution In The Troposphere (MOPITT) instrument (version 3) flown on the NASA TERRA satellite. We also develop a new observation operator for the assimilation of retrievals with the LETKF. We carry out numerical experiment for the period between 000UTC 1 July 2004 to 000UTC 15 August in the summer of 2004. The analysis and forecast impact of the assimilation of trace gas observations on the meteorological fields is assessed by comparing the analyses and forecasts to the high resolution operational NCEP GFS analyses and to radiosonde observations. The analysis and forecast impact on the trace gas fields is assessed by comparing the analyzed and predicted fields to observations collected during the Intercontinental Chemical Transport Experiment (INTEX-A) field mission. The INTEX-A field mission was conducted to characterize composition of pollution over North America, thus providing us with ozonesonde and aircraft based verification data. We find that adding the process of convective mixing to the parameterization package of the model and the assimilation of observations of the trace gases improves the analysis and forecast of the concentration of the trace gases. In particular, our system is more accurate in quantifying the concentration of O₃ in the troposphere than the original NCEP GFS. Also, our system is competitive with the state-of-the-art RAQMS atmospheric chemical model in analyzing the concentration of O₃ and CO throughout the full atmospheric model column. The assimilation of O₃ and CO observations has a mixed impact on the analysis and forecast of the meteorological fields. We find that most of the negative impact on the meteorological fields can be eliminated, without much reduction to the positive impact on the trace gas fields, by inflating the prescribed variance of the trace gas observations. The appendices of this dissertation reproduces two papers on related research. The first paper covers the northward front movement and rising surface temperatures in the great planes. The second paper covers the assessment of predictability with a Local Ensemble Kalman Filter.
THE GENERATION AND APPLICATIONS OF A SPECTRALLY RESOLVED INFRARED RADIANCE CLIMATOLOGY DERIVED FROM THE ATMOSPHERIC INFRARED SOUNDER
(2009) Goldberg, Mitchell David; Kalnay, Eugenia; Li, Zhanqing; Atmospheric and Oceanic Sciences; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)
There is growing consensus that persistent and increasing anthropogenic emissions, since the beginning of the industrial revolution in the 19th century, are increasing atmospheric temperatures, increasing sea levels, melting ice caps and glaciers, increasing the occurrence of severe weather, and causing regional shifts in precipitation patterns. Changes in these parameters or occurrences are responses to changes in climate forcing terms, notably greenhouse gases. The NASA Atmospheric InfraRed Sounder (AIRS), launched in May of 2002, is the first high spectral resolution infrared sounder with nearly complete global coverage on a daily basis. High spectral resolution in the infrared provides sensitivity to nearly all climate forcings, responses and feedbacks. The AIRS radiances are sensitive to changes in carbon dioxide, methane, carbon monoxide, ozone, water vapor, temperature, clouds, aerosols, and surface characteristics. This study uses the raw AIRS data to generate the first ever spectrally resolved infrared radiance (SRIR) dataset (2002- 2006) for monitoring changes in atmospheric temperature and constituents and for assessing the accuracy of climate and weather model analyses and forecasts. The SRIR dataset is a very powerful tool. Spectral signatures derived from the dataset confirmed the largest depletion of ozone over the Arctic in 2005, and also verified that the European Center for Medium Range Weather (ECMWF) model analysis water vapor fields are significantly more accurate than the analyses of the National Centers for Environmental Prediction (NCEP). The NCEP moisture fields are generally 20% more moist than those from ECMWF. This research included computations of radiances from NCEP and ECMWF atmospheric states and compared the calculated radiances with those obtained from the SRIR dataset. Comparisons showed very good agreement between the SRIR data and ECMWF simulated radiances, while the agreement with NCEP values was rather poor. Interannual differences of radiances computed from ECMWF analyses were nearly identical to those derived from the SRIR dataset, while the corresponding NCEP interannual differences were in poorer agreement. However, further comparisons with the SRIR dataset in 2006 found degradation in the ECMWF upper tropospheric water vapor fields due to an operational change in ECMWF assimilation procedures. This unexpected result demonstrates the importance of continuous routine monitoring. The SRIR climatology will be extended into the future using AIRS and other high spectral resolution sounders.
RETRIEVAL OF TROPOSPHERIC AEROSOL PROPERTIES OVER LAND FROM INVERSION OF VISIBLE AND NEAR-INFRARED SPECTRAL REFLECTANCE: APPLICATION OVER MARYLAND
(2007-04-26) Levy, Robert; Dickerson, Russell R.; Remer, Lorraine A; Atmospheric and Oceanic Sciences; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)
Aerosols are major components of the Earth's global climate system, affecting the radiation budget and cloud processes of the atmosphere. When located near the surface, high concentrations lead to lowered visibility, increased health problems and generally reduced quality of life for the human population. Over the United States mid-Atlantic region, aerosol pollution is a problem mainly during the summer. Satellites, such as the MODerate Imaging Spectrometer (MODIS), from their vantage point above the atmosphere, provide unprecedented coverage of global and regional aerosols over land. During MODIS' eight-year operation, exhaustive data validation and analyses have shown how the algorithm should be improved. This dissertation describes the development of the 'second-generation' operational algorithm for retrieval of global tropospheric aerosol properties over dark land surfaces, from MODIS -observed spectral reflectance. New understanding about global aerosol properties, land surface reflectance characteristics, and radiative transfer properties were learned in the process. This new operational algorithm performs a simultaneous inversion of reflectance in two visible channels (0.47 and 0.66 μm) and one shortwave infrared channel (2.12 μm), thereby having increased sensitivity to coarse aerosol. Inversion of the three channels retrieves the aerosol optical depth (τ) at 0.55 μm, the percentage of non-dust (fine model) aerosol (η) and the surface reflectance. This algorithm is applied globally, and retrieves τ that is highly correlated (y = 0.02 + 1.0x, R=0.9) with ground-based sunphotometer measurements. The new algorithm estimates the global, over-land, long-term averaged τ ~ 0.21, a 25% reduction from previous MODIS estimates. This leads to reducing estimates of global, non-desert, over-land aerosol direct radiative effect (all aerosols) by 1.7 W·m-2 (0.5 W·m-2 over the entire globe), which significantly impacts assessment of aerosol direct radiative forcing (contribution from anthropogenic aerosols only). Over the U.S. mid-Atlantic region, validated retrievals of τ (an integrated column property) can help to estimate surface PM2.5 concentration, a monitored criteria air quality property. The 3-dimensional aerosol loading in the region is characterized using aircraft measurements and the Community Multi-scale Air Quality Model (CMAQ) model, leading to some convergence of observed quantities and modeled processes.
MEASUREMENTS AND CHARACTERIZATION OF OPTICAL PROPERTIES IN THE CHESAPEAKE BAY'S ESTUARINE WATERS USING IN-SITU MEASUREMENTS, MODIS SATELLITE OBSERVATIONS, AND RADIATIVE TRANSFER MODELING
(2004-01-27) Tzortziou, Maria; Hudson, Robert; Meteorology
The core subject of this thesis is the development of coordinated atmospheric, in-water, and laboratory measurements leading to characterization of in-water optical properties in the estuarine environment of northern Chesapeake Bay, where natural and human-induced processes strongly interact. One of the main objectives is obtaining a sufficiently complete suite of measurements, combined with detailed radiative transfer calculations, so as to produce a closure experiment for the underwater inherent and apparent optical properties. The in-situ results are applied to the interpretation of satellite (MODIS) water leaving radiance data and their validation. The applicability of bio-optical models and parameterizations currently used in satellite algorithms are examined for the case of the optically complex Chesapeake Bay waters. Relationships between remotely sensed water leaving radiances and properties of optically active components in these waters are investigated. The resulting techniques and analysis should be broadly applicable to other coastal areas of the world. The results from this thesis, and other future work, will contribute to our ability to obtain more accurate information from remotely measured optical characteristics of estuarine and coastal regions. The combined use of in-situ measurements and detailed radiative transfer modeling enables the improvement of both the theoretical models and satellite remote sensing algorithms needed to a better understanding of biotic responses to environmental forcing.

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