Environmental Science & Technology Research Works
Permanent URI for this collectionhttp://hdl.handle.net/1903/1601
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Item Bio-Electrochemical Enhancement of Hydrogen and Methane Production in a Combined Anaerobic Digester (AD) and Microbial Electrolysis Cell (MEC) from Dairy Manure(MDPI, 2020-10-14) Hassanein, Amro; Witarsa, Freddy; Lansing, Stephanie; Qiu, Ling; Liang, YongAnaerobic digestion (AD) is a biological-based technology that generates methane-enriched biogas. A microbial electrolysis cell (MEC) uses electricity to initiate bacterial oxidization of organic matter to produce hydrogen. This study determined the effect of energy production and waste treatment when using dairy manure in a combined AD and MEC (AD-MEC) system compared to AD without MEC (AD-only). In the AD-MEC system, a single chamber MEC (150 mL) was placed inside a 10 L digester on day 20 of the digestion process and run for 272 h (11 days) to determine residual treatment and energy capacity with an MEC included. Cumulative H2 and CH4 production in the AD-MEC (2.43 L H2 and 23.6 L CH4) was higher than AD-only (0.00 L H2 and 10.9 L CH4). Hydrogen concentration during the first 24 h of MEC introduction constituted 20% of the produced biogas, after which time the H2 decreased as the CH4 concentration increased from 50% to 63%. The efficiency of electrical energy recovery (ηE) in the MEC was 73% (ηE min.) to 324% (ηE max.), with an average increase of 170% in total energy compared to AD-only. Chemical oxygen demand (COD) removal was higher in the AD-MEC (7.09 kJ/g COD removed) system compared to AD-only (6.19 kJ/g COD removed). This study showed that adding an MEC during the digestion process could increase overall energy production and organic removal from dairy manure.Item Assessment of Petroleum-Based Plastic and Bioplastics Degradation Using Anaerobic Digestion(MDPI, 2021-12-01) Nachod, Benjamin; Keller, Emily; Hassanein, Amro; Lansing, StephanieBioplastics have emerged as a viable alternative to traditional petroleum-based plastic (PET). Three of the most common bioplastic polymers are polyhydroxybutyrate-valerate (PHBV), polylactide (PLA), and cellulose-based bioplastic (CBB). This study assessed biodegradation through anaerobic digestion (AD) of these three bioplastics and PET digested with food waste (FW) at mesophilic (35 °C) and thermophilic (55 °C) temperatures. The four plastic types were digested with FW in triplicate batch reactors. Additionally, two blank treatments (inoculum-only) and two PHBV treatments (with FW + inoculum and inoculum-only) were digested at 35 and 55 °C. The PHBV treatment without FW at 35 °C (PHBV-35) produced the most methane (CH4) normalized by the volatile solids (VS) of the bioplastics over the 104-day experimental period (271 mL CH4/g VS). Most bioplastics had more CH4 production than PET when normalized by digester volume or gram substrate added, with the PLA-FW-55 (5.80 m3 CH4/m3), PHBV-FW-55 (2.29 m3 CH4/m3), and PHBV-55 (4.05 m3 CH4/m3) having 848,275 and 561%, respectively, more CH4 production than the PET treatment. The scanning electron microscopy (SEM) showed full degradation of PHBV pellets after AD. The results show that when PHBV is used as bioplastic, it can be degraded with energy production through AD.Item Olive Mill Waste-Based Anaerobic Digestion as a Source of Local Renewable Energy and Nutrients(MDPI, 2022-01-26) Aboelfetoh, Mohamed; Hassanein, Amro; Ragab, Mohamed; El-kassas, Mohamed; Marzouk, Ezzat R.This study focused on what combination of anaerobic digestion (AD) temperature (ambient, mesophilic, and thermophilic) and olive mill waste (OMW) to dairy manure (DM) ratio mixture delivers the desired renewable energy and digestate qualities when using AD as olive mill waste treatment. OMW is widespread in the local environment in the North Sinai region, Egypt, which causes many environmental hazards if left without proper treatment. Three different mixtures consisting of OMW, dairy manure (DM), and inoculum (IN) were incubated under ambient, mesophilic, and thermophilic conditions for 45 days. The results showed that mixture B (2:1:2, OMW:DM:IN) at 55 °C produced more methane than at 35 °C and ambient temperature by 40% and 252%, respectively. Another aim of this study was to investigate the effects of the different concentrations of the digestate taken from each mixture on faba bean growth. The results showed that the maximum fresh weight values of the shoot system were observed at 10% and 15% for mixture B at ambient temperature. The best concentration value for the highest root elongation rate is a 5% addition of digestate mixture A at 55 °C, compared with other treatments.