Atmospheric & Oceanic Science Research Works

Permanent URI for this collectionhttp://hdl.handle.net/1903/1596

Formerly known as the Department of Meteorology.

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Analysis of Summertime PM2.5 and haze in the Mid-Atlantic Region
(Air & Waste Management Association (A&WMA), 2003) Chen, L.-W. Antony; Chow, Judith C.; Doddridge, Bruce G.; Dickerson, Russell R.; Ryan, William F.; Mueller, Peter K.
Observations of the mass and chemical composition of particles less than 2.5 µm in aerodynamic diameter (PM2.5), light extinction, and meteorology in the urban Baltimore-Washington corridor during July 1999 and July 2000 are presented and analyzed to study summertime haze formation in the mid-Atlantic region. The mass fraction of ammoniated sulfate (SO4^2-) and carbonaceous material in PM2.5 were each ~50% for cleaner air (PM2.5 < 10 µg/m3) but changed to ~60% and ~20%, respectively, for more polluted air (PM2.5 > 30 µg/m3). This signifies the role of SO4^2- in haze formation. Comparisons of data from this study with the Interagency Monitoring of Protected Visual Environments network suggest that SO4^2- is more regional than carbonaceous material and originates in part from upwind source regions. The light extinction coefficient is well correlated to PM2.5 mass plus water associated with inorganic salt, leading to a mass extinction efficiency of 7.6 ± 1.7 m2/g for hydrated aerosol. The most serious haze episode occurring between July 15 and 19, 1999, was characterized by westerly transport and recirculation slowing removal of pollutants. At the peak of this episode, 1-hr PM2.5 concentration reached ~45 µg/m3, visual range dropped to ~5 km, and aerosol water likely contributed to ~40% of the light extinction coefficient.
Aircraft Observations of Dust and Pollutants over NE China: Insight into the Meteorological Mechanisms of Long-Range Transport
(2006) Dickerson, Russell; Li, Can; Li, Zhanqing; Marufu, Lackson; Stehr, Jeffrey; Chen, H.; Wang, P; Xia, X.; Ban, X.; Gong, F.; Yaun, J.; Yang, J.
Substantial concentrations of trace gases and aerosols are lofted and carried from Asia over the Pacific producing an inter-hemispheric impact on atmospheric chemistry and climate. The meteorological mechanism leading to this large-scale transport of dust and pollutants remains a major uncertainty in quantifying the global effects of emissions from the developing world. Models and downwind measurements have identified isentropic advection associated with wave cyclones (warm conveyor belt circulation) as an important mechanism. We present data from a case study conducted over Shenyang in NE China as part of EAST-AIRE in April 2005 in which upstream convection, rather than WCB lofting appears to dominate. Observations from instrumented aircraft flights, back trajectories, and satellite images of clouds (GOES) and aerosols (MODIS) are analyzed. In this heavily industrialized and populated region, the warm-sector PBL air ahead of a cold front was highly polluted. In the free troposphere, between ~1000 and 4000 m altitude, concentrations of trace gases and aerosols were lower, but well above background; we measured ~70 ppb O3, ~300 ppb CO, ~2 ppb SO2, and ~ 8x10-5 m-1 aerosol scattering. These observations show that dry (non-precipitating) convection can be an important mechanism for converting local air pollution problems into regional or global atmospheric chemistry problems. Climatological data indicate that spring (MAM) precipitation over NE China is low, about 90 mm compared to 290 mm over the NE US. Cloud cover, however, is similar with cumulus clouds reported about 7% of the time over NE China and about 9% of the time over the NE US suggesting that lofting in dry convective events may be common over NE Asia. Evaluation of models’ convective schemes and further observations near the source regions are called for.
Validation of SO2 retrievals from the Ozone Monitoring Instrument (OMI) over NE China
(American Geophysical Union (AGU), 2008) Krotkov, N. A.; McClure, B.; Dickerson, R. R.; Carn, S.; Li, C.; Bhartia, P. K.; Yang, K.; Krueger, A.; Li, Z.; Levelt, P. F.; Chen, Hongbin; Wang, Pucai; Lu, Daren
The Ozone Monitoring Instrument (OMI) launched on the NASA Aura satellite in July 2004 offers unprecedented spatial resolution, coupled with contiguous daily global coverage, for space-based UV measurements of sulfur dioxide (SO2). We present a first validation of the OMI SO2 data with in-situ aircraft measurements in NE China in April 2005. The study demonstrates that OMI can distinguish between background SO2 conditions and heavy pollution on a daily basis. The noise (expressed as the standard deviation, σ) in the PBL SO2 data is ~1.5DU (Dobson Unit, 2.691016 molecules/cm2) for instantaneous field of view (IFOV) data. By looking at the pristine South Pacific under optimal conditions we have determined that temporal and spatial averaging can improve the resolution of the instrument to σ ~ 0.3 DU; the long term average over this remote location was within 0.1 DU of zero. Under polluted conditions, however, Collection 2 data are higher than aircraft measurements by a factor of two in most cases. Parameterization of the airmass factor (AMF) appears to enhance the accuracy of the SO2 data. Improved calibrations of the radiance and irradiance data (Collection 3) result in better agreement with aircraft measurements on polluted days. The re-processed and AMF-corrected Collection 3 data still show positive bias and sensitivity to UV absorbing aerosols. The difference between the in situ data and the OMI daily PBL SO2 measurements within 30 km of the aircraft profiles was about 1 DU, equivalent to ~5 ppb from 0 to 3000 m altitude. Quantifying the SO2 profile and spectral dependence of aerosol absorption between 310 and 330 nm are critical for accurate estimates of SO2 from satellite UV measurements.
Observed Relationship of Ozone air Pollution with Temperature and Emissions
(American Geophysical Union (AGU), 2009) Bloomer, Bryan J. ; Stehr, Jeffrey W. ; Piety, Charles A.; Salawitch, Ross J.; Dickerson, Russell R.
Higher temperatures caused by increasing greenhouse gas concentrations are predicted to exacerbate photochemical smog if precursor emissions remain constant. We perform a statistical analysis of 21 years of ozone and temperature observations across the rural eastern U.S. The climate penalty factor is defined as the slope of the ozone/temperature relationship. For two precursor emission regimes, before and after 2002, the climate penalty factor was consistent across the distribution of ozone observations. Prior to 2002, ozone increased by an average of ~3.2 ppbv/°C. After 2002, power plant NOx emissions were reduced by 43%, ozone levels fell ~10%, and the climate penalty factor dropped to ~2.2 ppbv/°C. NOx controls are effective for reducing photochemical smog and might lessen the severity of projected climate change penalties. Air quality models should be evaluated against these observations, and the climate penalty factor metric may be useful for evaluating the response of ozone to climate change.
The Sensitivity of Modeled Ozone to the Temporal Distribution of Point, Area, and Mobile Emissions in the Eastern US
(Elsevier, 2009) Castellanos, Patricia; Ehrman, Sheryl H.; Stehr, Jeffrey W.; Dickerson, Russell R.
Ozone remains one of the most recalcitrant air pollution problems in the US. Hourly emissions fields used in air quality models (AQMs) generally show less temporal variability than corresponding measurements. In order to understand how the daily cycle of estimated emissions affects modeled ozone, we analyzed the effects of altering all anthropogenic emissions’ temporal distributions by source group 2 on 2002 summer-long simulations of ozone using the Community Multi-Scale Air Quality Model (CMAQ) v4.5 and the carbon bond IV (CBIV) chemical mechanism with a 12 km grid. We find that when mobile source emissions were made constant over the course of a day, 8-hour maximum ozone predictions changed by ±7 parts per billion by volume (ppbv) in urban areas on days when ozone concentrations greater than 80 ppbv were simulated in the base case. Increasing the temporal variation of point sources resulted in ozone changes of +6 and –6 ppbv, but only for small areas near sources. Changing the daily cycle of mobile source emissions produces substantial changes in simulated ozone, especially in urban areas at night; implications for abatement strategy are discussed.
Ozone production and its sensitivity to NOx and VOCs: results from the DISCOVER-AQ field experiment, Houston 2013
(Copernicus Publications, 2016-11-22) Mazzuca, Gina M.; Ren, Xinrong; Loughner, Christopher P.; Estes, Mark; Crawford, James H.; Pickering, Kenneth E.; Weinheimer, Andrew J.; Dickerson, Russell R.
An observation-constrained box model based on the Carbon Bond mechanism, version 5 (CB05), was used to study photochemical processes along the NASA P-3B flight track and spirals over eight surface sites during the September 2013 Houston, Texas deployment of the NASA Deriving Information on Surface Conditions from COlumn and VERtically Resolved Observations Relevant to Air Quality (DISCOVER-AQ) campaign. Data from this campaign provided an opportunity to examine and improve our understanding of atmospheric photochemical oxidation processes related to the formation of secondary air pollutants such as ozone (O3). O3 production and its sensitivity to NOx and volatile organic compounds (VOCs) were calculated at different locations and times of day. Ozone production efficiency (OPE), defined as the ratio of the ozone production rate to the NOx oxidation rate, was calculated using the observations and the simulation results of the box and Community Multiscale Air Quality (CMAQ) models. Correlations of these results with other parameters, such as radical sources and NOx mixing ratio, were also evaluated. It was generally found that O3 production tends to be more VOC-sensitive in the morning along with high ozone production rates, suggesting that control of VOCs may be an effective way to control O3 in Houston. In the afternoon, O3 production was found to be mainly NOx-sensitive with some exceptions. O3 production near major emissions sources such as Deer Park was mostly VOC-sensitive for the entire day, other urban areas near Moody Tower and Channelview were VOC-sensitive or in the transition regime, and areas farther from downtown Houston such as Smith Point and Conroe were mostly NOx-sensitive for the entire day. It was also found that the control of NOx emissions has reduced O3 concentrations over Houston but has led to larger OPE values. The results from this work strengthen our understanding of O3 production; they indicate that controlling NOx emissions will provide air quality benefits over the greater Houston metropolitan area in the long run, but in selected areas controlling VOC emissions will also be beneficial.
A Study of the Oklahoma City Urban Heat Island Effect Using a WRF/Single-Layer Urban Canopy Model, a Joint Urban 2003 Field Campaign, and MODIS Satellite Observations
(MDPI, 2017-09-07) Zhang, Hengyue; Jin, Menglin S.; Leach, Martin
The urban heat island effect (UHI) for inner land regions was investigated using satellite data, ground observations, and simulations with an Single-Layer Urban Canopy Parameterization (SLUCP) coupled into the regional Weather Research Forecasting model (WRF, http://wrf-model.org/index.php). Specifically, using the satellite-observed surface skin temperatures (Tskin), the intensity of the UHI was first compared for two inland cities (Xi’an City, China, and Oklahoma City (OKC)), which have different city populations and building densities. The larger population density and larger building density in Xi’an lead to a stronger skin-level UHI by 2 °C. However, the ground observed 2 m surface air temperature (Tair) observations showed an urban cooling island effect (UCI) over the downtown region in OKC during the daytime of 19 July 2003, from a DOE field campaign (Joint Urban 2003). To understand this contrast between satellite-based Tskin and ground-based Tair, a sensitivity study using WRF/SLUCP was analyzed. The model reproduced a UCI in OKC. Furthermore, WRF/Noah/SLUCM simulations were also compared with the Joint Urban 2003 ground observations, including wind speeds, wind directions, and energy fluxes. Although the WRF/SLUCM model failed to simulate these variables accurately, it reproduced the diurnal variations of surface temperatures, wind speeds, wind directions, and energy fluxes reasonably well.
Assessing Coastal SMAP Surface Salinity Accuracy and Its Application to Monitoring Gulf of Maine Circulation Dynamics
(MDPI, 2018-08-06) Grodsky, Semyon A.; Vandemark, Douglas; Feng, Hui
Monitoring the cold and productive waters of the Gulf of Maine and their interactions with the nearby northwestern (NW) Atlantic shelf is important but challenging. Although remotely sensed sea surface temperature (SST), ocean color, and sea level have become routine, much of the water exchange physics is reflected in salinity fields. The recent invention of satellite salinity sensors, including the Soil Moisture Active Passive (SMAP) radiometer, opens new prospects in regional shelf studies. However, local sea surface salinity (SSS) retrieval is challenging due to both cold SST limiting salinity sensor sensitivity and proximity to land. For the NW Atlantic, our analysis shows that SMAP SSS is subject to an SST-dependent bias that is negative and amplifies in winter and early spring due to the SST-related drop in SMAP sensor sensitivity. On top of that, SMAP SSS is subject to a land contamination bias. The latter bias becomes noticeable and negative when the antenna land contamination factor (LC) exceeds 0.2%, and attains maximum negative values at LC = 0.4%. Coastward of LC = 0.5%, a significant positive land contamination bias in absolute SMAP SSS is evident. SST and land contamination bias components are seasonally dependent due to seasonal changes in SST/winds and terrestrial microwave properties. Fortunately, it is shown that SSS anomalies computed relative to a satellite SSS climatology can effectively remove such seasonal biases along with the real seasonal cycle. SMAP monthly SSS anomalies have sufficient accuracy and applicability to extend nearer to the coasts. They are used to examine the Gulf of Maine water inflow, which displayed important water intrusions in between Georges Banks and Nova Scotia in the winters of 2016/17 and 2017/18. Water intrusion patterns observed by SMAP are generally consistent with independent measurements from the European Soil Moisture Ocean Salinity (SMOS) mission. Circulation dynamics related to the 2016/2017 period and enhanced wind-driven Scotian Shelf transport into the Gulf of Maine are discussed.
Climate model shows large-scale wind and solar farms in the Sahara increase rain and vegetation
(Science, 2018-09-07) Li, Yan; Kalnay, Eugenia; Motesharrei, Safa; Rivas, Jorge; Kucharski, Fred; Kirk-Davidoff, Daniel; Bach, Eviatar; Zeng, Ning
Wind and solar farms offer a major pathway to clean, renewable energies. However, these farms would significantly change land surface properties, and, if sufficiently large, the farms may lead to unintended climate consequences. In this study, we used a climate model with dynamic vegetation to show that large-scale installations of wind and solar farms covering the Sahara lead to a local temperature increase and more than a twofold precipitation increase, especially in the Sahel, through increased surface friction and reduced albedo. The resulting increase in vegetation further enhances precipitation, creating a positive albedo–precipitation–vegetation feedback that contributes ~80% of the precipitation increase for wind farms. This local enhancement is scale dependent and is particular to the Sahara, with small impacts in other deserts.
Tidal Mixing Signatures in the Hong Kong Coastal Waters from Satellite-Derived Sea Surface Temperature
(MDPI, 2018-12-20) Susanto, R. Dwi; Pan, Jiayi; Devlin, Adam T.
Tidal mixing in the coastal waters of Hong Kong was investigated using a combination of in situ observations and high-resolution satellite-derived sea surface temperature (SST) data. An indicator of tide-induced mixing is a fortnightly (spring-neap cycle) signature in SST due to nonlinear interactions between the two principal diurnal and the two principal semi-diurnal tides. Both semi-diurnal and diurnal tides have strong tidal amplitudes and currents near Hong Kong. As a result, both the near-fortnightly (Mf) and fortnightly (MSf) tides are enhanced due to nonlinear tidal signal interactions. In addition, these fortnightly tidal signals are modulated by seasonal variability, with the maximum seasonal modulation of fortnightly tides occurring during the monsoon transition periods in May and October. The largest fortnightly signals are found in the southwestern part of the Pearl River estuary. Tidal constituent properties vary by space and depth, and high-resolution SST plays a pivotal role in resolving the spatial characteristics of tidal mixing.
Towards a Unified and Coherent Land Surface Temperature Earth System Data Record from Geostationary Satellites
(MDPI, 2019-06-12) Pinker, Rachel T.; Ma, Yingtao; Chen, Wen; Hulley, Glynn; Borbas, Eva; Islam, Tanvir; Hain, Chris; Cawse-Nicholson, Kerry; Hook, Simon; Basara, Jeff
Our objective is to develop a framework for deriving long term, consistent Land Surface Temperatures (LSTs) from Geostationary (GEO) satellites that is able to account for satellite sensor updates. Specifically, we use the Radiative Transfer for TOVS (RTTOV) model driven with Modern-Era Retrospective Analysis for Research and Applications (MERRA-2) information and Combined ASTER and MODIS Emissivity over Land (CAMEL) products. We discuss the results from our comparison of the Geostationary Operational Environmental Satellite East (GOES-E) with the MODIS Land Surface Temperature and Emissivity (MOD11) products, as well as several independent sources of ground observations, for daytime and nighttime independently. Based on a six-year record at instantaneous time scale (2004–2009), most LST estimates are within one std from the mean observed value and the bias is under 1% of the mean. It was also shown that at several ground sites, the diurnal cycle of LST, as averaged over six years, is consistent with a similar record generated from satellite observations. Since the evaluation of the GOES-E LST estimates occurred at every hour, day and night, the data are well suited to address outstanding issues related to the temporal variability of LST, specifically, the diurnal cycle and the amplitude of the diurnal cycle, which are not well represented in LST retrievals form Low Earth Orbit (LEO) satellites.
Validation and Improvement of the WRF Building Environment Parametrization (BEP) Urban Scheme
(MDPI, 2019-09-10) Gohil, Kanishk; Jin, Menglin S.
The building environment parameterization scheme (BEP) is a built-in “urban physics” scheme in the weather research and forecasting (WRF) model. The urbanized College Park (CP) in Maryland state (MD) in the United States (US) covers an approximate land area of 14.8 km2 and has a population of 32,000 (reported by The United States Census Bureau, as of 2017). This study was an effort to validate and improve the BEP urban physics scheme for a small urban setting, College Park, MD. Comparing the WRF/BEP-simulated two-meter air temperatures with the local rooftop WeatherBug® observations and with the airport observations, systemic deficiencies in BEP for urban heat island effect simulation are evident. Specifically, WRF/BEP overestimates the two-meter air temperature by about 10 °F during clear summer nights and slightly underestimates it during noon of the same days by about 1–3 °F. Similar deficiencies in skin temperature simulations are also evident in WRF/BEP. Modification by adding an anthropogenic heat flux term resulted in better estimates for both skin and two-meter air temperatures on diurnal and seasonal scales.
The College Park, Maryland, Tornado of 24 September 2001
(MDPI, 2019-10-22) Pryor, Kenneth L.; Wawrzyniak, Tyler; Zhang, Da-Lin
The 24 September 2001 College Park, Maryland, tornado was a long-track and strong tornado that passed within a close range of two Doppler radars. It was the third in a series of three tornadoes associated with a supercell storm that developed in Stafford County, Virginia, and initiated 3–4 km southwest of College Park and dissipated near Columbia, Howard County. The supercell tracked approximately 120 km and lasted for about 126 min. This study presents a synoptic and mesoscale overview of favorable conditions and forcing mechanisms that resulted in the severe convective outbreak associated with the College Park tornado. The results show many critical elements of the tornadic event, including a negative-tilted upper-level trough over the Ohio Valley, a jet stream with moderate vertical shear, a low-level warm, moist tongue of the air associated with strong southerly flow over south-central Maryland and Virginia, and significantly increased convective available potential energy (CAPE) during the late afternoon hours. A possible role of the urban heat island effects from Washington, DC, in increasing CAPE for the development of the supercell is discussed. Satellite imagery reveals the banded convective morphology with high cloud tops associated with the supercell that produced the College Park tornado. Operational WSR-88D data exhibit a high reflectivity “debris ball” or tornadic debris signature (TDS) within the hook echo, the evolution of the parent storm from a supercell structure to a bow echo, and a tornado cyclone signature (TCS). Many of the mesoscale features could be captured by contemporary numerical model analyses. This study concludes with a discussion of the effectiveness of the coordinated use of satellite and radar observations in the operational environment of nowcasting severe convection.
Full Results Accompanying A Machine Learning Examination of Hydroxyl Radical Differences Among Model Simulations for CCMI-1
(2020) Nicely, Julie M.; Duncan, Bryan N.; Hanisco, Thomas F.; Wolfe, Glenn M.; Salawitch, Ross J.; Deushi, Makoto; Haslerud, Amund S.; Jöckel, Patrick; Josse, Béatrice; Kinnison, Douglas E.; Klekociuk, Andrew; Manyin, Michael E.; Marécal, Virginie; Morgenstern, Olaf; Murray, Lee T.; Myhre, Gunnar; Oman, Luke D.; Pitari, Giovanni; Pozzer, Andrea; Quaglia, Ilaria; Revell, Laura E.; Rozanov, Eugene; Stenke, Andrea; Stone, Kane; Strahan, Susan; Tilmes, Simone; Tost, Holger; Westervelt, Daniel M.; Zeng, Guang
The hydroxyl radical (OH) plays critical roles within the troposphere, such as determining the lifetime of methane (CH4), yet is challenging to model due to its fast cycling and dependence on a multitude of sources and sinks. As a result, the reasons for variations in OH and the resulting methane lifetime, both between models and in time, are difficult to diagnose. We apply a neural network (NN) approach to address this issue within a group of models that participated in the Chemistry-Climate Model Initiative (CCMI). Analysis of the historical specified dynamics simulations performed for CCMI indicates that the primary drivers of methane lifetime differences among ten models are the flux of UV light to the troposphere (indicated by the photolysis frequency JO1D), the mixing ratio of tropospheric ozone (O3), the abundance of nitrogen oxides (NOx=NO+NO2), and details of the various chemical mechanisms that drive OH. Water vapor, carbon monoxide (CO), the ratio of NO:NOx, and formaldehyde (HCHO) explain moderate differences in methane lifetime, while isoprene, methane, the photolysis frequency of NO2 by visible light (JNO2), overhead ozone column, and temperature account for little-to-no model variation in methane lifetime. We also apply the NNs to analysis of temporal trends in OH from 1980 to 2015. All models that participated in the specified dynamics historical simulation for CCMI demonstrate a decline in methane lifetime during the analysed timeframe. The significant contributors to this trend, in order of importance, are tropospheric O3, JO1D, NOx, and H2O, with CO also causing substantial interannual variability in OH burden. Finally, the identified trends in methane lifetime are compared to calculated trends in the tropospheric mean OH concentration from previous work, based on analysis of observations. The comparison reveals a robust result for the effect of rising water vapor on OH and methane lifetime, imparting an increasing and decreasing trend of about 0.5 % per decade, respectively. The responses due to NOx, ozone column, and temperature are also in reasonably good agreement between the two studies.
Wildfire Smoke Particle Properties and Evolution, from Space-Based Multi-Angle Imaging
(MDPI, 2020-02-26) Noyes, Katherine Junghenn; Kahn, Ralph; Sedlacek, Arthur; Kleinman, Lawrence; Limbacher, James; Li, Zhanqing
Emitted smoke composition is determined by properties of the biomass burning source and ambient ecosystem. However, conditions that mediate the partitioning of black carbon (BC) and brown carbon (BrC) formation, as well as the spatial and temporal factors that drive particle evolution, are not understood adequately for many climate and air-quality related modeling applications. In situ observations provide considerable detail about aerosol microphysical and chemical properties, although sampling is extremely limited. Satellites offer the frequent global coverage that would allow for statistical characterization of emitted and evolved smoke, but generally lack microphysical detail. However, once properly validated, data from the National Aeronautics and Space Administration (NASA) Earth Observing System’s Multi-Angle Imaging Spectroradiometer (MISR) instrument can create at least a partial picture of smoke particle properties and plume evolution. We use in situ data from the Department of Energy’s Biomass Burning Observation Project (BBOP) field campaign to assess the strengths and limitations of smoke particle retrieval results from the MISR Research Aerosol (RA) retrieval algorithm. We then use MISR to characterize wildfire smoke particle properties and to identify the relevant aging factors in several cases, to the extent possible. The RA successfully maps qualitative changes in effective particle size, light absorption, and its spectral dependence, when compared to in situ observations. By observing the entire plume uniformly, the satellite data can be interpreted in terms of smoke plume evolution, including size-selective deposition, new-particle formation, and locations within the plume where BC or BrC dominates.
Hygroscopicity of Different Types of Aerosol Particles: Case Studies Using Multi-Instrument Data in Megacity Beijing, China
(MDPI, 2020-03-01) Wu, Tong; Li, Zhanqing; Chen, Jun; Wang, Yuying; Wu, Hao; Jin, Xiao'ai; Liang, Chen; Li, Shangze; Wang, Wei; Cribb, Maureen
Water uptake by aerosol particles alters its light-scattering characteristics significantly. However, the hygroscopicities of different aerosol particles are not the same due to their different chemical and physical properties. Such differences are explored by making use of extensive measurements concerning aerosol optical and microphysical properties made during a field experiment from December 2018 to March 2019 in Beijing. The aerosol hygroscopic growth was captured by the aerosol optical characteristics obtained from micropulse lidar, aerosol chemical composition, and aerosol particle size distribution information from ground monitoring, together with conventional meteorological measurements. Aerosol hygroscopicity behaves rather distinctly for mineral dust coarse-mode aerosol (Case I) and non-dust fine-mode aerosol (Case II) in terms of the hygroscopic enhancement factor, 𝑓𝛽(𝑅𝐻,𝜆532), calculated for the same humidity range. The two types of aerosols were identified by applying the polarization lidar photometer networking method (POLIPHON). The hygroscopicity for non-dust aerosol was much higher than that for dust conditions with the 𝑓𝛽(𝑅𝐻,𝜆532) being around 1.4 and 3.1, respectively, at the relative humidity of 86% for the two cases identified in this study. To study the effect of dust particles on the hygroscopicity of the overall atmospheric aerosol, the two types of aerosols were identified and separated by applying the polarization lidar photometer networking method in Case I. The hygroscopic enhancement factor of separated non-dust fine-mode particles in Case I had been significantly strengthened, getting closer to that of the total aerosol in Case II. These results were verified by the hygroscopicity parameter, κ (Case I non-dust particles: 0.357 ± 0.024; Case II total: 0.344 ± 0.026), based on the chemical components obtained by an aerosol chemical speciation instrument, both of which showed strong hygroscopicity. It was found that non-dust fine-mode aerosol contributes more during hygroscopic growth and that non-hygroscopic mineral dust aerosol may reduce the total hygroscopicity per unit volume in Beijing.
Impact of Fire Emissions on U.S. Air Quality from 1997 to 2016–A Modeling Study in the Satellite Era
(MDPI, 2020-03-12) Tao, Zhining; He, Hao; Sun, Chao; Tong, Daniel; Liang, Xin-Zhong
A regional modeling system that integrates the state-of-the-art emissions processing (SMOKE), climate (CWRF), and air quality (CMAQ) models has been combined with satellite measurements of fire activities to assess the impact of fire emissions on the contiguous United States (CONUS) air quality during 1997–2016. The system realistically reproduced the spatiotemporal distributions of the observed meteorology and surface air quality, with a slight overestimate of surface ozone (O3) by ~4% and underestimate of surface PM2.5 by ~10%. The system simulation showed that the fire impacts on primary pollutants such as CO were generally confined to the fire source areas but its effects on secondary pollutants like O3 spread more broadly. The fire contribution to air quality varied greatly during 1997-2016 and occasionally accounted for more than 100 ppbv of monthly mean surface CO and over 20 µg m−3 of monthly mean PM2.5 in the Northwest U.S. and Northern California, two regions susceptible to frequent fires. Fire emissions also had implications on air quality compliance. From 1997 to 2016, fire emissions increased surface 8-hour O3 standard exceedances by 10% and 24-hour PM2.5 exceedances by 33% over CONUS.
The Urban–Rural Heterogeneity of Air Pollution in 35 Metropolitan Regions across China
(MDPI, 2020-07-19) Han, Wenchao; Li, Zhanqing; Guo, Jianping; Su, Tianning; Chen, Tianmeng; Wei, Jing; Cribb, Maureen
Urbanization and air pollution are major anthropogenic impacts on Earth’s environment, weather, and climate. Each has been studied extensively, but their interactions have not. Urbanization leads to a dramatic variation in the spatial distribution of air pollution (fine particles) by altering surface properties and boundary-layer micrometeorology, but it remains unclear, especially between the centers and suburbs of metropolitan regions. Here, we investigated the spatial variation, or inhomogeneity, of air quality in urban and rural areas of 35 major metropolitan regions across China using four different long-term observational datasets from both ground-based and space-borne observations during the period 2001–2015. In general, air pollution in summer in urban areas is more serious than in rural areas. However, it is more homogeneously polluted, and also more severely polluted in winter than that in summer. Four factors are found to play roles in the spatial inhomogeneity of air pollution between urban and rural areas and their seasonal differences: (1) the urban–rural difference in emissions in summer is slightly larger than in winter; (2) urban structures have a more obvious association with the spatial distribution of aerosols in summer; (3) the wind speed, topography, and different reductions in the planetary boundary layer height from clean to polluted conditions have different effects on the density of pollutants in different seasons; and (4) relative humidity can play an important role in affecting the spatial inhomogeneity of air pollution despite the large uncertainties.
Wildfire Smoke Particle Properties and Evolution, From Space-Based Multi-Angle Imaging II: The Williams Flats Fire during the FIREX-AQ Campaign
(MDPI, 2020-11-21) Junghenn Noyes, Katherine T.; Kahn, Ralph A.; Limbacher, James A.; Li, Zhanqing; Fenn, Marta A.; Giles, David M.; Hair, Johnathan W.; Katich, Joseph M.; Moore, Richard H.; Robinson, Claire E.; Sanchez, Kevin J.; Shingler, Taylor J.; Thornhill, Kenneth L.; Wiggins, Elizabeth B.; Winstead, Edward L.
Although the characteristics of biomass burning events and the ambient ecosystem determine emitted smoke composition, the conditions that modulate the partitioning of black carbon (BC) and brown carbon (BrC) formation are not well understood, nor are the spatial or temporal frequency of factors driving smoke particle evolution, such as hydration, coagulation, and oxidation, all of which impact smoke radiative forcing. In situ data from surface observation sites and aircraft field campaigns offer deep insight into the optical, chemical, and microphysical traits of biomass burning (BB) smoke aerosols, such as single scattering albedo (SSA) and size distribution, but cannot by themselves provide robust statistical characterization of both emitted and evolved particles. Data from the NASA Earth Observing System’s Multi-Angle Imaging SpectroRadiometer (MISR) instrument can provide at least a partial picture of BB particle properties and their evolution downwind, once properly validated. Here we use in situ data from the joint NOAA/NASA 2019 Fire Influence on Regional to Global Environments Experiment-Air Quality (FIREX-AQ) field campaign to assess the strengths and limitations of MISR-derived constraints on particle size, shape, light-absorption, and its spectral slope, as well as plume height and associated wind vectors. Based on the satellite observations, we also offer inferences about aging mechanisms effecting downwind particle evolution, such as gravitational settling, oxidation, secondary particle formation, and the combination of particle aggregation and condensational growth. This work builds upon our previous study, adding confidence to our interpretation of the remote-sensing data based on an expanded suite of in situ measurements for validation. The satellite and in situ measurements offer similar characterizations of particle property evolution as a function of smoke age for the 06 August Williams Flats Fire, and most of the key differences in particle size and absorption can be attributed to differences in sampling and changes in the plume geometry between sampling times. Whereas the aircraft data provide validation for the MISR retrievals, the satellite data offer a spatially continuous mapping of particle properties over the plume, which helps identify trends in particle property downwind evolution that are ambiguous in the sparsely sampled aircraft transects. The MISR data record is more than two decades long, offering future opportunities to study regional wildfire plume behavior statistically, where aircraft data are limited or entirely lacking.
Diurnal Variability of Surface Temperature over Lakes: Case Study for Lake Huron
(MDPI, 2021-02-13) Chen, Wen; Pinker, Rachel T.; Rivera, Gerardo; Hook, Simon
The significance of the diurnal variability of Lake Surface Temperature (LST) has been recognized; yet, its magnitude in terms of spatial and temporal variability is not well known. Attempts have been made to derive such information from satellites at a high spatial resolution; however, most have been made from polar orbiting satellites that sample only twice per day. We have developed an approach to derive such information from geostationary satellites at an hourly time scale and at a spatial resolution of about 5 km. The approach to derive LST uses the Radiative Transfer for TIROS Operational Vertical Sounder (TOVS) (RTTOV) model driven by the Modern-Era Retrospective analysis for Research and Applications (MERRA)-2 information. The methodology has been implemented over Lake Huron for about six years. We present the results of the evaluation against various independent satellite products and demonstrate that there is a strong diurnal variability in the skin temperature over the lake and that the lowest and highest values, as derived twice per day from polar orbiting satellites, may not represent the magnitude of the Diurnal Temperature Range (DTR).