N-METHYL-4-PICOLINIUM IODIDE ESTERS AS VISIBLE LIGHT PHOTOREMOVABLE PROTECTING GROUPS FOR CARBOXYLIC ACIDS

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dc.contributor.advisorFalvey, Daniel E.en_US
dc.contributor.authorKunsberg, David Josephen_US
dc.contributor.departmentChemistryen_US
dc.contributor.publisherDigital Repository at the University of Marylanden_US
dc.contributor.publisherUniversity of Maryland (College Park, Md.)en_US
dc.date.accessioned2015-09-18T06:04:40Z
dc.date.available2015-09-18T06:04:40Z
dc.date.issued2015en_US
dc.description.abstractFacile photorelease of carboxylic acids is performed through charge-transfer excitation of N-methyl-4-picolinium iodide esters. Photolysis reactions are carried out under mild, biphasic solvent conditions using a household LED lamp. Release is quantified by 1H NMR analysis and carboxylic acid release is reported in high yields. The viability of this method for synthetic chemistry is demonstrated through a macroscale photolysis. Additionally, the potential for solvent-independent NAP ester charge-transfer photolysis is explored.en_US
dc.identifierhttps://doi.org/10.13016/M2F347
dc.identifier.urihttp://hdl.handle.net/1903/17122
dc.language.isoenen_US
dc.subject.pqcontrolledChemistryen_US
dc.subject.pqcontrolledPhysical chemistryen_US
dc.subject.pquncontrolledCarboxylic Acid Releaseen_US
dc.subject.pquncontrolledCharge Transfer Complexen_US
dc.subject.pquncontrolledNAP Estersen_US
dc.subject.pquncontrolledPhotochemistryen_US
dc.subject.pquncontrolledPhotoremovable Protecting Groupsen_US
dc.titleN-METHYL-4-PICOLINIUM IODIDE ESTERS AS VISIBLE LIGHT PHOTOREMOVABLE PROTECTING GROUPS FOR CARBOXYLIC ACIDSen_US
dc.typeThesisen_US

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