Effects of seawater Sr/Ca on coral paleothermometry in the Florida Keys and Virgin Islands revealed by multi-year continuous monitoring

dc.contributor.advisorKilbourne, Kelly Hen_US
dc.contributor.advisorSchijf, Johanen_US
dc.contributor.authorHughes, Hunter Passmanen_US
dc.contributor.departmentMarine-Estuarine-Environmental Sciencesen_US
dc.contributor.publisherDigital Repository at the University of Marylanden_US
dc.contributor.publisherUniversity of Maryland (College Park, Md.)en_US
dc.date.accessioned2021-02-13T06:30:44Z
dc.date.available2021-02-13T06:30:44Z
dc.date.issued2020en_US
dc.description.abstractCoral skeletal Sr/Ca is a widely applied proxy indicator for tropical sea surface temperature (SST) because the elemental ratio in coral aragonite is influenced by both SST and seawater Sr/Ca. Application of the methodology assumes that seawater Sr/Ca is a constant in coral reef environments, and the ratio can be used to solve for paleotemperatures based upon an established coral Sr/Ca – SST relationship. This study tests that assumption by documenting seawater Sr/Ca variability in the Florida Keys and in the U.S. and British Virgin Islands using continuous osmotic pumps. Samples are analyzed for Sr/Ca using a novel method via Inductively Coupled Plasma – Atomic Emission Spectrometry. While mean seawater Sr/Ca did not vary significantly between sites, all sites exhibited significant annual variability (~0.5 – 0.1 mmol/mol), with the greatest variability observed in locations most impacted by freshwater discharge. These findings correspond to large temperature offsets (>2 degrees Celsius) in standard coral Sr/Ca-based SST reconstructions.en_US
dc.identifierhttps://doi.org/10.13016/s6bo-hxpk
dc.identifier.urihttp://hdl.handle.net/1903/26699
dc.language.isoenen_US
dc.subject.pqcontrolledPaleoclimate scienceen_US
dc.subject.pqcontrolledChemical oceanographyen_US
dc.titleEffects of seawater Sr/Ca on coral paleothermometry in the Florida Keys and Virgin Islands revealed by multi-year continuous monitoringen_US
dc.typeThesisen_US

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