VOLUMETRIC SOLAR ABSORBING FLUIDS AND THEIR APPLICATIONS IN TWO-PHASE THERMOSYPHON

Abstract

A two-phase thermosyphon is a passive system utilizing gravity to transfer working fluids. The working fluids of a two-phase thermosyphon must undergo vaporization and condensation in the same system. Two-phase thermosyphons can also be used as solar collectors. Traditional solar collectors utilize surface absorbers to convert incident solar radiation into thermal energy, but those systems feature a large temperature difference between the surface absorbers and heat transfer fluids, resulting in a reduction in the overall thermal efficiency. Volumetric solar absorbing fluids serve both as solar absorbers and heat transfer fluids, therefore significantly improving the overall efficiency of solar collectors. Comparing to pure fluids, nanofluids possess both enhanced thermal conductivity and solar absorption capacity as volumetric absorbing fluids. Nanofluids, when serving as volumetric solar absorbing fluids, are so far reported to work only at relatively low temperatures and in a single-phase heat transfer regime due to stability issue. This research investigates the possibility of using nanofluids, especially graphene oxide (GO) nanofluids, as volumetric solar absorbing fluids in two-phase thermosyphons. Despite their reputation as both stable and solar absorptive among nanofluids, graphene oxide nanofluids still deteriorate quickly under boiling-condensation processes (~100 °C). The solar transmittance of the GO nanofluids declines from 38 to 4%, during the first 24 h of testing. Further investigation shows that the stability deterioration is caused by the thermal reduction of GO nanoparticles, which mainly featured with de-carboxylation and de-hydroxylation. A commercial dye named acid black 52, when dissolved in water, exhibits great broadband solar absorption properties and excellent stability. It remains stable for over 199 days in two-phase thermosyphon, and their transmittance in solar spectral region varies less than 9%. The stability of acid black 52 aqueous solution is further confirmed with the 191-day enhanced radiation test, as it shows less than 5% transmittance change in solar spectral region.