Composites have become a integral part of the structure of airplanes, and their use within aircraft continues to grow as composites continue to improve. While polymer composites are an improvement in many facets to traditional airspace materials, their flammability is something called into question. The work performed for this study was to create a pyrolysis model for a particular aerospace composite, IM7 graphite fiber with Cytec 5250-4 Bismaleimide matrix (BMI), and three innovative composite barrier coatings that could be applied to the BMI to potentially improve its performance in fire scenarios. The composites were all tested individually, in a series of milligram-scale tests, and the test results were inversely analyzed to determine stoichiometry, chemical kinetics, and thermodynamics of their thermal decomposition and combustion. Gram-scale experiments using the Controlled Atmosphere Pyrolysis Apparatus II (CAPA II) were performed on the BMI by itself and then again with one of each of the composite barrier coatings applied in a defined thickness. This data were inversely analyzed to define the thermal conductivity of the sample and resolve it’s emissivity. It was found after fully defining a pyrolysis model for each composite material that the composite barrier coatings did not provide any benefit to the base composite BMI, and only added more fuel load which in turn contributed to a increase in heat release rate when computational simulations were run to mimic a airplane fuel fire.