A. James Clark School of Engineering
Permanent URI for this communityhttp://hdl.handle.net/1903/1654
The collections in this community comprise faculty research works, as well as graduate theses and dissertations.
Browse
1554 results
Search Results
Item Battery Studies with Particular Reference to Organic Depolarizers(1955) Monson, William L.; Huff, W. J.; Chemical Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, MD)Since Volta's invention of the first primary cell, using silver and zinc, numerous other cell combinations have been studied, covering a wide variety of anode and cathode materials. The latter have included both inorganic and organic substances capable of electrochemical reduction, although, historically, organic cathode materials have received very much less attention than the inorganic. It was the purpose of this investigation to study the actual behavior of a selected number of quinones as depolarizers in primary cells. Performance of experimental cells was compared with cells of the usual dry cell composition but of the same size and construction as cells of experimental composition. The results show that certain substituted anthraquinones possess good depolarizing ability as measured by discharge voltage and coulombic capacity. Energy output in some cases was higher than that of the manganese dioxide control cells (zinc anodes in all cases) because of higher effective coulombic capacities. A qualitative study of the effect of substituents on the discharge voltages of various quinones showed that cell working voltages were much more sensitive to quinone substitution than were the calculated reversible potentials. Also, in the case of nitro-substituted anthraquinones more coulombic capacity was obtained than could be accounted for by the simple reduction to the corresponding hydroquinone. The possibility of a reduction of the nitro-group of this compound was considered. Substances investigated were benzoquinone, naphthoquinone, anthraquinone, and certain of their derivatives, using various electrolytes. The size of the experimental cells was such that about 0.2 gram of the various depolarizers could be studied conveniently.Item Hinge-Bill Orientation Techniques for Automated Oyster Processing(1977) Gird, John; Wheaton, F.W.; Bioengineering; Digital Repository at the University of Maryland; University of Maryland (College Park, MD)The width and thickness dimensions of oysters and an inclined V-shaped trough were studied as means for achieving end orientation. Two series of experiments were conducted on 2,430 oysters sampled from three different locations in the Chesapeake Bay. Both width and thickness were measured every 0.2 inch along the oyster length from the hinge to the bill end. A width to thickness ratio was found to be the best dimensional combination for distinguishing between the hinge and bill ends. Less than 0.50 percent of all oysters failed the ratio test conditions. Statistical analysis on five width to thickness ratio tests with failure rates between 0.25 and 0.49 percent showed there to be no differences in the percent oyster failure over all bars and across all tests. Results indicate that comparable oyster orienting efficiencies can be attained by width to thickness ratios with orienting points located 0.4 to 1.0 inches in from the oyster ends. Negative results occurred when an inclined V-shaped trough was used for orienting oysters. There were significant differences in the proportion of hinge and bill leading oysters exiting the trough for each trough loading position over all bars and oyster axes. The tendency for the oyster axes to behave differently explained some of the differences in the trough's orienting efficiency. However, there were no significant relationships between orienting efficiency and oyster axes.Item Microwave Nonlinearities in Photodiodes(1994) Williams, Keith Jake; Dagenais, Mario; Electrical & Computer Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, MD)The nonlinearities in p-i-n photodiodes have been measured and numerically modeled. Harmonic distortion, response reduction, and sinusoidal output distortion measurements were made with two singlefrequency offset-phased-locked Nd: YAG lasers, which provided a source dynamic range greater than 130 dB, a 1 MHz to 50 GHz frequency range, and optical powers up to 10 mW. A semi-classical approach was used to solve the carrier transport in a one-dimensional p-i-n photodiode structure. This required the simultaneous solution of three coupled nonlinear differential equations: Poisson's equation and the hole and electron continuity equations. Space-charge electric fields, loading in the external circuit, and absorption in undepleted regions next to the intrinsic region all contributed to the nonlinear behavior described by these equations. Numerical simulations were performed to investigate and isolate the various nonlinear mechanisms. It was found that for intrinsic region electric fields below 50 kV/cm, the nonlinearities were influenced primarily by the space-charge electric-field-induced change in hole and electron velocities. Between 50 and 100kV/cm, the nonlinearities were found to be influenced primarily by changes in electron velocity for frequencies above 5 GHz and by p-region absorption below 1 GHz. Above 100 kV/cm, only p-region absorption could explain the observed nonlinear behavior, where only 8 to 14 nm of undepleted absorbing material next to the intrinsic region was necessary to model the observed second harmonic distortions of -60 dBc at 1 mA. Simulations were performed at high power densities to explain the observed response reductions and time distortions. A radially inward component of electron velocity was discovered, and under certain conditions, was estimated to have the same magnitude as the axial velocity. The model was extended to predict that maximum photodiode currents of 50 mA should be possible before a sharp increase in nonlinear output occurs. For capacitively-limited devices, the space-charge-induced nonlinearities were found to be independent of the intrinsic region length, while external circuit loading was determined to cause higher nonlinearities in shorter devices. Simulations indicate that second harmonic improvements of 40 to 60 dB may be possible if the photodiode can be fabricated without undepleted absorbing regions next to the intrinsic region.Item Experimental Evaluation of Circulation Control Aerodynamics on a Cylindrical Body(1987) Ngo, Hieu Thien; Chopra, Inderjit; Aerospace Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, MD)In this study, an experimental investigation is conducted on a two-dimensional circulation control cylinder with blowing taking place from a single spanwise slot to determine its aerodynamic characteristics. The results include detailed pressure distributions (both chordwise and spanwise) for a range of momentum coefficients and slot locations. The measured results showed that the lift coefficients up to 4.8 were produced at momentum coefficients of 0.14 in a turbulent flow condition. The experimental results of lift coeffficients Were correlated satisfactorily with analytical results. The surface flow patterns were observed using the oil and smoke techniques. Also flow field surveys of the model Were obtained using total pressure, yaw and pitch probes. A color video display technique was used to present the results of the flow field surveys. Based on this evidence, a flow field model of the circulation control cylinder is presented.Item ENGINEERING THE B1 DOMAIN OF STREPTOCOCCAL PROTEIN G: STRUCTURAL INVESTIGATIONS BY MULTlDIMENSIONAL HETERONUCLEAR NMR(2000) Frank, Mary Kirsten; Thirumalai, Devarajan; Institute for Physical Science and Technology; Digital Repository at the University of Maryland; University of Maryland (College Park, MD)The B1 domain of streptococcal protein G provides a well-characterized system for structural investigations of proteins. In this thesis, the urea-unfolded state has been characterized, the tolerance towards hydrophobic substitutions in the core has been surveyed, the hydrogen exchange behavior of the backbone amides has been elucidated, and structural information on a tetrameric mutant of this domain has been gathered. The chemical shifts of the urea-unfolded state were assigned. The secondary chemical shifts, the 3JHNa coupling constants and the short-range NOEs gave no indication of residual structure. Measurement of the backbone 15N relaxation parameters revealed a region of restricted motion in the β3- β4 turn of the native protein. Motion in the rest of the protein was uniform, with the exception of 3-4 residues at either end of the chain. A series of hydrophobic substitutions were made in the hydrophobic core. The resulting mutants were assayed for stability and overall fold . The core of the protein is particularly sensitive to substitutions at position 26. One of the mutants was unable to adopt the GB1 fold and optimized its stability by adopting a homotetrameric form. Hydrogen exchange in the backbone amides was measured at 25 °C. Rates of hydrogen exchange were inversely correlated with burial of the amide nitrogen. The slow-exchanging backbone amides did not correlate with the hydrogen bonds formed early in protein folding. Hydrogen exchange rates from NH to ND and from ND to NH were similar. The ratio between these two rates does not correlate with any obvious physical parameters of the hydrogen bonds. Chemical shifts for the tetrameric mutant (HS#124) were determined using three-dimensional heteronuclear NMR techniques. Measurement of the backbone dynamics revealed a highly flexible region between positions 8 and 22. The secondary structure and β-sheet interactions of this mutant were characterized. The β-sheet interactions were intermolecular and only one of the three β-strand pairings was similar to the β-strand pairings found in wild type GB1 . The novel pairing is between β1 of one monomer and β1 of another monomer and a shift in register is observed for the β3-β4 pairing.Item Predicting the Ignition Time and Burning Rate of Thermoplastics in the Cone Calorimeter(1995) Hopkins, Donald Jr.; Quintiere, James G.; Fire Protection Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, MD)Ignition and burning rate data are developed for Nylon 6/6, Polyethylene, and Polypropylene in a Cone Calorimeter heating assembly. The objective is to examine a testing protocol that leads to the prediction of ignition and burning rate for thermoplastics from Cone data. The flame heat flux is not measured, but is inferred from Cone data. The constancy of the flame heat flux for thermoplastics in the Cone calorimeter is due to the geometry of the flame. The burning rate model is shown to yield good accuracy in comparison to measured transient values. Ignition and burning rate data are developed for Redwood and Red Oak in a Cone Calorimeter heating assembly. Measurements of the flame plus external heat flux are presented. The data is intended to be used for future work to develop a testing protocol and burning rate model for charring materials.Item The Determination of Preferred Orientation in Rolled Electrical Steels Using Single Diffraction of Neutrons(1963) Eugenio, Manuel; Duffey, Dick; Nuclear Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, MD)Preferred orientation in rolled electrical steels has been determined using single diffraction of neutrons from the University of Maryland pool-type nuclear reactor (DMR) operating at 10 KW thermal . X-rays are used extensively to determine preferred orientations in metallic wires and rolled sheets, but X-rays suffer the disadvantage of high absorption and cannot be used effectively on thick samples without chemical or mechanical treatment which ultimately results in the destruction of the samples. The use of reactor neutrons for this purpose is believed to offer particular advantages such as the use of thicker samples and wider beams. To this end, neutrons from the UMR were scattered directly from metallic sheet samples to obtain diffraction patterns from which preferred orientations of the crystallographic axes could be deduced. The neutron diffraction data were obtained in the form of : 1) Maxwellian curves; and 2) rocking curves. To obtain the first type of curve, the sample and neutron detector were rotated at a 1-to-2 angular ratio, respectively, and the diffraction pattern was essentially the Maxwellian neutron energy distribution. From the maximum of the Maxwellian curve, the crystallographic plane mainly responsible for the reflection was calculated; from this, the main orientation was deduced. For the second type of curve, the sample was rocked back and forth, with the neutron detector fixed, and the resulting pattern was used to infer the variation of a given crystallographic direction about its main orientation. The results of this study, particularly on grain-oriented and cube-textured silicon-iron (Si-Fe) alloy sheets demonstrate that single diffraction techniques can be used to determine preferred orientation in highly oriented materials. The results on Si-Fe sheets described as non-oriented indicate the possibility that these techniques may be applicable to ordinary rolled metallic sheets, which are not highly oriented.Item Stress-Controlled Versus Strain-Controlled Triaxial Testing of Sand(1994) Alqutri, Samir Ahmed; Goodings, Deborah J.; Civil Engineering; University of Maryland (College Park, Md); Digital Repository at the University of MarylandThe purpose of this research was to compare the strength characterizations of Mystic White Silica Sands using stress-controlled loading versus strain-controlled loading in a standard compression triaxial tests. To this end one hundred sixty-six tests were conducted involving two types of quartz sand, one fine MWSS45 and one medium coarse MWSS18 , tested at three low to intermediate confining stresses of 14 kN/m2, 28 kN/m2 and 55 kN/m2 with only one specimen diameter size of 71.1 mm. Of the one hundred sixty-six tests, eighty-six were stress-controlled tests and eighty were strain-controlled tests. All specimens were dry, but both loose and dense specimens were tested. The results were evaluated individually and as group. Comparison of the two types of loading tests were evaluated for repeatability, stress-strain characteristics and strength parameters. The plots show that stress-controlled loading in general gives more reproducible results with smoother. steeper stress-strain plot s and a larger average deviator stresses at failure than strain-controlled loading at all three levels of confining stresses for both sands. This results in somewhat larger values of Φ' . Stress-controlled specimens were stiffer and failed with a clear cut failure surface while strain-controlled specimens mostly barreled.Item Interface Broadening and Radiation Enhanced Diffusion During Sputter Depth Profiling(1988) Chambers, George Paul; Rousch, Marvin; Chemical and Nuclear Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md)The process of ion bombardment of solids has been investigated using Monte Carlo Computer Code simulation in conjunction with ultra-high vacuum experimental techniques. The computer code EVOLVE has been used to study the shape of the resultant collision cascade as well as the origins of sputtered particles while experimental studies of interface regions have been performed to elucidate the physical processes occurring during sputtering. The EVOLVE code models the target as an amorphous multicomponent semi-infinite solid. The target composition during ion bombardment is simulated. The study concludes that recoil activity grows in size and tends to move away from the target surface with increasing time. It is further concluded that the majority of sputtered atoms originate from early generations and are produced from sites near the entry point of the bombarding ion. Low energy noble gas ion bombardment of thin-film Cr/Ni multilayered structures has been performed in conjunction with Auger electron spectroscopy under UHV conditions. An accurate, reliable, and systematic parameterization of the interface region between metallic layers is presented. It is concluded from this study that the extent of the distortion of the interface region due to ion induced broadening is dependent not only on the material system used but on the experimental conditions employed as well. Lastly, radiation enhanced diffusion (RED) has been studied using Ag/Ni thin-film multilayered structures. A physical mathematical model of the radiation broadened Ag layer, capable of successfully deconvoluting the contributions to interface broadening due to RED from those due to cascade mixing and microstructure development, is presented and shown to be an accurate characterization of the interface region. It is concluded from the application of this model that RED can contribute substantially to interface broadening in multicomponent systems with low activation energies of diffusion. It is further concluded from this study that elevated temperatures, sustained during the depth profiling process, can cause the effects of RED to subside dramatically. This phenomenon is most probably due to the dispersion of complex defects responsible for the RED process.Item Physics-of-Failure Methodology for Accelerated Thermal Cycling of LCC Solder Joints(1995) Rothman, Timothy Paul; Dasgupta, Abhijit; Mechanical Engineering; University of Maryland (College Park, Md); Digital Repository at the University of MarylandThis research presents a case study were existing physics-of-failure models and Bayesian statistical methods are used in conjunction to quantify the test-time compression achieved during accelerated temperature cycling tests on leadless solder joints. Different combinations of substrate materials and package styles are evaluated with physics-of-failure models and calculable information is obtained from a relatively small population of test specimens under accelerated stresses, because the critical variables are identified, and their influences on the stress magnitude are quantified. Bayesian statistical analysis is employed to obtain an acceleration transform, determine the confidence on the calculations, and determine which outliers are contaminating the database. In addition to accelerating the stress levels, the total test time is further minimized by tailoring the stress drivers in each sample such that multiple stress levels can be achieved under a single loading, which eliminates the need for repeating the test at multiple load levels. This research presents the details of how the models and statistical methods are applied, the results of evaluating different material combinations and package styles, problems encountered during the test, and a summary of the acceleration transforms obtained from the test. Analytical predicative models for life predictions are essential and will obviously result in significant savings of cost and time. The methods used in this are general enough to be applied to screening, qualification, and reliability enhancement tests of a wide range of new or existing electronics assemblies.