Mechanical Engineering
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Item Nanocomposite and Soluble Energetic Additives for Burning Enhancement of Hydrocarbon Fuels(2017) Guerieri, Philip Michael; Zachariah, Michael R; Mechanical Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Metallizing liquid fuels and propellants to improve performance of energy conversion and propulsion systems has been of interest for decades but past attempts to do so using micron-sized metal powders demonstrated inefficient combustion and low burning rates of modified hydrocarbons. “Nanofuels” composed of energetic nanoparticles like nanoaluminum suspended in liquid fuels have slowly emerged in scientific research over the last two decades with promising results. Increased burning rates, lower ignition delays, and high suspension stabilities compared to slurry fuels of micron-sized particles have been demonstrated; however, the effects of various energetic nanoparticles on the combustion of hydrocarbons remain poorly understood while particle agglomeration remains a performance-limiting problem. The research in this dissertation identifies strategies for inclusion of aluminum into hydrocarbons which promote combustion performance in a free-droplet burning experiment developed herein. Considering the low burning rates which plagued micron particle-based slurry fuels, specific attention is paid to characterizing and understanding effects on droplet burning rate constants. Classical characterization of this metric based on the D-squared-law for isolated droplet combustion is found to be unsuitable with heterogeneous energetic additives and thusly an original scheme for experimental approximation of burning rate constant is set forth. Several beneficial strategies for aluminum inclusion and burning rate enhancement are studied including co-addition of nanoaluminum with the gas generator nitrocellulose (NC), dissolution of Al-containing molecules including organometallic clusters into hydrocarbons, and burning rate enhancements realized with oxygen-carrying nanoparticle co-additives. Arguably the most impactful strategy identified however is the preassembly of active nanoparticles into NC-bound clusters or controlled agglomerates, termed “mesoparticles” (MPs), by electrospray which drastically improves droplet burning rate increases and nanofuel suspension stabilities observed compared to nanofuels of unassembled nanoparticles. Mechanisms of the various additives studied are probed with a variety of diagnostic techniques and burning rate enhancements are linked to physical effects of droplet disruptions on the diffusion-limited burning droplet system. The MP architecture causes a feedback loop between physical disruptions by gas liberation from droplets, transport of active additives into the flame where they react, and promotion of further gas evolution repeating and accelerating this process.Item Electrostatic Gas-Liquid Separation from High Speed Streams--Application to Advanced On-Line/On- Demand Separation Techniques(2009) Alshehhi, Mohamed Saeed; Ohadi, Michael M; Mechanical Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)The separation of suspended droplets from gases has been one of the basic scientific and technical problems of the industrial era and this interest continues. Various industrial applications, such as refrigeration and HVAC systems, require control of fine droplets concentrations in moving gaseous mediums to maintain system functionality and efficiency. Separating of such fine droplets can be achieved using electrostatic charging as implemented in electrostatic precipitators (ESPs). They use electrostatic force to charge and collect solid particles. The objective of the present work was to study the feasibility of using wiretube electrostatic separator on the removal of fine water and oil droplets from air stream based on corona discharge ionization process. A parametric study was conducted to find key parameters affecting the separation process. This goal was approached by simulating the charging and separation phenomena numerically, and then verifying the modeling findings through experiments. The numerical methodology simulated the highly complex interaction between droplets suspended in the flow and electrical field. Two test rigs were constructed, one for air-water separation and the other for air-oil separation. A wiretube electrostatic separator was used as the test section for both test rigs. The separation performance was evaluated under different electric field and flow conditions. Finally, based on the results, a novel air-water separator prototype was designed, fabricated and tested. The numerical modeling results qualitatively showed acceptable agreement with the experimental data in terms of the trend of grade efficiency based on droplets size. Both numerical modeling results and experimental data showed that with a proper separator design, high separation efficiency is achievable for water and oil droplets. Based on the experimental data, at flow velocity of 5 m/s and applied voltage of 7.0 kV, the maximum separation efficiency for water and oil was 99.999 % and 96.267 %, respectively. The pressure drop was as low as 100 Pa and maximum power consumption was 12.0 W.