Geology

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    Developing Sensor Proxies for “Chemical Cocktails” of Trace Metals in Urban Streams
    (MDPI, 2020-10-14) Morel, Carol J.; Kaushal, Sujay S.; Tan, Maggie L.; Belt, Kenneth T.
    Understanding transport mechanisms and temporal patterns in the context of metal concentrations in urban streams is important for developing best management practices and restoration strategies to improve water quality. In some cases, in-situ sensors can be used to estimate unknown concentrations of trace metals or to interpolate between sampling events. Continuous sensor data from the United States Geological Survey were analyzed to determine statistically significant relationships between lead, copper, zinc, cadmium, and mercury with turbidity, specific conductance, dissolved oxygen, and discharge for the Hickey Run, Watts Branch, and Rock Creek watersheds in the Washington, D.C. region. We observed a significant negative linear relationship between concentrations of Cu and dissolved oxygen at Rock Creek (p < 0.05). Sometimes, turbidity had significant positive linear relationships with Pb and Hg concentrations. There were negative or positive linear relationships between Pb, Cd, Zn, and Hg and specific conductance. There also appeared to be relationships between watershed areal fluxes of Pb, Cu, Zn, and Cd in streams with turbidity. Watershed monitoring approaches using continuous sensor data have the potential to characterize the frequency, magnitude, and composition of pulses in concentrations and loads of trace metals, which could improve the management and restoration of urban streams.
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    HYDROLOGICAL, BIOLOGICAL, AND GEOCHEMICAL RELATIONSHIPS AMONG CARBON, NITROGEN, AND BASE CATIONS IN RESTORED AND UNRESTORED URBAN STREAMS
    (2017) Doody, Thomas Rossiter; Kaushal, Sujay S; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)
    Urban infrastructure changes hydrologic flowpaths of water into streams and alters ecosystem function. Geomorphic stream restoration is commonly implemented to stabilize channels, while ecosystem function, and nutrient retention are of secondary concern. This research investigated whether restoration alone significantly influences N uptake in streams and if significant hydrological, biological, and geochemical relationships exist between coupled biogeochemical cycles that should be considered when evaluating restorations. Carbon, nitrogen, base cations, and stream metabolism dynamics were investigated in six urban streams in Baltimore,MD. Nitrate tracer injections were used to quantify nitrogen uptake dynamics. Results did not show significant differences in nitrogen uptake based on restoration. Organic carbon, inorganic carbon, and nitrogen each have distinct but interrelated hydrological, biological, and geochemical relationships across all sites. These dynamic relationships may also significantly affect nitrogen uptake, but more spatiotemporal data are needed to quantify and understand variability among restored and unrestored sites.