Geology
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Item TREE TRADE-OFFS IN STREAM RESTORATION: IMPACTS ON RIPARIAN GROUNDWATER QUALITY(2020) Wood, Kelsey Lynn; Kaushal, Sujay; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Restoring urban degraded stream channels in efforts to improve water quality often includes substantial alteration of the riparian zone which can require the removal of mature trees. This study assessed the impact of tree removal on riparian groundwater quality over time and space using a chronosequence of restored sites ages 5-20 years and well transects along groundwater flow paths. The response of multiple elements through various hydrologic conditions was evaluated by monitoring dissolved concentrations of inorganic carbon, organic carbon, total nitrogen, boron, calcium, copper, iron, potassium, magnesium, manganese, sodium, and sulfur over a 2-year period. Results revealed that concentrations of most bioreactive and organically derived elements were significantly elevated and increase along flowpaths at recently restored sites.Item Vegetation-Hydrodynamic Interactions and the Stability of Channel Inlets of Tidal Freshwater Wetlands, Chesapeake Bay System(2014) Statkiewicz, Anna; Prestegaard, Karen L; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)To maintain elevation, deposition of mineral and organic sediment in tidal freshwater wetlands (TFWs) must outweigh losses due to sea-level rise, erosion, decomposition, and compaction. Sediment loads into tidal marshes are controlled by inlet size and sediment supply, but interactions among vegetation, hydraulics, and geomorphology affect sediment retention. This study focused on these interactions in TFW inlets partially covered by aquatic vegetation (N.luteum, Z.aquatica, and H.verticullata). Measurements of hydraulic parameters and geomorphic change were correlated with observations of spatial and morphological characteristics for each vegetation type. The aquatic plants grew in significantly different water depths and well-defined platforms formed in areas occupied by emergent vegetation where effective shear stress is lowest. Net annual accretion data indicate an inverse relationship between maximum inlet depth and accretion rate. These results suggest that initial vegetation colonization modifies channel inlet morphology; both vegetation and morphology generate the shear stress distributions, which maintain channel form.Item Geomorphic, hydraulic, and biogeochemical controls on nitrate retention in tidal freshwater marshes(2012) Seldomridge, Emily; Prestegaard, Karen; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Tidal freshwater wetlands are ideal sites for nitrate retention because of their position within the landscape (near the head of tide); they receive water, discharge, nutrients (N and P), and sediment loads directly from contributing watersheds. Nitrate retention (the difference between nitrate inputs and outputs in an ecosystem), however, is difficult to predict due to the complex interactions between flow processes and the multiple retention processes. The goal of the study was to evaluate both external and internal controls on nitrate retention, and to determine whether scaling procedures could be identified to estimate nitrate retention for an entire ecosystem. The external controls included temperature, dissolved oxygen concentrations, and incoming nitrate concentrations. Internal controls are the interactions among geomorphic, hydrologic, and biological systems within individual marshes that influence nitrate retention. This study was conducted in the upper Patuxent River Estuary where the ecosystem is composed of hundreds of individual marshes that are connected to the estuary through tidal inlets; marsh inlet geomorphology governs water and nitrate fluxes into the marshes. This study therefore took a mass balance approach to determine geomorphic, hydrologic, and biological influences on nitrate retention. Nitrate retention was measured over a 4-year period in three tidal freshwater wetlands, selected to represent a range of marsh sizes. An examination of the mass balance data suggest that nitrate retention is an outcome of complex interactions among inlet geomorphic characteristics, hydrologic flux, and biogeochemical processes. In cases where nitrate concentrations and temperatures are greater than critical (limiting) values, an emergent behavior in which nitrate retention is a simple function of water volume is observed. The wetland ecosystem is composed of numerous, small wetlands that process a small percentage of total nitrate; approximately 50% of retention is processed by the large marshes that comprise only 4% of the total population, but over 80% of the marsh area; therefore, any processes that affect tidal water volumes in large marshes is likely to affect net nitrate retention. The growth of vegetation in these large channels reduced ecosystem nitrate retention.Item ISOTOPE GEOCHEMISTRY OF ORGANIC SULFUR COMPOUNDS WITH LINKS TO BIOGEOCHEMICAL SULFUR CYCLING AND RADICAL CHEMISTRY(2012) Oduro, Harry Daniel; Farquhar, James; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)your words