Fire Protection Engineering Research Works

Permanent URI for this collectionhttp://hdl.handle.net/1903/1659

Browse

Start date: 2020End date: 2021

Search Results

Now showing 1 - 2 of 2
  • Thumbnail Image
    Item
    Viability of Various Sources to Ignite A2L Refrigerants
    (MDPI, 2020-12-28) Kim, Dennis K.; Sunderland, Peter B.
    Environmental considerations are motivating the adoption of low global warming potential refrigerants. Most of these are mildly flammable, i.e., A2L. Their susceptibility to ignition from various ignition sources is poorly understood, particularly for the stoichiometric and quiescent mixtures that are emphasized here. The viability of fifteen residential ignition sources to ignite four A2L refrigerants is considered. Tests are performed in a windowed chamber with a volume of 26 L. The refrigerants are R-32 (difluoromethane); R-452B (67% R-32, 26% R-1234yf, and 7% pentafluoroethane); R-1234yf (2,3,3,3-tetrafluoropropene); and R-1234ze (1,3,3,3-tetrafluoropropene). Two types of ignition sources are confirmed here to be viable: a resistively heated wire at 740 °C and open flames. When the refrigerant concentration was increased slowly, candle flames and butane flames extinguished before initiating any large deflagrations. Eleven other sources were not viable: a smoldering cigarette, a butane lighter, friction sparks, a plug and receptacle, a light switch, a hand mixer, a cordless drill, a bread toaster, a hair dryer, a hot plate, and a space heater. The difficulty to ignite these refrigerants in air is attributed to their long quenching distances (up to 25 mm). Under some conditions the refrigerants were observed to act as flame suppressants.
  • Thumbnail Image
    Item
    Polyisocyanurate Foam Pyrolysis and Flame Spread Modeling
    (MDPI, 2021-04-13) Chaudhari, Dushyant M.; Stoliarov, Stanislav I.; Beach, Mark W.; Suryadevara, Kali A.
    Polyisocyanurate (PIR) foam is a robust thermal insulation material utilized widely in the modern construction. In this work, the flammability of one representative example of this material was studied systematically using experiments and modeling. The thermal decomposition of this material was analyzed through thermogravimetric analysis, differential scanning calorimetry, and microscale combustion calorimetry. The thermal transport properties of the pyrolyzing foam were evaluated using Controlled Atmosphere Pyrolysis Apparatus II experiments. Cone calorimetry tests were also carried out on the foam samples to quantify the contribution of the blowing agent (contained within the foam) to its flammability, which was found to be significant. A complete pyrolysis property set was developed and was shown to accurately predict the results of all aforementioned measurements. The foam was also subjected to full-scale flame spread tests, similar to the Single Burning Item test. A previously developed modeling approach based on a coupling between detailed pyrolysis simulations and a spatially-resolved relationship between the total heat release rate and heat feedback from the flame, derived from the experiments on a different material in the same experimental setup, was found to successfully predict the evolution of the heat release rate measured in the full-scale tests on the PIR foam.