Hygroscopicity of Cholesterol in Various Organic Solvents

dc.contributor.advisorAsa- Awuku, Akuaen_US
dc.contributor.authorBarati, Farimaen_US
dc.contributor.departmentChemical Engineeringen_US
dc.contributor.publisherDigital Repository at the University of Marylanden_US
dc.contributor.publisherUniversity of Maryland (College Park, Md.)en_US
dc.date.accessioned2019-06-19T05:30:56Z
dc.date.available2019-06-19T05:30:56Z
dc.date.issued2018en_US
dc.description.abstractOrganic aerosols and partially soluble particles can uptake water, form droplets and act as Cloud Condensation Nuclei (CCN). Cholesterol is a well-known organic aerosol. Cholesterol is insoluble in water (<0.002 gram in 100 ml of H2O) but dissolves in organic solvents. In this study, we examine the ability of cholesterol generated in three dilutions of 3 alcohols (ethanol, isopropanol and acetone) to act as CCN. The apparent hygroscopicity, κ, varies over two orders of magnitude, from ~ 0.001 to 0.1. We use statistical analysis of variance (ANOVA) to define significant physical and chemical factors that modify κ. Results show that as volume of water increases, κ changes. However, the type of alcohol does not significantly modify the hygroscopicity. Increases in alcohol concentration decrease droplet surface tension and change aerosol shape. Thus, the apparent κ is corrected with surface tension and shape factor data and estimated to be ~0.028 ± 0.02.en_US
dc.identifierhttps://doi.org/10.13016/bm6i-2p3x
dc.identifier.urihttp://hdl.handle.net/1903/21866
dc.language.isoenen_US
dc.subject.pqcontrolledChemical engineeringen_US
dc.titleHygroscopicity of Cholesterol in Various Organic Solventsen_US
dc.typeThesisen_US

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