Show simple item record

Multiple sulfur isotope fractionations in inorganic aqueous systems

dc.contributor.advisorFarquhar, Jamesen_US
dc.contributor.authorEldridge, Daniel Leeen_US
dc.date.accessioned2016-09-08T05:39:29Z
dc.date.available2016-09-08T05:39:29Z
dc.date.issued2016en_US
dc.identifierhttps://doi.org/10.13016/M2JJ7S
dc.identifier.urihttp://hdl.handle.net/1903/18754
dc.description.abstractNew constraints on isotope fractionation factors in inorganic aqueous sulfur systems based on theoretical and experimental techniques relevant to studies of the sulfur cycle in modern environments and the geologic rock record are presented in this dissertation. These include theoretical estimations of equilibrium isotope fractionation factors utilizing quantum mechanical software and a water cluster model approach for aqueous sulfur compounds that span the entire range of oxidation state for sulfur. These theoretical calculations generally reproduce the available experimental determinations from the literature and provide new constraints where no others are available. These theoretical calculations illustrate in detail the relationship between sulfur bonding environment and the mass dependence associated with equilibrium isotope exchange reactions involving all four isotopes of sulfur. I additionally highlight the effect of isomers of protonated compounds (compounds with the same chemical formula but different structure, where protons are bound to either sulfur or oxygen atoms) on isotope partitioning in the sulfite (S4+) and sulfoxylate (S2+) systems, both of which are key intermediates in oxidation-reduction processes in the sulfur cycle. I demonstrate that isomers containing the highest degree of coordination around sulfur (where protonation occurs on the sulfur atom) have a strong influence on isotopic fractionation factors, and argue that isomerization phenomenon should be considered in models of the sulfur cycle. Additionally, experimental results of the reaction rates and isotope fractionations associated with the chemical oxidation of aqueous sulfide are presented. Sulfide oxidation is a major process in the global sulfur cycle due largely to the sulfide-producing activity of anaerobic microorganisms in organic-rich marine sediments. These experiments reveal relationships between isotope fractionations and reaction rate as a function of both temperature and trace metal (ferrous iron) catalysis that I interpret in the context of the complex mechanism of sulfide oxidation. I also demonstrate that sulfide oxidation is a process associated with a mass dependence that can be described as not conforming to the mass dependence typically associated with equilibrium isotope exchange. This observation has implications for the inclusion of oxidative processes in environmental- and global-scale models of the sulfur cycle based on the mass balance of all four isotopes of sulfur. The contents of this dissertation provide key reference information on isotopic fractionation factors in aqueous sulfur systems that will have far-reaching applicability to studies of the sulfur cycle in a wide variety of natural settings.en_US
dc.language.isoenen_US
dc.titleMultiple sulfur isotope fractionations in inorganic aqueous systemsen_US
dc.typeDissertationen_US
dc.contributor.publisherDigital Repository at the University of Marylanden_US
dc.contributor.publisherUniversity of Maryland (College Park, Md.)en_US
dc.contributor.departmentGeologyen_US
dc.subject.pqcontrolledGeochemistryen_US
dc.subject.pquncontrolledcomputational chemistryen_US
dc.subject.pquncontrolledexplicit solvation modelen_US
dc.subject.pquncontrolledkineticsen_US
dc.subject.pquncontrolledsulfur chemistryen_US
dc.subject.pquncontrolledsulfur isotopesen_US


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record