A. James Clark School of Engineering
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Item Failure Modes, Mechanisms, Effects, and Criticality Analysis of Ceramic Anodes of Solid Oxide Fuel Cells(MDPI, 2018-11-15) Patel, Nripendra K.; Bishop, Sean R.; Utter, Robert G.; Das, Diganta; Pecht, MichaelSolid oxide fuel cells (SOFCs) are a highly efficient chemical to electrical energy conversion devices that have potential in a global energy strategy. The wide adoption of SOFCs is currently limited by cost and concerns about cell durability. Improved understanding of their degradation modes and mechanisms combined with reduction–oxidation stable anodes via all-ceramic-anode cell technology are expected to lead to durability improvements, while economies of scale for production will mitigate cost of commercialization. This paper presents an Ishikawa analysis and a failure modes, mechanisms, effects, and criticality analysis (FMMECA) for all-ceramic anode based SOFCs. FMMECA takes into account the life cycle conditions, multiple failure mechanisms, and their potential effects on fuel-cell health and safety.Item RELIABILITY OF CERAMIC ELECTRODES OF SOLID OXIDE FUEL CELLS(2018) Patel, Nripendra Kumar; Pecht, Michael G; Das, Diganta; Mechanical Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Solid oxide fuel cells (SOFCs) are highly efficient chemical to electrical energy conversion devices that have potential in a global energy strategy. The wide adoption of SOFCs is currently limited by cell durability and manufacturing cost. Ceramic anodes show promise for improved durability and are prominent candidate for electrodes of SOFCs. Ishikawa diagram was developed and a comprehensive failure modes, mechanisms, effects, and criticality analysis (FMMECA) methodology is applied to ceramic anodes of SOFCs to understand possible causes of failure. Despite high conductivity and better performance of conventional ceramic electrodes i.e. strontium-based perovskite electrodes, there is a concern that humidity, especially high humidity and high temperature, during storage can affect the properties prior to installation. Degradation mechanisms which can manifest themselves during storage was found and empirical degradation model was developed to determine the storage specification for strontium-based perovskite electrodes of SOFCs.