A. James Clark School of Engineering

Permanent URI for this communityhttp://hdl.handle.net/1903/1654

The collections in this community comprise faculty research works, as well as graduate theses and dissertations.

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Start date: 2010End date: 2019

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Now showing 1 - 10 of 2351
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    Feedback motion replanning during high-stakes scenario
    (2019) M Jaffar, Mohamed Khalid; Otte, Michael
    This paper proposes a novel algorithm for a quadrotor to replan its motion in the event of one, two or three rotor loss. Further, during the course of its replanned trajectory, the MAV avoids collision with static obstacles including the ground.
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    Simplified Reflection Fabry-Perot Method for Determination of Electro-Optic Coefficients of Poled Polymer Thin Films
    (MDPI, 2011-08-18) Park, Dong Hun; Luo, Jingdong; Jen, Alex K.-Y.; Herman, Warren N.
    We report a simplified reflection mode Fabry-Perot interferometry method for determination of electro-optic (EO) coefficients of poled polymer thin films. Rather than fitting the detailed shape of the Fabry-Perot resonance curve, our simplification involves a technique to experimentally determine the voltage-induced shift in the angular position of the resonance minimum. Rigorous analysis based on optical properties of individual layers of the multilayer structure is not necessary in the data analysis. Although angle scans are involved, the experimental setup does not require a θ-2θ rotation stage and the simplified analysis is an advantage for polymer synthetic efforts requiring quick and reliable screening of new materials. Numerical and experimental results show that our proposed method can determine EO coefficients to within an error of ∼8% if poled values for the refractive indices are used.
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    The Hardness and Strength Properties of WC-Co Composites
    (MDPI, 2011-07-14) Armstrong, Ronald W.
    The industrially-important WC-Co composite materials provide a useful, albeit complicated materials system for understanding the combined influences on hardness and strength properties of the constituent WC particle strengths, the particle sizes, their contiguities, and of Co binder hardness and mean free paths, and in total, the volume fraction of constituents. A connection is made here between the composite material properties, especially including the material fracture toughness, and the several materials-type considerations of: (1) related hardness stress-strain behaviors; (2) dislocation (viscoplastic) thermal activation characterizations; (3) Hall-Petch type reciprocal square root of particle or grain size dependencies; and (4) indentation and conventional fracture mechanics results. Related behaviors of MgO and Al2O3 crystal and polycrystal materials are also described for the purpose of making comparisons.
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    Measurements of True Leak Rates of MEMS Packages
    (MDPI, 2012-03-06) Han, Bongtae
    Gas transport mechanisms that characterize the hermetic behavior of MEMS packages are fundamentally different depending upon which sealing materials are used in the packages. In metallic seals, gas transport occurs through a few nanoscale leak channels (gas conduction) that are produced randomly during the solder reflow process, while gas transport in polymeric seals occurs through the bulk material (gas diffusion). In this review article, the techniques to measure true leak rates of MEMS packages with the two sealing materials are described and discussed: a Helium mass spectrometer based technique for metallic sealing and a gas diffusion based model for polymeric sealing.
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    Decomposition Mechanisms and Kinetics of Novel Energetic Molecules BNFF-1 and ANFF-1: Quantum-Chemical Modeling
    (MDPI, 2013-07-18) Tsyshevsky, Roman V.; Kuklja, Maija M.
    Decomposition mechanisms, activation barriers, Arrhenius parameters, and reaction kinetics of the novel explosive compounds, 3,4-bis(4-nitro-1,2,5-oxadiazol-3-yl)-1,2,5-oxadiazole (BNFF-1), and 3-(4-amino-1,2,5-oxadiazol-3-yl)-4-(4-nitro-1,2,5-oxadiazol-3-yl)-1,2,5-oxadiazole (ANFF-1) were explored by means of density functional theory with a range of functionals combined with variational transition state theory. BNFF-1 and ANFF-1 were recently suggested to be good candidates for insensitive high energy density materials. Our modeling reveals that the decomposition initiation in both BNFF-1 and ANFF-1 molecules is triggered by ring cleavage reactions while the further process is defined by a competition between two major pathways, the fast C-NO2 homolysis and slow nitro-nitrite isomerization releasing NO. We discuss insights on design of new energetic materials with targeted properties gained from our modeling.
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    Dynamic Modeling for the Design and Cyclic Operation of an Atomic Layer Deposition (ALD) Reactor
    (MDPI, 2013-08-19) Travis, Curtisha D.; Adomaitis, Raymond A.
    A laboratory-scale atomic layer deposition (ALD) reactor system model is derived for alumina deposition using trimethylaluminum and water as precursors. Model components describing the precursor thermophysical properties, reactor-scale gas-phase dynamics and surface reaction kinetics derived from absolute reaction rate theory are integrated to simulate the complete reactor system. Limit-cycle solutions defining continuous cyclic ALD reactor operation are computed with a fixed point algorithm based on collocation discretization in time, resulting in an unambiguous definition of film growth-per-cycle (𝑔𝑝𝑐). A key finding of this study is that unintended chemical vapor deposition conditions can mask regions of operation that would otherwise correspond to ideal saturating ALD operation. The use of the simulator for assisting in process design decisions is presented.
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    Lessons Learned from the 787 Dreamliner Issue on Lithium-Ion Battery Reliability
    (MDPI, 2013-09-09) Williard, Nicholas; He, Wei; Hendricks, Christopher; Pecht, Michael
    On 16 January 2013, all Boeing 787 Dreamliners were indefinitely grounded due to lithium-ion battery failures that had occurred in two planes. Subsequent investigations into the battery failures released through the National Transportation Safety Board (NTSB) factual report, the March 15th Boeing press conference in Japan, and the NTSB hearings in Washington D.C., never identified the root causes of the failures—a major concern for ensuring safety and meeting reliability expectations. This paper discusses the challenges to lithium-ion battery qualification, reliability assessment, and safety in light of the Boeing 787 battery failures. New assessment methods and control techniques that can improve battery reliability and safety in avionic systems are then presented.
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    Topography of Photochemical Initiation in Molecular Materials
    (MDPI, 2013-11-15) Aluker, Edward D.; Krechetov, Alexander G.; Mitrofanov, Anatoly Y.; Zverev, Anton S.; Kuklja, Maija M.
    We propose a fluctuation model of the photochemical initiation of an explosive chain reaction in energetic materials. In accordance with the developed model, density fluctuations of photo-excited molecules serve as reaction nucleation sites due to the stochastic character of interactions between photons and energetic molecules. A further development of the reaction is determined by a competition of two processes. The first process is growth in size of the isolated reaction cell, leading to a micro-explosion and release of the material from the cell towards the sample surface. The second process is the overlap of reaction cells due to an increase in their size, leading to the formation of a continuous reaction zone and culminating in a macro-explosion, i.e., explosion of the entire area, covering a large part of the volume of the sample. Within the proposed analytical model, we derived expressions of the explosion probability and the duration of the induction period as a function of the initiation energy (exposure). An experimental verification of the model was performed by exploring the initiation of pentaerythritol tetranitrate (PETN) with the first harmonic of YAG: Nd laser excitation (1,064 nm, 10 ns), which has confirmed the adequacy of the model. This validation allowed us to make a few quantitative assessments and predictions. For example, there must be a few dozen optically excited molecules produced by the initial fluctuations for the explosive decomposition reaction to occur and the life-time of an isolated cell before the micro-explosion must be of the order of microseconds.
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    Control of a Heavy-Lift Robotic Manipulator with Pneumatic Artificial Muscles
    (MDPI, 2014-04-24) Robinson, Ryan M.; Kothera, Curt S.; Wereley, Norman M.
    Lightweight, compliant actuators are particularly desirable in robotic systems intended for interaction with humans. Pneumatic artificial muscles (PAMs) exhibit these characteristics and are capable of higher specific work than comparably-sized hydraulic actuators and electric motors. The objective of this work is to develop a control algorithm that can smoothly and accurately track the desired motions of a manipulator actuated by pneumatic artificial muscles. The manipulator is intended for lifting humans in nursing assistance or casualty extraction scenarios; hence, the control strategy must be capable of responding to large variations in payload over a large range of motion. The present work first investigates the feasibility of two output feedback controllers (proportional-integral-derivative and fuzzy logic), but due to the limitations of pure output feedback control, a model-based feedforward controller is developed and combined with output feedback to achieve improved closed-loop performance. The model upon which the controller is based incorporates the internal airflow dynamics, the physical parameters of the pneumatic muscles and the manipulator dynamics. Simulations were performed in order to validate the control algorithms, guide controller design and predict optimal gains. Using real-time interface software and hardware, the controllers were implemented and experimentally tested on the manipulator, demonstrating the improved capability.
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    Metamaterial Model of Tachyonic Dark Energy
    (MDPI, 2014-02-17) Smolyaninov, Igor I.
    Dark energy with negative pressure and positive energy density is believed to be responsible for the accelerated expansion of the universe. Quite a few theoretical models of dark energy are based on tachyonic fields interacting with itself and normal (bradyonic) matter. Here, we propose an experimental model of tachyonic dark energy based on hyperbolic metamaterials. Wave equation describing propagation of extraordinary light inside hyperbolic metamaterials exhibits 2 + 1 dimensional Lorentz symmetry. The role of time in the corresponding effective 3D Minkowski spacetime is played by the spatial coordinate aligned with the optical axis of the metamaterial. Nonlinear optical Kerr effect bends this spacetime resulting in effective gravitational force between extraordinary photons. We demonstrate that this model has a self-interacting tachyonic sector having negative effective pressure and positive effective energy density. Moreover, a composite multilayer SiC-Si hyperbolic metamaterial exhibits closely separated tachyonic and bradyonic sectors in the long wavelength infrared range. This system may be used as a laboratory model of inflation and late time acceleration of the universe.