Civil & Environmental Engineering
Permanent URI for this communityhttp://hdl.handle.net/1903/2221
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Item Chemical Characterization of Urban Stormwater: Traditional and Emerging Contaminants(Elsevier, 2022-03) Pamuru, Sai Thejaswini; Forgione, Erica; Croft, Kristen; Kjellerup, Birthe V.; Davis, Allen P.Increases in urbanization have led to increased stormwater runoff and mobilization of pollutants from urban watersheds. Discharge of these pollutants often leads to contamination of receiving water bodies. Chemical characterization of urban stormwater is necessary to gain deeper insights into the ecological impacts of urban runoff and to evaluate parameters that influence possible treatment technologies. This study assessed stormwater event mean concentrations and particle size fractions from field studies reported in national/international stormwater quality databases (The National Stormwater Quality and The Best Management Practices databases) and peer-reviewed literature. This characterization of urban stormwater includes statistical evaluation of probability distribution, consideration of dissolved and particulate-bound pollutants and focuses on partitioning and speciation behavior. Solids, nutrients, metals, organic pollutants, and bacterial pathogen indicators were evaluated. A significant fraction of stormwater phosphorus, metals and organic pollutants are particle-bound. Results from the speciation of metals demonstrated that metals are predominantly present as either inner-sphere or electrostatic complexes with dissolved organic matter. This study provides a comprehensive overview of the myriad pollutants found in urban stormwater and provides a starting point for addressing ubiquitous and emerging contaminants. Finally, research needs for further detailed stormwater characterization were identified.Item Interactions and Treatment of Metals in Urban Stormwater(2023) Croft, Kristen; Kjellerup, Birthe V; Davis, Allen P; Civil Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Increasing urbanization and a changing climate will only exacerbate the magnitude of pollution entering our waterways, threatening our drinking water source and aquatic ecosystems. Urban stormwater contains a cornucopia of pollutants that pose direct toxicity risks (e.g., metals, organics, pathogens) and indirect adverse effects (e.g., sediments, nutrients) to aquatic life. Metals, specifically copper (Cu) and zinc (Zn), are both ubiquitous in the urban environment and detrimental to aquatic ecosystems at low concentrations (approximately 10 ppb). Targeting this growing source of pollution upstream is critical in providing necessary environmental protections, especially as the intensifying effects of climate change and urbanization are imminent. This leads to the main research question – how can Cu and Zn loads in stormwater be reduced to protect aquatic ecosystems?Bioretention is a stormwater control measure (SCM) that mimics natural systems to take advantage of the natural filtering processes. In addition to hydrologic benefits, bioretention provides removal of particulate matter (PM) through filtration and sedimentation, and potential removal of dissolved constituents through chemical and biological processes. Studies including characterization of stormwater, road-deposited sediments (RDS), and performance of a mature bioretention cell were performed to determine treatability, mobility, and bioavailability of Cu and Zn in stormwater and through bioretention treatment. Both metals accumulated in the finest (<25 μm) fraction of RDS samples, however particulate bound (PB) Zn concentrations were enriched in stormwater compared to finer fractions of RDS, while PB-Cu was not. This indicated that PB-Zn is more mobile than PB-Cu, likely due to different sources of these metals in urban environments. The PM and PB metal loads were reduced by 82% and 83%, respectively, showing that mature bioretention cells are effective at reducing PM and PB contaminant loads. However, dissolved constituents were essentially unchanged through bioretention treatment, and concentrations of dissolved metals were measured at levels that potentially cause aquatic toxicity. Thus, alternative media amendments were investigated for further reduction of dissolved metal contents. Black carbon (BC) media including biochar, granular activated carbon (GAC), regenerated activated carbon (RAC), and a natural mineral sorbent, clinoptilolite zeolite, were tested in continuous columns, and in up-scaled modular treatment columns. The four tested BC media performed similarly for Cu and Zn removal, with Zn having an earlier breakthrough compared to Cu. This technology is predicted to provide reduction of dissolved Cu for up to 60 years with current rainfall predictions. Modular treatment columns showed that traditional bioretention soil media (BSM) provided effective removal of dissolved Zn (71%) and ineffective removal of Cu (17%). The subsequent BC polishing module was effective for Cu removal (40%), and zeolite showed potential for Zn removal. Overall, dissolved metals in stormwater are the most mobile, bioavailable, and difficult to remove through traditional filtration-based SCMs. This research has shown that fresh BSM can provide effective removal of dissolved Zn, and BC amendments are a potential solution for removal of dissolved Cu in stormwater. Refreshing the top few centimeters of an existing bioretention with fresh BSM can provide treatment of dissolved Zn. Retrofitting bioretention to include a polishing module either layered or in series with a mix of BC and zeolite can further reduce dissolved Cu and Zn loads in stormwater.Item Implementing wastewater surveillance for SARS-CoV-2 on a university campus: Lessons learned(Wiley, 2022-10-21) Wartell, Brian A.; Proano, Camila; Bakalian, Lena; Kaya, Devrim; Croft, Kristen; McCreary, Michael; Lichtenstein, Naomi; Miske, Victoria; Arcellana, Patricia; Boyer, Jessica; Van Benschoten, Isabelle; Anderson, Marya; Crabb, Andrea; Gilson, Susan; Gourley, Anthony; Wheeler, Tim; Trest, Brian; Bowman, Glynnis; Kjellerup, Birthe V.Wastewater surveillance, also known as wastewater-based epidemiology (WBE), has been successfully used to detect SARS-CoV-2 and other viruses in sewage in many locations in the United States and globally. This includes implementation of the surveillance on college and university campuses. A two-phase study was conducted during the 2020–2021 academic year to test the feasibility of a WBE system on campus and to supplement the clinical COVID-19 testing performed for the student, staff, and faculty body. The primary objective during the Fall 2020 semester was to monitor a large portion of the on-campus population and to obtain an understanding of the spreading of the SARS-CoV-2 virus. The Spring 2021 objective was focused on selected residence halls and groups of residents on campus, as this was more efficient and relevant for an effective follow-up response. Logistical problems and planning oversights initially occurred but were corrected with improved communication and experience. Many lessons were learned, including effective mapping, site planning, communication, personnel organization, and equipment management, and obtained along the way, thereby paving an opportune guide for future planning efforts.