UMD Theses and Dissertations

Permanent URI for this collectionhttp://hdl.handle.net/1903/3

New submissions to the thesis/dissertation collections are added automatically as they are received from the Graduate School. Currently, the Graduate School deposits all theses and dissertations from a given semester after the official graduation date. This means that there may be up to a 4 month delay in the appearance of a given thesis/dissertation in DRUM.

More information is available at Theses and Dissertations at University of Maryland Libraries.

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Subject: search.filters.subject.Material Characterization

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    NOVEL GRAPHENE HETEROSTRUCTURES FOR SENSITIVE ENVIRONMENTAL AND BIOLOGICAL SENSING
    (2024) Pedowitz, Michael Donald; Daniels, Kevin; Electrical Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)
    The COVID-19 pandemic has underscored the need for rapid, mobile, and adaptable sensing platforms to respond swiftly to pandemic-level emergencies. Additionally, smog and volatile organic compounds (VOCs), which posed significant health risks during last year’s wildfires, highlight the critical need for environmental air quality monitoring. Graphene, with its high sensitivity and fast response times, shows promise as a powerful sensing platform. However, it faces challenges related to low selectivity and the complexities of device fabrication using conventional chemical vapor-deposited graphene grown on metal foil, which requires exfoliation and transfer to suitable substrates.This dissertation explores the use of epitaxial graphene, which is graphene grown from the sublimation of silicon from silicon carbide, and forming heterostructures with legacy functional materials, such as transition metal oxides and selective capture probes like antibodies and aptamers to develop rapid, ultrasensitive, and selective sensors to address critical environmental and public health challenges. Epitaxial graphene provides a single-crystal, lithography-compatible graphene substrate that retains the desirable electronic properties of graphene without the drawbacks associated with transferred materials. This work focuses on creating heterostructures using traditional functional materials, such as manganese dioxide and antibodies, to develop high-quality, selective sensors for both biological and environmental applications. The practical applications of these sensors are demonstrated and validated using techniques such as Raman spectroscopy, X-ray photoelectron spectroscopy, atomic force microscopy, scanning electron microscopy, and electrical characterization. Additionally, detailed material analysis on producing these heterostructures is provided, emphasizing their ability to be modified without damaging the underlying graphene surface. This highlights epitaxial graphene's robust and versatile nature and its potential for creating high-quality devices with relatively simple designs. Finally, these biosensors are applied to alternate antibody-antigen systems, including influenza, to enhance disease-tracking capabilities. We also explore advanced functional materials, such as protease-peptide systems, which enable the creation of on-chip chemistry systems previously unattainable with current material systems.
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    MOLD PROCESS INDUCED RESIDUAL STRESS PREDICTION USING CURE EXTENT DEPENDENT VISCOELASTIC BEHAVIOR
    (2024) Phansalkar, Sukrut Prashant; Han, Bongtae; Mechanical Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)
    Epoxy molding compounds (EMC) are widely used in encapsulation of semiconductor packages. Encapsulation protects the package from physical damage or corrosion due to harsh environments. Molding processes produce residual stresses in encapsulated components. They are combined with the stresses caused by the coefficient of thermal expansion (CTE) mismatch to dictate the final warpage at room and reflow temperatures, which must be controlled for fabrication of redistribution layer (RDL) as well as yield during assembly. During molding process, EMC is continuously curing and the mechanical properties continue to evolve; more specifically, the equilibrium modulus and the relaxation modulus. The former defines behavior after complete relaxation while the latter describes the transient behavior. It is thus necessary to measure cure-dependent viscoelastic properties of EMC to be able to determine mold induced residual stresses accurately. This is the motivation for this thesis. In this thesis, a set of novel methodologies are developed and implemented to quantify a complete set of cure-dependent viscoelastic properties, including the fully cured properties. Firstly, an advanced numerical scheme has been developed to quantify cure kinetics of thermosets with both single and dual-reaction systems. Secondly, a unique methodology is proposed to measure the viscoelastic bulk modulus -K(t,T) of EMC using hydrostatic testing. The methodology is implemented with a unique test setup based on inert gas. The results of viscoelastic testing along with the shear modulus (G) and bulk modulus (K) master curves and temperature-dependent shift factors (a(T)) of fully-cured EMC are presented. Thirdly, a novel test methodology utilizing monotonic testing has been developed to measure two sets of equilibrium moduli of EMC as a function of cure extent (p). The main challenge for the measurements is that the equilibrium moduli could only be measured accurately only when the EMC has fully relaxed. The temperatures for complete relaxation typically occur above the glass transition temperature, Tg (p), where the curing rate is also high. A special measurement procedure is developed, through which the EMC moduli above Tg can be determined quickly at a near isocure state. Viscoelastic testing of partially-cured EMC is followed to determine the cure-dependent shift factors of EMC. The test durations have to be very long (several hours) and it is conducted below Tg (p) of the EMC where the reaction is slow (under diffusion-control) Finally, a numerical scheme that can utilize the measured cure-dependent viscoelastic properties is developed. It is implemented to predict the residual stress evolution of molded packages during and after molding processes.
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    Development of Magnetic Shape Memory Alloy Actuators for a Swashplateless Helicopter Rotor
    (2006-04-28) Couch, Ronald Newton; Chopra, Inderjit; Aerospace Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)
    Actuator concepts utilizing NiMnGa, ferromagnetic shape memory alloy are investigated for potential use on a smart rotor for trailing edge flap actuation. With their high energy density, large dynamic stroke, and wide operating bandwidth, ferromagnetic shape memory alloys (FSMA) like NiMnGa, seem like attractive candidates for smart rotor actuators, potentially able to fulfill the requirements for both primary rotor control and vibration suppression. However, because of the recent discovery of the material, current experimental data and analytical tools are limited. To rectify these shortcomings, an extensive set of detailed experiments were conducted on samples of NiMnGa to characterize the response of the alloy for a wide variety of mechanical and magnetic loading conditions. Measurements of the material performance parameters such as power density, damping properties, magneto-mechanical coupling, and transduction efficiency were included. Once characterized, the experimental data were used to develop a series of analytical tools to predict the behavior of the material. A model, developed in parallel to thermal shape memory alloy models is proposed to predict the quasi-static stress-strain behavior. A simple, low frequency, parameter based model was also developed to predict the alloy's dynamic strain response. A method for developing conceptual actuators utilizing NiMnGa as the actuation element was proposed. This approach incorporates experimental data into a process that down-selects a series of possible actuator configurations to obtain a single configuration optimized for volumetric and weight considerations. The proposed actuator was designed to deliver 2 mm of stroke and 60 N of force at an actuation frequency of 50 Hz. However, to generate the 1.0 T magnetic field, the actuator mass was determined to be 2.8 kg and required a minimum of 320 Watts of power for operation. The mass of the NiMnGa element was only 18.3 g. It was concluded that although the NiMnGa alloy was capable of meeting the trailing edge flap actuation requirements, the material is not suitable in its present form for this application because of weight and power consumption issues. The magnetic field requirements must be reduced to improve the utility of the material for rotorcraft applications.