UMD Theses and Dissertations
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New submissions to the thesis/dissertation collections are added automatically as they are received from the Graduate School. Currently, the Graduate School deposits all theses and dissertations from a given semester after the official graduation date. This means that there may be up to a 4 month delay in the appearance of a given thesis/dissertation in DRUM.
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Item GEOCHEMICAL INDICATORS OF REDOX AND WEATHERING ACROSS THE EDIACARAN-CAMBRIAN TRANSITION IN SIBERIA(2024) Doerrler, Andrew; Kaufman, Alan Jay; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)The transition between the Ediacaran and Cambrian periods witnessed the fall of the enigmatic Ediacara biota. The cause of their extinction is poorly understood, but the timing broadly coincides with a significant negative ẟ13C anomaly, the BAsal Cambrian Carbon isotope Excursion (BACE). These macroscopic organisms were likely tolerant of anoxic conditions, so oceanic oxidation may have been a kill mechanism. This study utilizes uranium isotopes, sulfur isotopes, and cerium anomalies to understand oceanic redox conditions from two BACE sections in Siberia, as well as lithium isotopes to constrain weathering intensity. Reconstruction of seawater ẟ238U values from equivalent evaporite and carbonate-dominated successions indicate a notable increase in oxygen during the event supporting the oxidation hypothesis. Global sea level fall and evaporite formation suggest that seawater salinity increased dramatically along continental margins, which may provide an alternative osmotic kill mechanism for the softbodied Ediacaran biota. Support for the salinity hypothesis comes from profound ẟ7Li and ẟ34S compositions of carbonate and pyrite, respectively, which arguably resulted from the distillation of lithium and sulfate from seawater into evaporite-rich lithologies.Item The Ecological Velocity of Climate Change(2020) O'Leary, Donal Sean; Hurtt, George C; Geography; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Vegetation productivity and distributions are largely driven by climate, and increasing variability in seasonal and interannual climate is both changing the spatiotemporal patterns of resource availability across the landscape, and driving species’ migrations towards climate refugia. Climate and vegetation dynamics take place along the time dimension (e.g. earlier snowmelt and arrival of spring in temperate mountains), but they also occur throughout space, where changes in climate can be expressed as a movement across the landscape (e.g. warm temperatures and migratory animals moving uphill in spring, or tree species distributions moving uphill and towards the poles under climate change). Here, we present new methods to track the movement of climate and vegetation, quantifying the ecological velocity of climate change at the landscape scale. Our focus is on national parks of the USA, which are important study areas because of their great conservation and social value, protection from anthropogenic disturbances, and longstanding research and monitoring records. First, we explore the spatio-temporal relationships between snowmelt timing and vegetation phenology in Crater Lake National Park. We find that snowmelt timing is closely linked to spring greenup, but has far weaker influence on later season phenology, such as the senescence or growing season length. Second, we extend our comparison of snowmelt timing with vegetation phenology across space and time together as we track the speed and direction of receding seasonal snowpack (snowmelt velocity) with the ‘green wave velocity’ of spring greenness that follows. We find that snowmelt velocity has a moderate predictive power for green wave velocity in areas with steep slopes, where both phenomena are controlled by strong spatial gradients relating to elevation. Third, we extend our analysis into the future as we forecast the climate velocity of air temperature and precipitation in and surrounding national parks from 2019-2099. Here, we identify possible corridors and velocities of future climate migration across park boundaries, highlighting locations of ecological concern and climate vulnerability. Taken together, our analysis of the ecological velocity of climate change forms new connections among climate, conservation, and spatial sciences while prioritizing management-relevant deliverables.Item Authigenesis, biomineralization, and carbon-sulfur cycling in the Ediacaran ocean(2015) Cui, Huan; Kaufman, Alan J.; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Fossil record of the Ediacaran Period (635-541 Ma) reveals unprecedented rise of early animal life (metazoan) in Earth history. Coupled with this evolutionary milestone, the Earth’s atmosphere and hydrosphere experienced dramatic redox fluctuations. In order to better constrain the redox architecture of the Ediacaran ocean margin, an integrated chemostratigraphic correlation of the Doushantuo Formation in basin scale was conducted (see Chapter 2). The revised redox model suggests that euxinic conditions on the platforms were mainly restricted in lagoonal settings, which helps us to better understand Ediacaran fossil distributions and fluctuated δ13C records in the Ediacaran strata in South China. One of the most distinct features of the Ediacaran chemostratigraphy is the δ13C negative excursion (i.e. Shuram Excursion, or SE) reported globally, which is the largest known C cycle anomaly in Earth history. In order to understand the biogeochemical processes that gave rise to the SE expressed in the upper Doushantuo Formation, systematic petrographic and geochemical investigations were conducted for the outer shelf sections in the Yangtze block (see Chapter 3). Methane-derived authigenic calcite cements and nodules with extreme 13C-depletion were discovered and interpreted as the first empirical evidence of authigenic mineralization associated with the SE. In light of these novel observations, it is proposed that the globally distributed SE may be formed by widespread syndeposition of authigenic carbonates in a sulfate-methane transitional zone positioned at the sediment-water interface in response to a global seawater sulfate increase. Finally, to provide environmental context for the terminal Ediacaran biomineralization of animals, we conducted a high-resolution elemental and isotopic study of the richly fossiliferous Gaojiashan Member (see Chapter 4). Coincident with the first appearance of Cloudina are significant C-S-Ca-Sr cycle anomalies. It is proposed that the onset of calcarious biomineralization of animals may have coincided with an increase in terrestrial weathering fluxes of sulfate, alkalinity, and nutrients to the depositional basin. Enhanced concentration of Ca ion in seawater may have promoted the calcarious biomineralization of the early animals. Integrated chemo-, bio- and litho-stratigraphy of the Doushantuo and Dengying formations presented in this dissertation emphasized intimate co-evolution of Earth-life system during the Ediacaran Period.Item An Integrated Isotopic and Biomarker Analysis of the Glaciogenic Vazante Group, Brazil(2012) Miller, Kristen Elizabeth; Kaufman, Alan J; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)The Vazante Group, a meta-sedimentary succession located in south-central Brazil, contains several intervals of diamictite, interpreted as glacial in origin, bracketed by well-preserved carbonate and shale. This glacial succession was previously associated with the global occurrence of Neoproterozoic low latitude glacial deposits (aka Snowball Earth), and biomarkers (molecular fossils) identified from an organic-rich interval within this succession were used to infer active photosynthesis during the ice age (Olcott et al., 2005). However, new Re-Os and detrital zircon U-Pb ages suggest that the upper Vazante Group is ca. 1.3 to 1.0 billion-years old (Geboy, 2006; Azmy et al., 2008; Rodrigues et al., 2008) and thus may preserve evidence for hitherto unknown Mesoproterozoic ice ages. Within this context, I present biomarker and time-series stable isotope data from a basin-wide distribution of pre- and post-glacial sedimentary units in order to i) evaluate the Mesoproterozoic interpretation of this succession, ii) assess the biologic and environmental conditions present when these sediments were deposited, and iii) to understand the co-evolution of life and ocean chemistry in response to rapidly changing environmental conditions. Biomarker distributions and abundances from the Serra do Garrote Formation, a pre-glacial shale, and the Serra do Poço Verde and Lapa formations, both post-glacial shales, show evidence of a diverse microbial community that would have only existed in a redox stratified water column. Additionally, the presence of aryl isoprenoids, biomarkers indicative of green sulfur bacteria, in the Serra do Garrote and Serra do Poço Verde formations suggest that reducing, sulfide-rich water was present in the photic zone. These biomarkers however, are absent from the Lapa Formation suggesting that sulfidic conditions either receded to deeper water or collapsed entirely. Carbon and sulfur isotopic signatures support the conclusions drawn from this biomarker study. Carbon and sulfur trends from the Serra do Garrote and Serra do Poço Verde formations show evidence of a large, anoxic, isotopically stable, dissolved organic carbon pool (relative to inorganic carbon) and extensive bacterial sulfate reduction of a small, oceanic sulfate reservoir. The Lapa Formation, on the other hand, displays evidence for a smaller, isotopically responsive, dissolved organic carbon pool. The carbon isotopic compositions of carbonates from these three units are consistent with other Mesoproterozic successions supporting the geochronological age constraints. Taken together, biomarker and time-series stable isotope data from the upper Vazante Group map a transition from a sulfide-rich, stratified, water column to one that, while still stratified, was no longer sulfidic. This environmental transition occurred in response to consecutive Mesoproterozoic ice ages.