UMD Theses and Dissertations
Permanent URI for this collectionhttp://hdl.handle.net/1903/3
New submissions to the thesis/dissertation collections are added automatically as they are received from the Graduate School. Currently, the Graduate School deposits all theses and dissertations from a given semester after the official graduation date. This means that there may be up to a 4 month delay in the appearance of a given thesis/dissertation in DRUM.
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Item GENERATING BIOENERGY AND HIGH-VALUE PRODUCTS FROM HIGH SALINITY FOOD WASTE(2024) McCoy, Emily Lim; Lansing, Stephanie; Environmental Science and Technology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Bioenergy generation and volatile fatty acids (VFAs) production from household food waste and high salinity food processing waste were explored using anaerobic digestion and dark fermentation processes, respectively. This study tested adding value to three organic waste streams: household food waste, high salinity food processing waste (composed of glycerin sludge from biodiesel production), and residual solids from VFAs separation after dark fermentation of food waste. The investigations were conducted using batch and semi-continuous systems in mesophilic conditions (35°C). Methane (CH4) potential tests were conducted to determine the bioenergy production of food waste and residual solids, including the addition of dark fermentation gas at four ratios of hydrogen (H2) to carbon dioxide (CO2) (1:1, 1:2, 1:3, 1:5) into the liquid portion of the reactor to enhance CH4 production and three inoculum to substrate ratios (1.5:1, 2:1, 4:1). Additionally, a semi-continuous dark fermentation study was used to determine the VFA production from household food waste and high salinity food processing waste combinations over 62 days. The anaerobic digestion of residual solids from VFAs separation had similar bioenergy potential as household food waste when normalized by volatile solids (VS) added (492 ± 11 mL CH4/g VS and 470 ± 11 mL CH4/g VS, respectively). Dark fermentation gas added into the liquid portion of the reactor during anaerobic digestion decreased CH4 yields, especially at low H2:CO2 ratios, suggesting that only dark fermentation reactors that produce high H2:CO2 ratios should have the gas sparged into anaerobic digestion systems. When the residual solids from dark fermentation were fermented at three inoculum to substrate ratios (1.5:1, 2:1, 4:1), the lowest inoculum to substrate ratio (1.5:1) had the highest VFAs concentration (28.05 ± 0.89 g/L) after nine days of fermentation, which showed that residual solids can be fermented with low inoculum levels, allowing more room for substrate fermentation. Additionally, the mono- and co-fermentation of household food waste and high salinity food processing waste showed that the high salinity waste improved VFA production due to the high pH (9 – 10) and high organic loading (6.3 – 17.8 g VS/L-day), even with high salinity levels (21.4 – 85.6 g/L Na) in this waste. There was significantly higher VFA production in high salinity food processing waste (36.04 ± 0.54 g/L) compared to household food waste (9.29 ± 1.01 g/L). The maximum VFA concentration (36.04 ± 0.54 g/L) was achieved after 51 days of high salinity food processing waste semi-continuous fermentation. The findings in this study can be used to improve operations of anaerobic digestion and dark fermentation systems by using residual solids for bioenergy generation or VFA production. The testing of mono- and co-fermentation of household food waste and high salinity food processing waste showed high VFA production in fermenting high salinity food processing waste. This work showed the valorization of three organic waste streams through bioconversion to both bioenergy and high-value products (VFAs), which redirected these waste products from municipal solids landfills and into resources, thereby reducing CH4 released into the atmosphere from landfills and reducing global warming potential.Item Fate of antimicrobials and nutrients in dairy manure management systems(2018) Schueler, Jenna E; Lansing, Stephanie; Environmental Science and Technology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Anaerobic digestion (AD) and composting manure management strategies were explored at the field scale to monitor antimicrobial degradation, nutrient transformations, and optimize mitigation of these pollutants in manure fertilizer to decrease their entry to waterways. Removal of antimicrobials and antimicrobial resistance genes (ARGs) were explored at the bench scale, where AD degraded >85% of antimicrobials. At the field-scale, antimicrobials were not consistently removed, persisting in concentrations up to 34,000 ng/g DW in the AD effluent. The tetM genes were reduced during bench-scale AD suggesting that AD could be an effective treatment for removing tetracycline ARGs from manure. The 100% reduction of sulfadimethoxine antimicrobials during AD did not correspond with Sul1 reduction, illustrating differences in antimicrobial versus gene reductions during manure treatment. Antimicrobials did not degrade significantly during field scale composting, likely due to a shortened composting period (33-days). The field-scale results illuminate limitations of tracking antimicrobials in complex treatment systems.Item ENVIRONMENTAL SUSTAINABILITY AND WASTE TREATMENT CAPABILITIES OF SMALL-SCALE ANAEROBIC DIGESTION SYSTEMS(2012) Moss, Andrew Robert; Lansing, Stephanie A.; Environmental Science and Technology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Anaerobic digestion is a common form of waste treatment and energy production throughout the world, and in the United States the number of agricultural digesters is increasing at a rate of approximately 10% annually. As the number of digesters grows, efforts to assess the environmental cost of their installation and the potential utility of their by-products are required. This research investigates the relative environmental sustainability of small-scale digesters treating dairy manure in the U.S. and human waste in Haiti, and explores the biogas potential and nutrient transformations resulting from the anaerobic digestion of dairy manure. Specifically, the objectives of the research are: 1) to conduct an eMergy analysis on the two digestion systems to assess the effect of waste source, climate, and infrastructure on system sustainability; and 2) to provide an overview of waste treatment and energy production options for agricultural digesters treating dairy manure in the United States.