UMD Theses and Dissertations

Permanent URI for this collectionhttp://hdl.handle.net/1903/3

New submissions to the thesis/dissertation collections are added automatically as they are received from the Graduate School. Currently, the Graduate School deposits all theses and dissertations from a given semester after the official graduation date. This means that there may be up to a 4 month delay in the appearance of a given thesis/dissertation in DRUM.

More information is available at Theses and Dissertations at University of Maryland Libraries.

Browse

Filters

20061

Settings

Author: search.filters.author.Lee, SeungchanSubject: search.filters.subject.Nanocomposites

Search Results

Now showing 1 - 1 of 1
  • Thumbnail Image
    Item
    SIZE MODIFICATION AND COATING OF TITANIUM DIOXIDE USING A PREMIXED HYDROGEN/AIR FLAME
    (2006-08-22) Lee, Seungchan; Ehrman, Sheryl H; Chemical Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)
    A study was conducted of the effect of flame processing on the size distribution of titania nanoparticles, and a flame process was developed for producing TiO2/SiO2 coreshell particles from aqueous suspensions of TiO2 and SiO2 nanoparticles. Both were performed using a premixed hydrogen/air flame. At the adiabatic flame temperature of 2400 K, the number mean diameter of titania primary particle increased considerably from an initial value of 44 nm to 96 nm, presumably by atomic diffusion, and viscous flow coalescence. Moreover, the majority of product particles from this high flame temperature were smooth and spherical. Based on the results of size modification experiments, coating experiments were performed. The dominant morphology observed in the product particles from coating experiments was silica coated titania. The silica coating was very smooth and dense. The total particle size and the shell volume of the product particles were in reasonable agreement with values predicted from the atomized droplet size distribution and the droplet concentration.