Theses and Dissertations from UMD
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New submissions to the thesis/dissertation collections are added automatically as they are received from the Graduate School. Currently, the Graduate School deposits all theses and dissertations from a given semester after the official graduation date. This means that there may be up to a 4 month delay in the appearance of a give thesis/dissertation in DRUM
More information is available at Theses and Dissertations at University of Maryland Libraries.
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Item ELECTROCHEMICAL COMPRESSION WITH ION EXCHANGE MEMBRANES FOR AIR CONDITIONING, REFRIGERATION AND OTHER RELATED APPLICATIONS(2017) Tao, Ye; Wang, Chunsheng; Chemical Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)The refrigeration industry in the US are facing two main challenges. First of all, the phase down of HFCs in the future would require industries to seek alternative refrigerants which do not contribute to global warming. Secondly, the mechanical compressor in the small scale cooling system with a large energy impact is reaching its limitation due to heat transfer and manufacturing tolerances. Therefore there is an urgent need to develop a highly efficient compression process that works with environmentally friendly refrigerants. And the electrochemical compressor is developed to meet these requirement based on the following reasons. First of all, the electrochemical compressor can achieve an isothermal compression efficiency of greater than 90%. It also operates without moving parts, lubrication and noise. Most importantly, the compressor works with environmentally friendly refrigerants. In this thesis, three distinct electrochemical compression processes were studied. The first study is focused on modeling a metal hydride heat pump driven by electrochemical hydrogen compressor. The performance of the cooling-generating desorption reactor, the heating-generating absorption reactor, as well as the whole system were demonstrated. The results showed the superior performance of electrochemical hydrogen compressor over mechanical compressor in the system with optimized operating condition and COP. The second study demonstrated the feasibility of electrochemical ammonia compression with hydrogen as a carrier gas. The reaction mechanisms and the compression principle were verified and the compression efficiency was measured to be greater than 90%. The technology can be applied to ammonia vapor compression refrigeration cycle and ammonia storage. The third study is about developing and studying the electrochemical CO2 compression process with oxygen as a carrier gas. The reaction mechanism was verified and compared for both Pt and CaRuO3 electro-catalysts. And the latter was selected due to better CO2 and O2 absorption. The technology can potentially be applied in carbon dioxide transcritical refrigeration cycle and carbon capture. In conclusion, the electrochemical compression is a promising technology with higher compression efficiency and would bring a revolutionary change to the compressor engineering industry and global refrigeration and air conditioning market. It can also be used in fuel storage and separation based on the selective properties of the ion exchange membrane.Item Thermoacoustic-Piezoelectric Systems with Dynamic Magnifiers(2013) Nouh, Mostafa Akram; Baz, Amr; Mechanical Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Thermoacoustic energy conversion is an emergent technology with considerable potential for research, development, and innovation. In thermoacoustic resonators, self-excited acoustic oscillations are induced in a working gas by means of a temperature gradient across a porous body and vice versa with no need of moving parts. In the first part of this dissertation, thermoacoustic resonators are integrated with piezoelectric membranes to create a new class of energy harvesters. The incident acoustic waves impinge on a piezo-diaphragm located at one end of the thermoacoustic-piezoelectric (TAP) resonator to generate an electrical power output. The TAP design is enhanced by appending the resonator with an elastic structure aimed at enhancing the strain experienced by the piezo-element to magnify the electric energy produced for the same input acoustic power. An analytical approach to model the thermal, acoustical, mechanical and electrical domains of the developed harvester is introduced and optimized. The performance of the harvesters is compared with experimental data obtained from an in-house built prototype with similar dimensions. In an attempt to further understand the dynamics and transient behavior of the excited waves in the presence of piezoelectric coupling, a novel approach to compute and accurately predict critical temperature gradients that onset the acoustic waves is discussed. The developed model encompasses tools from electric circuit analogy of the lumped acoustical and mechanical components to unify the modeling domain. In the second part of the dissertation, piezo-driven thermoacoustic refrigerators (PDTARs) are presented. The PDTARs rely on the inverse thermoacoustic effect for their operation. A high amplitude pressure wave in a working medium is used to create a temperature gradient across the ends of a porous body located in an acoustic resonator. Finally, PDTARs with dynamic magnifiers are introduced. The developed design is shown, theoretically and experimentally, as capable of potentially enhancing the cooling effect of PDTARs by increasing the temperature gradient created across the porous body.