Theses and Dissertations from UMD
Permanent URI for this communityhttp://hdl.handle.net/1903/2
New submissions to the thesis/dissertation collections are added automatically as they are received from the Graduate School. Currently, the Graduate School deposits all theses and dissertations from a given semester after the official graduation date. This means that there may be up to a 4 month delay in the appearance of a give thesis/dissertation in DRUM
More information is available at Theses and Dissertations at University of Maryland Libraries.
Browse
19 results
Search Results
Item Characterizing nutrient budgets on and beyond farms for sustainable nutrient management(2023) Zou, Tan; Zhang, Xin; Marine-Estuarine-Environmental Sciences; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)The production and security of food are heavily reliant on adequate nitrogen (N) and phosphorus (P) inputs in agriculture. However, ineffective management of N and P from the farm to the table can result in nutrient pollution, triggering both environmental and social issues. Moreover, another important challenge for P management is limited and unevenly distributed P resources, leading to P scarcity in many parts of the world. Inefficient use of nutrients in agriculture-food systems is the root cause of both nutrient pollution and scarcity. To improve nutrient use efficiency and reduce nutrient loss, it is crucial to address key knowledge gaps in nutrient management research, which include inadequate quantification of nutrient budgets, as well as identifying and addressing nutrient management challenges across various systems and spatial scales. This dissertation tackles the knowledge gaps in two studies, including a global-scale study and a case study of the Chesapeake Bay watershed. In the global-scale study, I establish and utilize a unique P budget database to assess historical P budget and usage patterns at the national and crop type level from 1961 to 2019. This analysis reveals the impacts of various agricultural and socioeconomic drivers on cropland P use efficiency (PUE), including N use efficiency (NUE), fertilizer-to-crop-price ratio, farm size, crop mix, and agricultural machinery. The findings indicate that P management challenges vary by country and spatial scale, necessitating tailored country-level strategies. The regional-scale study applies a framework adapted from N studies to the Chesapeake Bay watershed, analyzing nutrient (N and P) management across systems and spatial scales. This approach uncovers that nutrient loss potential beyond crop farms is larger than that at crop farms. This highlights the need to enhance nutrient management and curb nutrient loss in animal production, food processing and retail, and human consumption. This study also identifies a large potential for meeting cropland nutrient demand by increasing the recycling of nutrients in manure, food waste, and human waste. To tackle the challenges surrounding nutrient management in the watershed, it is imperative to target factors significantly related to nutrient management, such as agricultural practices, soil properties, climate change, and socioeconomic conditions. This dissertation contributes to a deeper understanding of N and P management challenges, gaps, priorities, hidden drivers, and potential solutions at various scales, from regional to national and global levels. The analytical procedures and statistical tools developed in this dissertation are generalizable, allowing for their adaptation to similar nutrient management studies in different regions and for diverse research purposes.Item TWO MARINE SPONGES, LENDENFELDIA CHONDRODES AND HYMENIACIDON HELIOPHILA, AND THEIR MICROBIAL SYMBIONTS: ROLES IN MARINE PHOSPHORUS CYCLING.(2021) Jonas, Lauren; Hill, Russell; Marine-Estuarine-Environmental Sciences; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Marine sponges have emerged as major players within coral reef biogeochemical cycles, facilitating intake and release of carbon, nitrogen, and phosphorus. The majority of studies have investigated the role of sponges in transforming dissolved carbon and nitrogen; however, the same breadth of insights has not been extended to phosphorus. This study uses 32P-labeled orthophosphate and ATP to determine that two marine sponges, Lendenfeldia chondrodes and Hymeniacidon heliophila, both rapidly take up ambient dissolved inorganic phosphate and dissolved organic phosphorus. Subsequent genetic analysis and chemical extraction showed that sponge symbionts store phosphorus in the form of energy-rich polyphosphate (poly-P). L. chondrodes, a sponge from oligotrophic habitats and with a microbiome dominated by cyanobacterial symbionts, stores more phosphorus as poly-P (6–8%) than H. heliophila (0.55%), a eutrophic sponge with low cyanobacterial abundance. This work adds new insights to the roles of the sponge holobiont in cycling the crucial element, phosphorus.Item Saltwater intrusion alters nitrogen and phosphorus transformations in coastal agroecosystems(2020) Weissman, Dani; Tully, Katherine L; Plant Science and Landscape Architecture (PSLA); Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)As sea levels rise, coastal regions are becoming more vulnerable to saltwater intrusion (SWI). In coastal agricultural areas, SWI is causing changes in biogeochemical cycling in soil and waterways. These changes are leading to the release of excess nitrogen (N) and phosphorus (P) from farm fields, which in turn can cause impaired water quality downstream. I explored the effects of saltwater intrusion on N and P concentrations of surface water and soil porewater on Maryland’s Eastern Shore in the Chesapeake Bay Watershed on three spatial and temporal scales: 1) a three-year field study through farmland and various surrounding habitats; 2) a one-month laboratory soil incubation study; and 3) a regional study of tidal tributaries (sub-watersheds) along Maryland’s Eastern Shore where I utilized 35 years of observational data on nutrient concentrations and salinity from the Chesapeake Bay Water Quality Monitoring Program. The results of the field and incubation studies suggest that SWI can cause a large release of N and P from the soils of coastal landscapes to downstream water bodies such as tidal creeks and marshes. However, the results of the regional study suggest that the relative magnitude of SWI-driven contributions of N and P to waterways as compared to other sources and drivers of N and P differ depending on the spatial and temporal scale considered. Defining mechanisms through which SWI spurs nutrient release from soils of agricultural fields and surrounding habitats as well as the magnitude of these processes is critical for quantifying N and P export in coastal watersheds. The results of these three studies can potentially be used to inform water quality models for individual tidal tributaries, which would allow for more targeted approaches to nutrient load reductions in sub-watersheds of the Chesapeake Bay and other watersheds globally.Item IMPROVING STORMWATER QUALITY USING A NOVEL PERMEABLE PAVEMENT BASE MATERIAL(2018) OSTROM, TRAVIS Kyle; Davis, Allen P; Civil Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)A novel stormwater treatment media has been developed using expanded shale aggregate, Al-based water treatment residual (WTR), and psyllium-based binder. The media (HPMM) has sufficient structural capacity and hydraulic conductivity to serve as a permeable pavement base material and demonstrated effective phosphorus (P) retention in lab- and field-scale studies. Long-term adsorption capacity is projected to exceed 600 years of useful life before P saturation under conditions typical of urban stormwater in Maryland (i.e., 0.20 mg/L dissolved P (DP) influent and 100 cm of direct rainfall per year). A dynamic model was developed to describe DP adsorption onto the media based on lab testing and verified under field monitoring. The model predicted 62% DP concentration reduction and 65% DP mass load reduction. Actual reductions from 17 months of monitoring in a field pilot study were 67% for DP concentration and 69% DP mass load. Total Cu and Zn were also removed from stormwater in lab and field studies. Percent concentration reductions of 59-69% for Cu and 78-90% for Zn were shown in lab studies using synthetic stormwater. Mass load was reduced in field monitoring by 32 and 21% for Cu and Zn, respectively. WTR in the media was shown to be a potential source of nitrogen (N). An internal water storage (IWS) zone was established in a 5-cm permeable pavement base layer to mitigate N export by promoting denitrification. The IWS was shown to effectively lower N concentrations in simulated stormwater when carbon (C) was available in excess (~10 mg/L total C as C). Elevated Al concentrations were found in some filtrate samples from the field study, resulting from washout of fines from the media. Improved HPMM mix preparation methods have been developed and are critical to prevent Al washout and export. This research resulted in development of the first known enhanced stormwater treatment media to retain DP in a permeable pavement base layer. With appropriate N and Al control, the novel media can be an effective tool and can enhance permeable pavements to improve urban stormwater quality.Item Evaluating Soil Phosphorus Dynamics over Time(2017) Lucas, Emileigh Rosso; Coale, Frank J; Environmental Science and Technology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Agricultural nutrient management became mandatory in Maryland (MD) due to water quality concerns. Phosphorus (P) management is complex due to the stability of P in the soil, nutrient mass imbalance, and “legacy” P. To explore how potential P application bans impact historically manured fields, agronomic and environmental soil tests were conducted on plots treated with five manure-P rates, then no P applications, spanning 15 years. Mehlich-3 extractable P (M3P) declined slowly and then generally did not change during the last six years. Phosphorus saturation declined slowly or not significantly. Excessive P soils had sufficient P for crop growth in solution. Phosphorus saturation and M3P were compared in fifty sites across MD pre- and post- nutrient management planning. Results showed an increase in P concentration of Maryland agricultural fields. This response was logical, as better management would increase below-optimum P concentrations, and the regulations were not designed to draw down P.Item Nutrient Leaching from Leaf-and-Grass Compost Addition to Stormwater Submerged Gravel Wetlands(2016) Mangum, Kyle Robert; Davis, Allen P; Civil Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Submerged Gravel Wetlands (SGWs) are subsurface-flow wetlands, and are effective stormwater control measures (SCM). Compost addition has many properties beneficial to SGWs but may also lead to leaching of nitrogen (N) and phosphorus (P). To investigate nutrient leaching effects of leaf-and-grass compost addition in SGWs, mesocosm studies were conducted using bioretention soil media (BSM) mixed with 30% and 15% compost, by volume. Synthetic stormwater was applied to mesocosms and effluent analyzed for N and P. Compost-added mesocosms were found to leach N and P. Maximum N concentrations of 16 and 6.4 mg-N/L were reached after 1.7 and 3.0 cm of rainfall for 15% and 30%, respectively. Maximum P concentrations of 2.9 and 0.52 mg-P/L were both reached after 2.5 cm for 30% and 15%, respectively. Particulate P was the dominant P species found in effluent samples, while N species were mixed. Although compost addition led to leaching of N and P, treatment of both nutrients was achieved, with the 15%, reaching a net-zero export of P after the equivalent of 20 cm of rainfall. Nitrogen treatment was attributed to denitrification and plant and microbial uptake. Phosphorus treatment was attributed primarily to adsorption.Item Nutrient Leaching from Bioretention Amended with Source-Separated Compost(2016) Owen, Dylan; Davis, Allen P; Civil Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Bioretention has been noted to be an effective stormwater control measure (SCM). Compost addition to bioretention could be beneficial, but could also act as a source for excess nutrients. This project analyzed possible nitrogen (N) and phosphorus (P) leaching from bioretention soil media (BSM) amended with source-separated compost. Columns were mixed with compost and BSM at volumes of 30%, and 15%. A final column had 15% compost and an additional 4% water treatment residual (WTR). Synthetic stormwater was applied to each column and the effluent was analyzed for N and P. The 30% column increased the mass exported for both nutrients. Both 15% columns had a net zero effect on nitrogen, but the 15%+WTR column reduced the exported phosphorus load. All compost columns discharged more nutrients than standard BSM. Compost addition should be minimized in bioretention, less than 15% by volume, and WTR should be added to control phosphorus leaching.Item Evaluation of accuracy and sensitivity of the University of Maryland Phosphorus Management Tool and investigation of subsurface phosphorus dynamics in the Maryland Coastal Plains region(2015) Fiorellino, Nicole; McGrath, Joshua M; Environmental Science and Technology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Phosphorus (P) loss from agricultural fields to surface water represents a major environmental challenge in agricultural nutrient management. To reduce P loading, areas where both P source and transport conditions are present must be identified and appropriate management practices implemented to reduce the source or break transport connectivity. The Maryland P Site Index (MD-PSI) was modified from a multiplicative structure to a component structure and renamed University of Maryland Phosphorus Management Tool (UM-PMT). In the UM-PMT, each component is the product of source, transport, and management factors specific to a P loss pathway. Our objectives were to evaluate the UM-PMT for accuracy, investigate soil conditions in ditch-drained agricultural systems, compare different methods for degree of P saturation (DPS) calculation, and compare numerical and categorical final scores of the multiple versions of the Maryland P loss risk indices. Agronomic soil samples were collected from fields across Maryland, and analyzed for P, aluminum (Al), and iron (Fe) concentration using multiple extractions, soil texture was determined, and degree of P saturation (DPS) was calculated using five methods. Deep soil samples were collected and analyzed similarly from three sites on Maryland's eastern shore. A poor relationship was identified between UM-PMT and modeled P loss data (R2=0.09), but the relationship improved with modifications to UM-PMT calculation (R2=0.97), which resulted in UM-PMT Version 2 (UM-PMT v.2). Soil Fe concentration was responsible for a large proportion of DPS at one sample location on the Eastern Shore, demonstrated through poor correlation between two methods for DPS calculation, including and excluding Fe concentration. Numerical differences existed between different methods for DPS calculation and these translated to differences in UM-PMT final score, particularly in the Lower Shore region. The UM-PMT v.2 categorized more fields as HIGH risk than MD-PSI but less than UM-PMT. Neither version of the UM-PMT was very sensitive to management factor input variables. Evaluation of tools like the UM-PMT for accuracy, sensitivity, and magnitude of change is necessary to understand potential economic and environmental impacts of implementing new indices as nutrient management tools.Item Physiological responses of Acartia and Eurytemora spp. to changes in the nitrogen:phosphorus quality of their food(2014) Bentley, Katherine Marie; Glibert, Patricia; Marine-Estuarine-Environmental Sciences; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)This study addressed how copepods respond to varying nutrient content in their prey. Copepod physiological responses were measured along a gradient of prey nitrogen:phosphorus (N:P) ratios created by altering the P content in diatom prey grown at a constant rate. Acartia tonsa, a broadcast spawner, and Eurytemora carolleeae, a brood spawner, increased excretion of P as prey N:P declined (i.e. P increased). E. carolleeae had higher somatic tissue nutrient content, while A. tonsa had higher egg nutrient content overall and higher P in eggs as N:P decreased. E. carolleeae egg production was greatest when eating high N:P prey while A. tonsa showed the opposite. Egg viability declined at high N:P for both copepods, yet A. tonsa viability was always greater than E. carolleeae viability. Both copepods responded physiologically to food of varying quality, yet regulated their homeostasis differently. Prey nutrient content may be significant in the environmental selection of different copepods.Item USE OF DRINKING WATER TREATMENT RESIDUALS AS A SOIL AMENDMENT FOR STORMWATER NUTRIENT TREATMENT(2010) O'Neill, Sean William; Davis, Allen P; Civil Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Stormwater runoff has been implicated as a major source of excess nutrients to surface waters, contributing to the development of eutrophic conditions. Bioretention, a promising technology for urban stormwater pollution treatment, was investigated to determine if an aluminum-based water treatment residual (WTR) amended bioretention soil media (BSM) could adsorb phosphorus to produce discharge concentrations below 25 μg/L. Batch, small column, and vegetated column studies were employed to determine both the optimal BSM mixture and media performance. Media tests demonstrated P adsorption proportional to WTR addition. Final selected experimental media consisted of 75% sand, 10% silt, 5.8% clay, 5.2% WTR, and 3.4% bark mulch (air dry mass basis).This media showed excellent P removal relative to a non-WTR-amended media. Whereas the control media leached P (71.1% increase in mass), the experimental media adsorbed 85.7% of the P mass applied, displaying a cumulative effluent EMC of 16.1 μg/L, below the 25 μg/L goal.