Theses and Dissertations from UMD
Permanent URI for this communityhttp://hdl.handle.net/1903/2
New submissions to the thesis/dissertation collections are added automatically as they are received from the Graduate School. Currently, the Graduate School deposits all theses and dissertations from a given semester after the official graduation date. This means that there may be up to a 4 month delay in the appearance of a give thesis/dissertation in DRUM
More information is available at Theses and Dissertations at University of Maryland Libraries.
Browse
2 results
Search Results
Item DESIGN AND PERFORMANCE EXPLORATION OF A SCALED-UP MILLIGRAM-SCALE FLAME CALORIMETER(2024) Cromwell Reed, Kyra; Raffan-Montoya, Fernando; Fire Protection Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Fire causes thousands of lost lives and injuries, as well as billions of dollars of property damage, each year. It is critical to understand the fire hazard associated with materials used in the built environment. One method to evaluate the flammability properties of a material is through bench- scale and milligram-scale testing with apparatus such as the Milligram-Scale Flame Calorimeter (MFC). The MFC has previously been used to test samples ranging from 30 mg – 50 mg in mass. The small samples were useful for testing materials under development or materials cost prohibitive to test at larger sizes, but presented some difficulties in testing, including in sample preparation and as inconsistency in the results of testing on inhomogeneous materials. Furthermore, the small size of the MFC caused difficulty in heater manufacturing, requiring laborious by-hand construction. The size of the MFC crucible and apparatus was increased in this work to allow testing on larger sample masses, ranging in size from 90 mg – 150 mg, and for the exploration of five alternate heater manufacturing techniques. The MFC was rebuilt with a larger heater and optimized to create the best possible test conditions for this work. Tests were conducted on five polymers: polymethyl methacrylate (PMMA), polyethylene (PE), polyvinyl chloride (PVC), and polyether ether ketone (PEEK), and on a wood-based material: oriented strand board (OSB). The tests showed general consistency when materials were tested at different sample masses and sample presentations. The results for the heat release rate and heat of combustion of the materials also aligned well with testing conducted using the previous version of the MFC apparatus. The updates to the MFC conducted in this work constitute an improvement to the versatility of the apparatus, allowing for testing on larger sample masses, but future work is needed to resolve flow and exhaust issues that caused some inconsistency in the test results and to further explore and develop alternate heater manufacturing techniques.Item USE OF MILLIGRAM-SCALE FLAME CALORIMETRY FOR CHARACTERIZING FLAMMABILITY OF FABRIC SAMPLES WITH FLAME RETARDANT TREATMENTS(2023) Roche, Thomas William; Raffan-Montoya, Fernando; Fire Protection Engineering; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)The fire hazard associated with fabrics threatens everyone’s safety, and the current standards used to reduce those hazards are expensive and time-consuming. Fabrics are a key component in clothing, upholstery, and carpentry and are present in nearly every built environment. The inherent flammability of fabrics leads to the application of flame-retardant treatments on nearly all commercial fabric products. Recently, environmental, economic and performance concerns have driven research to develop new flame retardants across a variety of materials. The military industry in particular has focused recent research efforts on flame retardant treatments for fabrics, given the challenging environments that military uniforms must endure. Current methods for testing performance of novel flame retardants, such as the Cone Calorimeter and Microscale Combustion Calorimeter can be prohibitively expensive or only provide a limited understanding of flame-retardant action. Fabrics present additional testing challenges due to their low density and thickness, effectively reducing the amount of fuel available for testing. A novel apparatus, the Milligram-scale Flame Calorimeter (MFC), has been used to test flame retardants in polymeric materials, successfully capturing gas-phase activity and with favorable comparison to Cone Calorimeter results. This study aims to expand the use of the MFC to the testing of fabrics and flame-retardant treated fabrics. Optimization tests were run to find the optimal number of fabric layers and best method for preparing samples for use in MFC. Subsequently, cotton fabrics (untreated and treated with phosphoric acid), as well as Nylon fabrics (untreated and treated with tannic acid) were characterized with MFC, and results were compared to those from the Microscale Combustion Calorimeter and Cone Calorimeter. The MFC showed similar trends in the onset of ignition, peak heat release rate, average heat release rate, char yield, and heat of combustion for the untreated fabrics with the Cone Calorimeter and Microscale Combustion Calorimeter results. The results for the flame-retarded fabrics are inconclusive and require additional testing, though the observations of the condensed-phase and gas-phase activity for the MFC samples does provide important insights on how the mechanism for the flame retardants operate.