Theses and Dissertations from UMD

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New submissions to the thesis/dissertation collections are added automatically as they are received from the Graduate School. Currently, the Graduate School deposits all theses and dissertations from a given semester after the official graduation date. This means that there may be up to a 4 month delay in the appearance of a give thesis/dissertation in DRUM

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Author: search.filters.author.Zhelezinskaia, IadvigaSubject: search.filters.subject.Carbon isotopes

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    A Time-Series Geochemical Study of the ca. 2.5 Ga Batatal Formation in Brazil: Sulfur and Carbon Isotopic Insights into Environmental Conditions before the Great Oxidation Event
    (2013) Zhelezinskaia, Iadviga; Kaufman, Alan J; Farquhar, James; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)
    Neoarchean metasedimentary rocks from the Batatal Formation, Brazil were studied using petrographic, elemental and stable isotopic techniques to provide a better understanding of coupling between the atmosphere-ocean system and biogeochemical cycles prior to the Great Oxidation Event. Multiple sulfur isotope data from both shale and carbonate lithofacies confirms global preservation of mass-independent fractionations, thought to be produced through photochemical reactions in an oxygen-free Neoarchean atmosphere. Isotopic differences between lithofacies within the shallow marine Batatal Formation, and beyond in deeper subtidal environments from correlative successions in Western Australia and South Africa, suggest a strong influence of environmental conditions on the preservation of distinct &Delta33S signatures. To explain the novel isotopic data, it is proposed the Batatal Formation was deposited in a shallow water evaporitic environment, which resulted in higher sulfate concentrations and greater sulfur isotope fractionation associated with the activity of sulfate-reducing bacteria. Higher temperatures associated with such environments may have also promoted carbon dioxide limitation resulting in lesser carbon isotopic fractionation by photoautotrophs.