Cromwell Reed, KyraFire causes thousands of lost lives and injuries, as well as billions of dollars of property damage, each year. It is critical to understand the fire hazard associated with materials used in the built environment. One method to evaluate the flammability properties of a material is through bench- scale and milligram-scale testing with apparatus such as the Milligram-Scale Flame Calorimeter (MFC). The MFC has previously been used to test samples ranging from 30 mg – 50 mg in mass. The small samples were useful for testing materials under development or materials cost prohibitive to test at larger sizes, but presented some difficulties in testing, including in sample preparation and as inconsistency in the results of testing on inhomogeneous materials. Furthermore, the small size of the MFC caused difficulty in heater manufacturing, requiring laborious by-hand construction. The size of the MFC crucible and apparatus was increased in this work to allow testing on larger sample masses, ranging in size from 90 mg – 150 mg, and for the exploration of five alternate heater manufacturing techniques. The MFC was rebuilt with a larger heater and optimized to create the best possible test conditions for this work. Tests were conducted on five polymers: polymethyl methacrylate (PMMA), polyethylene (PE), polyvinyl chloride (PVC), and polyether ether ketone (PEEK), and on a wood-based material: oriented strand board (OSB). The tests showed general consistency when materials were tested at different sample masses and sample presentations. The results for the heat release rate and heat of combustion of the materials also aligned well with testing conducted using the previous version of the MFC apparatus. The updates to the MFC conducted in this work constitute an improvement to the versatility of the apparatus, allowing for testing on larger sample masses, but future work is needed to resolve flow and exhaust issues that caused some inconsistency in the test results and to further explore and develop alternate heater manufacturing techniques.enThesisPolymer chemistryCalorimetryFlammabilityHeat of combustionHeat release ratePyrolysis