The significance of the diurnal variability of Lake Surface Temperature (LST) has been recognized; yet, its magnitude in terms of spatial and temporal variability is not well known. Attempts have been made to derive such information from satellites at a high spatial resolution; however, most have been made from polar orbiting satellites that sample only twice per day. We have developed an approach to derive such information from geostationary satellites at an hourly time scale and at a spatial resolution of about 5 km. The approach to derive LST uses the Radiative Transfer for TIROS Operational Vertical Sounder (TOVS) (RTTOV) model driven by the Modern-Era Retrospective analysis for Research and Applications (MERRA)-2 information. The methodology has been implemented over Lake Huron for about six years. We present the results of the evaluation against various independent satellite products and demonstrate that there is a strong diurnal variability in the skin temperature over the lake and that the lowest and highest values, as derived twice per day from polar orbiting satellites, may not represent the magnitude of the Diurnal Temperature Range (DTR).