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DEGENERATIVE TRANSFER LIVING ZIEGLER-NATTA POLYMERIZATION OF α-OLEFINS
A degenerative transfer (DT) living Ziegler-Natta polymerization system based on the cyclopentadienyl amidinate zirconium complex, (h5-C5Me5)ZrMe2[N(t-Bu)C(Me)N(Et)] (19), has been studied in detail. Compound 19 is an ...
Living Coordinative Chain Transfer Polymerization of 1-Alkenes
A novel polymerization method, living coordinative chain transfer polymerization (CCTP), was recently developed with monocyclopentadienyl monoamidinate (CpAm) Group 4 metal complexes, which were previously applied for the ...
Hypercoordinate Silicon Compounds In Organic Synthesis: Improved Methods For The Synthesis Of Aryl(Trialkoxy)Silane Derivatives; And Trimethylsilyl Cyanide As A Cyanide Source For Nucleophilic Substitution
Palladium-catalyzed cross-coupling reactions are versatile methods for the synthesis of carbon-carbon bonds. The Stille and Suzuki cross-coupling protocols have achieved prominence in the synthesis of pharmaceuticals and ...
The Redox Chemistry of Dirhodium Carboxamidates: From Fundamental Structures to Catalytic Functions.
Redox chemistry is the study of molecular structure and function associated with changes in oxidation state. In this manuscript, the structures and functions of dinuclear rhodium complexes in various oxidation states are ...
NEW LIGAND MOTIFS FOR PLATINUM-BASED `SHILOV CHEMISTRY' AND DETOURS INTO BASIC ORGANOMETALLIC RESEARCH
The C-H activation reaction at cationic platinum centers utilizing chelating aromatic N-type ligands has been widely studied in TFE (trifluoroethanol): a weakly coordinating solvent. In our laboratory, recent studies ...