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DEGENERATIVE TRANSFER LIVING ZIEGLER-NATTA POLYMERIZATION OF α-OLEFINS
(2005-12-04)
A degenerative transfer (DT) living Ziegler-Natta polymerization system based on the cyclopentadienyl amidinate zirconium complex, (h5-C5Me5)ZrMe2[N(t-Bu)C(Me)N(Et)] (19), has been studied in detail. Compound 19 is an ...
TURNIP CRINKLE VIRUS COAT PROTEIN EXPRESSION AND PURIFICATION
(2005-07-29)
Turnip crinkle virus is a (+) sense single strand RNA plant virus consisting of a single copy of the genome surrounded by 180 copies of the 38 kDa coat protein (CP) that comprise the virion capsid. As a structural protein, ...
SOLUTION ISOELECTRIC FOCUSING AND ITS APPLICATION IN COMPARATIVE PROTEOMIC STUDIES OF NUCLEAR PROTEINS
(2005-05-27)
In proteomic research, experimental and computational approaches are combined to provide global analysis of the entire proteomes of cells and tissues. The identification and quantification of multiple proteins, which ...
CAPILLARY ISOELECTRIC FOCUSING-BASED MULTIDIMENSIONAL PEPTIDE/PROTEIN SEPARATIONS FOR PROTEOMICS ANALYSIS
(2005-05-18)
With the completion of the human genome project, the proteomics has become the focus of research interest for better understanding the complex biological processes. The mass spectrometry (MS) detection of vast number and ...
Investigation of Shell Model States in Exotic Odd-A Sb Isotopes
(2005-03-23)
The level structures of 134Sb and 135Sb were studied in the b- decays of the very-neutron-rich 134,135Sn isotopes. Tin isotopes were produced by proton- or neutron-induced fission at CERN/ISOLDE and ionized using a resonance ...
PATH-INTEGRAL MONTE-CARLO SIMULATIONS OF ALUMINUM ATOMS EMBEDDED IN SOLID PARA-HYDROGEN AND IN HELIUM CLUSTERS
(2005-05-27)
In this dissertation we use a path-integral Monte Carlo (PIMC) simulation method to study an open-shell atomic Al impurity doped in two kinds of low temperature condensed media.
We first use the Multilevel Metropolis ...
EMPLOYING A REMOTE CONFORMATIONAL BIAS, INHIBITION OF GAMMA-BUTYROLACTONE FORMATION, AND A SODIUM TEMPLATE TO ENHANCE MACROCYCLIZATION IN CARBENE ADDITION REACTIONS
(2005-09-19)
Ring closure via dirhodium(II) catalyzed diazo decomposition of diazoacetates is an efficient method of asymmetric macrocycle formation, affording up to 28-membered rings without the high dilution requirement of many other ...
ORBITAL-FREE DENSITY FUNCTIONAL THEORY OF ATOMS, MOLECULES, AND SOLIDS
(2005-11-23)
Density functional (DF) theory has proved to be a powerful way to determine the ground state energy of atoms, molecules, and extended systems. An important part of the theory requires one to determine the kinetic energy ...
The Mechanism of Rhenium Fixation in Reducing Sediments
(2005-05-02)
There is a wide range of uses of information related to rhenium's geochemical behavior. Field studies indicate that rhenium is highly enriched in reducing sediments. However the mechanisms by which this high degree of ...
Stretching Biomolecules
(2005-11-23)
Biomolecular self-assembly is the complicated processes characterized by broad and hierarchical structure of energy, length, and time scales.
Various experimental tools have, for decades, been used to understand the ...