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Now showing items 31-40 of 43
NEW LIGAND MOTIFS FOR PLATINUM-BASED `SHILOV CHEMISTRY' AND DETOURS INTO BASIC ORGANOMETALLIC RESEARCH
(2009)
The C-H activation reaction at cationic platinum centers utilizing chelating aromatic N-type ligands has been widely studied in TFE (trifluoroethanol): a weakly coordinating solvent. In our laboratory, recent studies ...
COMPLEX SELF-SORTING SYSTEMS
(2009)
Over the past century scientists have taken a reductionist approach towards much of the physical and biological sciences. More recently scientists have become interested in constructing complex systems from their components ...
USING "SMALL" MOLECULES AS TRANSMEMBRANE ANION TRANSPORTERS
(2009)
Functional, "small" molecule anion transporters have been identified and developed from natural products and synthetic organic compounds. The major discoveries include the design of a transmembrane Cl<super>-</super> ...
EFFORTS TOWARD (+)-7-DEOXYPANCRATISTATIN FEATURING A PALLADIUM CATALYZED ALLYLIC ARYLATION
(2005-01-21)
The synthesis of pancratistatin, 7-deoxypancratistatin, and its analogs have attracted the interest of synthetic chemists due to both their structural complexity as well as interesting biological activity. Although previous ...
Ketyl Radical Recombination Reaction in Various Ionic Liquids
(2009)
Ten ionic liquids were made for a series of experiments meant to help characterize the usefulness of room temperature ionic liquids (RTILs) in various settings. This series of experiments used laser flash photolysis to ...
Theoretical and Experimental Investigations of High Spin Ionic Intermediates
(2007-11-20)
In order to identify high-spin organic intermediates that could potentially be used as building blocks for the construction of high-spin organic ferromagnets, density functional theory (DFT) computations were performed to ...
N-METHYL-4-PICOLINIUM ESTERS AS PHOTOREMOVABLE PROTECTING GROUPS BASED ON PHOTOINDUCED ELECTRON TRANSFER
(2005-05-03)
The goal of this project is to develop an improved photoremovable protecting group (PRPG) for the carboxylate functionality that can be released using high wavelength light through a photoinduced electron transfer (PET) ...
Cucurbit[n]uril Analogues
(2005-11-22)
Molecular recognition and self-assembly in aqueous solution have experienced rapid growth in recent years. The use of alpha-, beta-, and gamma-cyclodextrins, calixarenes, and cyclophanes have served as the platforms for ...
PHOTOLYTIC GENERATION OF NITRENIUM IONS: KINETIC STUDIES AND POLYMERIZATION REACTIONS
(2005-11-29)
Nitrenium ions are highly reactive transient species that contain a positively charged and dicoordinate nitrogen atom. The nitrogen atom contains only six electrons in its valence shell and thus the nitrogen is electron ...
Catechols as Membrane Anion Transporters
(2009)
ABSTRACT
Title of Document: CATECHOLS AS MEMBRANE ANION
TRANSPORTERS
Sofya Berezin, Doctor of Philosophy, 2009
Directed By:
Professor, Jeffery T. Davis,
Department of Chemistry and Biochemistry
...