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Design and Synthesis of New Group (IV) Cyclopentadienyl Amidinate and Guanidinate Initiators for Controlling the Microstructure of Poly(α-olefins) During Living Coordinative Chain Transfer Polymerizations
(2014)
C1-symmetric, cationic group 4 metal (Zr and Hf) mono-methyl complexes, {(η5-C5Me5)M[N(tBu)C(Me)N(Et)](Me)}[B(C6F5)4], are highly active initiators for the living and stereo-selective (isotactic) coordinative ...