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Mechanistic investigations of stoichiometric and catalytic Pt-mediated oxidative functionalization at a proximal boron center
The focus of the work detailed in this dissertation is the investigation of mechanism and catalytic applications of Pt complexes supported by novel anionic di(2-pyridyl)borate ligands. It was found that oxidation of ...
NOVEL PLATINUM COMPLEXES SUPPORTED BY SULFONATED CNN PINCER LIGANDS RELEVANT TO AEROBIC METHANE FUNCTIONALIZATION CHEMISTRY
Mild and selective aerobic methane functionalization has always been a challenge. Shilov developed a PtII based system that has a potential to solve the problem, but the non-practical PtIV oxidant needs to be substituted ...