Now showing items 1-4 of 4
DIRHODIUM CAPROLACTAMATE CATALYZED OXIDATIONS BY TERT-BUTYL HYDROPEROXIDE. FROM MECHANISMS TO NEW METHODOLOGIES
Dirhodium caprolactamate, Rh<sub>2</sub>(cap)<sub>4</sub>, is a very efficient catalyst for the generation of the <italic>tert</italic>-butylperoxy radical from <italic>tert</italic>-butyl hydroperoxide, and the ...
Expanding the Range of Polyolefins through Living Coordinative Chain Transfer Polymerization
The strategy, termed living coordinative chain-transfer polymerization (LCCTP), has been explored to boost the efficiency and versatility of polyolefin synthesis by coupling a reversible chain-transfer process with living ...
Synthesis and Characterization of Bimetallic Zintl Clusters and their Use in the Fabrication of Intermetallic Nanoparticles
In this thesis, the synthesis, characterization and applications of bimetallic Zintl clusters are explored. Zintl ions are polyanions of main group elements, primarily of the heavier elements of groups 14 and 15. The ...
Novel Precision Polyolefins from Living Coordinative Chain-Transfer Polymerization
ABSTRACT Title of Document: Novel Precision Polyolefins from Living Coordinative Chain-Transfer Polymerization Rennisha R. Wickham Doctor of Philosophy, ...