Browsing Chemistry & Biochemistry by Subject "macrocyclization"

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EMPLOYING A REMOTE CONFORMATIONAL BIAS, INHIBITION OF GAMMA-BUTYROLACTONE FORMATION, AND A SODIUM TEMPLATE TO ENHANCE MACROCYCLIZATION IN CARBENE ADDITION REACTIONS

Weathers, Thomas M (2005-09-19)

Ring closure via dirhodium(II) catalyzed diazo decomposition of diazoacetates is an efficient method of asymmetric macrocycle formation, affording up to 28-membered rings without the high dilution requirement of many other ...