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Item 182W and HSE constraints from 2.7 Ga komatiites on the heterogeneous nature of the Archean mantle(Elsevier - Geochimica et Cosmochimica Acta, 2018) Puchtel, Igor S; Blichert-Toft, Janne; Touboul, Mathieu; Walker, Richard J.While the isotopically heterogeneous nature of the terrestrial mantle has long been established, the origin, scale, and longevity of the heterogeneities for different elements and isotopic systems are still debated. Here, we report Nd, Hf, W, and Os isotopic and highly siderophile element (HSE) abundance data for the Boston Creek komatiitic basalt lava flow (BCF) in the 2.7 Ga Abitibi greenstone belt, Canada. This lava flow is characterized by strong depletions in Al and heavy rare earth elements (REE), enrichments in light REE, and initial epsilon143Nd = +2.5 ± 0.2 and initial epsilon176Hf = +4.2 ± 0.9 indicative of derivation from a deep mantle source with time-integrated suprachondritic Sm/Nd and Lu/Hf ratios. The data plot on the terrestrial Nd-Hf array suggesting minimal involvement of early magma ocean processes in the fractionation of lithophile trace elements in the mantle source. This conclusion is supported by a mean mu142Nd = -3.8 ± 2.8 that is unresolvable from terrestrial standards. By contrast, the BCF exhibits a positive 182W anomaly (mu182W = +11.7 ± 4.5), yet is characterized by chondritic initial gamma187Os = +0.1 ± 0.3 and low inferred source HSE abundances (35 ± 5% of those estimated for the present-day Bulk Silicate Earth, BSE). Collectively, these characteristics are unique among Archean komatiite systems studied so far. The deficit in the HSE, coupled with the chondritic Os isotopic composition, but a positive 182W anomaly, are best explained by derivation of the parental BCF magma from a mantle domain characterized by a predominance of HSE-deficient, differentiated late accreted material. According to the model presented here, the mantle domain that gave rise to the BCF received only ~35% of the present-day HSE complement in the BSE before becoming isolated from the rest of the convecting mantle until the time of komatiite emplacement at 2.72 Ga. These new data provide strong evidence for a highly heterogeneous Archean mantle in terms of absolute HSE abundances and W isotopic composition, and also indicate slow mixing, on a timescale of at least 1.8 billion years. Additionally, the data are consistent with a stagnant-lid plate tectonic regime in the Hadean and Archean, prior to the onset of modern-style plate tectonics.Item 182W and HSE constraints from 2.7 Ga komatiites on the heterogeneous nature of the Archen mantle(Elsevier, 2018-03-02) Puchtel, I.S.; Blichert-Toft, J.; Touboul, M.; Walker, Richard J.While the isotopically heterogeneous nature of the terrestrial mantle has long been established, the origin, scale, and longevity of the heterogeneities for different elements and isotopic systems are still debated. Here, we report Nd, Hf, W, and Os isotopic and highly siderophile element (HSE) abundance data for the Boston Creek komatiitic basalt lava flow (BCF) in the 2.7 Ga Abitibi greenstone belt, Canada. This lava flow is characterized by strong depletions in Al and heavy rare earth elements (REE), enrichments in light REE, and initial e143Nd = +2.5 ± 0.2 and initial e176Hf = +4.2 ± 0.9 indicative of derivation from a deep mantle source with time-integrated suprachondritic Sm/Nd and Lu/Hf ratios. The data plot on the terrestrial Nd-Hf array suggesting minimal involvement of early magma ocean processes in the fractionation of lithophile trace elements in the mantle source. This conclusion is supported by a mean mu142Nd = -3.8 ± 2.8 that is unresolvable from terrestrial standards. By contrast, the BCF exhibits a positive 182W anomaly (mu182W = +11.7 ± 4.5), yet is characterized by chondritic initial g187Os = +0.1 ± 0.3 and low inferred source HSE abundances (35 ± 5% of those estimated for the present-day Bulk Silicate Earth, BSE). Collectively, these characteristics are unique among Archean komatiite systems studied so far. The deficit in the HSE, coupled with the chondritic Os isotopic composition, but a positive 182W anomaly, are best explained by derivation of the parental BCF magma from a mantle domain characterized by a predominance of HSE-deficient, differentiated late accreted material. According to the model presented here, the mantle domain that gave rise to the BCF received only ~35% of the present-day HSE complement in the BSE before becoming isolated from the rest of the convecting mantle until the time of komatiite emplacement at 2.72 Ga. These new data provide strong evidence for a highly heterogeneous Archean mantle in terms of absolute HSE abundances and W isotopic composition, and also indicate slow mixing, on a timescale of at least 1.8 billion years. Additionally, the data are consistent with a stagnant-lid plate tectonic regime in the Hadean and Archean, prior to the onset of modern-style plate tectonics.Item A Better Understanding of Atmospheric Methane Sources Using 13CH3D and 12CH2D2 Clumped Isotopes(2024-09) Haghnegahdar, Mojhgan A.We evaluate the use of clumped isotopes of methane (CH4) to fingerprint local atmospheric sources of methane. We focus on a regenerative stormwater conveyance (RSC) stream wetland site running through the University of Maryland campus, which emits methane due to its engineering. Air samples in the RSC were collected at different heights above the surface and at different times of the day including both early in the morning, after methane accumulated below the nocturnal boundary layer, and late in the afternoon when convection mixed air to the cloud layer. Measured Δ12CH2D2 values of air samples record mixing between locally produced methane with low D/H and ambient air. The Δ12CH2D2 of the near surface air collected at the RSC during the early morning ranges from ~+23‰ to ~+35‰ which is lower than the ~+50‰ values of tropospheric air. Mixing between background air (with Δ12CH2D2 ~+50‰) and methane captured from chamber and bubble samples, as well as produced in incubation (all with negative Δ12CH2D2), explains the observed values of Δ12CH2D2 and Δ13CH3D of near surface RSC air samples. The effect of mixing with biogenic sources on Δ13CH3D is much smaller. The findings demonstrate how methane isotopologues can be used as a tool not only to fingerprint local contributions to these greenhouse gas emissions but also to identify sources of near-surface methane hot spots.Item A New Method for Generating the SMOPS Blended Satellite Soil Moisture Data Product without Relying on a Model Climatology(MDPI, 2022-03-31) Yin, Jifu; Zhan, Xiwu; Liu, Jicheng; Ferraro, Ralph R.Soil moisture operational product system (SMOPS) is developed by National Oceanic and Atmospheric Administration (NOAA) to provide the real-time blended soil moisture (SM) for numeric weather prediction and national water model applications. However, all individual satellite SM data ingested into the current operational SMOPS are scaled to global land data assimilation system (GLDAS) 0–10 cm SM climatology before the combination. As a result, the useful information from the original microwave SM retrievals could be lost, and the GLDAS model errors could be brought into the final SMOPS blended product. In this paper, we propose to scale the individual SM retrievals to the soil moisture active passive (SMAP) data through building regression models. The rescaled individual SM data and the SMAP observations then have similar climatology and dynamics, which allows producing the SMOPScdr (distinguishing with the current operational SMOPSopr) data using an equal-weight averaging approach. With respect to the in situ SM measurements, the developed SMOPScdr is more successful tracking the surface SM status than the individual satellite SM products with significantly decreased errors. The proposed method also preserves the climatology of the reference SMAP data for the period when SMAP is not available, allowing us to produce a long-term SMOPScdr data product.Item A Study of Lunar Microwave Radiation Based on Satellite Observations(MDPI, 2020-04-02) Yang, Hu; Burgdorf, MartinIn recent years, the study of microwave radiation from the Moon’s surface has been of interest to the astronomy and remote sensing communities. Due to the stable geophysical properties of the Moon’s surface, microwave lunar radiation is highly predictable and can be accurately modeled, given sufficient observations from reliable instruments. Specifically, for microwave remote sensing study, if International System of Unit (SI) traceable observations of the Moon are available, the Moon can thus be used as an SI traceable calibration reference for microwave instruments to evaluate their calibration accuracies and assess their long-term calibration stabilities. Major challenges of using the Moon as a radiometric source standard for microwave sensors include the uncertainties in antenna pattern measurements, the reliability of measurements of brightness temperature (Tb) in the microwave spectrum of the lunar surface, and knowledge of the lunar phase lag because of penetration depths at different detection frequencies. Most microwave-sounding instruments can collect lunar radiation data from space-view observations during so-called lunar intrusion events that usually occur several days each month. Addressed in this work based on Moon observations from the Advanced Technology Microwave Sounder and the Advanced Microwave Sounding Unit/Microwave Humidity Sounder are two major issues in lunar calibration: the lunar surface microwave Tb spectrum and phase lag. The scientific objective of this study is to present our most recent progress on the study of lunar microwave radiation based on satellite observations. Reported here are the lunar microwave Tb spectrum and phase lag from 23 to 183 GHz based on observations of microwave-sounding instruments onboard different satellite platforms. For current Moon microwave radiation research, this study can help toward better understanding lunar microwave radiation features over a wide spectrum range, laying a solid foundation for future lunar microwave calibration efforts.Item Advection-Diffusion Controlled Lithium Isotopic Distribution in Contact Aureoles: A Case Study from the Florence County Pegmatites, Wisconsin(2009) Liu, Xiaoming; Hier-Majumder, Saswata; Rudnick, Roberta L; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Stable isotopes are useful tracers of fluid-rock interactions in contact aureole settings. To date, only a few case studies have used Li isotopes to study fluid-rock interactions in contact aureole settings. These studies highlight the very large Li isotopic fractionation that can be generated in these settings via diffusion of Li from the pluton into the country rocks, but none of these studies have generated a complete and detailed section of the contact aureole needed to understand the Li distributions. Here, I report the results from a combination of Li isotope analyses and 2-D advection-diffusion modeling for two detailed profiles through country rocks adjacent to Li-rich pegmatite dikes in the Florence County pegmatite field. The results show that the Li concentration and isotopic distribution in the two contact profiles is consistent with fluid infiltration and diffusion of Li through a grain boundary fluid from the pegmatites into their country rocks.Item Age, composition, and origin of the lower continental crust, northern Tanzania(2008) Mansur, Adam T.; Rudnick, Roberta L; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Granulite xenoliths from the East African rift in Tanzania sample the lower continental crust beneath both the stable Tanzanian craton and the adjacent, polymetamorphic Mozambique belt. Protoliths of surface rocks in both terranes formed 2.8 to 2.6 Ga ago, but only the Mozambique belt underwent significant post-Archean metamorphism. Most granulite xenoliths represent mafic magmas formed in a convergent margin at ca. 2660 Ma that were subsequently metamorphosed at lower crustal conditions. However, a small number of xenoliths are more similar to intraplate magmas, suggesting that at least two episodes of lower crustal growth occurred during the Archean. No post-Archean additions to the crust were detected beneath either terrane, but xenoliths from the Mozambique belt record high P-T conditions, suggesting equilibration at the base of orogenically thickened crust. By contrast, xenoliths from beneath the craton equilibrated under conditions typical of unthickened continental crust.Item Age, genetics, and crystallization sequence of the group IIIE iron meteorites(Elsevier, 2023-06-14) Chiappe, Emily M.; Ash, Richard; Walker, Richard J.Chemical and isotopic data were obtained for ten iron meteorites classified as members of the IIIE group. Nine of the IIIE irons exhibit broadly similar bulk siderophile element characteristics. Modeling of highly siderophile element abundances suggests that they can be related to one another through simple crystal-liquid fractionation of a parent melt. Our preferred model suggests initial S, P, and C concentrations of approximately 12 wt%, 0.8 wt %, and 0.08 wt%, respectively. The modeled IIIE parent melt composition is ~4 times more enriched in highly siderophile elements than a non-carbonaceous (NC) chondrite-like parent body, suggesting a core comprising ~22% of the mass of the parent body. Although chemically distinct from the other IIIE irons, formation of the anomalous IIIE iron Aletai can potentially be accounted for under the conditions of this model through the nonequilibrium mixing of an evolved liquid and early formed solid. Cosmic ray exposure-corrected nucleosynthetic Mo, Ru, and W isotopic compositions of four of the bona fide IIIE irons and Aletai indicate that they originated from the non-carbonaceous (NC) isotopic domain. Tungsten-182 isotopic data for the IIIE irons and Aletai yield similar model metal-silicate segregation ages of 1.6 ± 0.8 Myr and 1.2 ± 0.8 Myr, respectively, after calcium aluminum-rich inclusion (CAI) formation. These ages are consistent with those reported for other NC-type iron meteorite parent bodies. The IIIE irons are chemically and isotopically similar to the much larger IIIAB group. Despite some textural, mineralogical, and chemical differences, such as higher C content, the new results suggest they may have originated from a different crystallization sequence on the same or closely-related parent body.Item ANALYZING TIME-VARYING SEISMICITY AND AFTERSHOCK BEHAVIOR IN CENTRAL AND EASTERN UNITED STATES(2021) Pearson, Karen M; Lekic, Vedran; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Central and Eastern United States (CEUS) earthquakes are far less common than those in the tectonically active west coast, but the significance is elevated for a few reasons. Due to older, harder, and often denser rocks making up the bedrock geology east of the Rockies, seismic waves can travel much further without losing energy. Poor construction, efficient transmission of seismic waves, and site amplification effects can make even light to moderate earthquakes pose high risk within the CEUS. The CEUS has significant aging infrastructure and some of the highest population densities in the country, which would lead to great economic losses and even the potential for human injury if hazards are not properly identified and communicated. Aftershock sequences are governed by several descriptive statistical “laws,” each with one or more characteristic parameters. These parameters are used to illustrate factors such as the overall productivity, the rate of decay, and the relative frequency of larger and smaller magnitude aftershocks. Variations in these parameters can relate to the geologic region being studied, the tectonic environment, the driving force of seismicity (i.e. induced earthquakes, volcanic, or geothermal-related), and more. This work discusses the aftershock sequences of two unusual CEUS earthquakes from the past five years. The first earthquake I study is a M4.2 earthquake that occurred east of Dover, DE, in late 2017. I continue by studying the aftershocks in the six weeks following a M5.8 earthquake that occurred near Pawnee, OK, in autumn 2016. Both of these earthquakes experienced below-normal aftershock productivities. I explore the challenges of analysis when station coverage is heterogeneous for the period of aftershock analysis. From there, I discuss the limitations of some statistical tests for special cases such as aftershock decay. The work concludes by highlighting additional CEUS earthquakes exceeding M4 that have occurred in the past 20 years and discussing some preliminary analytical findings.Item Anatexis and crustal differentiation: Insights from the Fosdick migmatite-granite complex, West Antarctica(2014) Yakymchuk, Christopher; Brown, Michael; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)In the Fosdick migmatite-granite complex of West Antarctica, U-Pb geochronology of monazite in migmatites and zircon in granites records two episodes of high-temperature metamorphism, one in the Devonian-Carboniferous and another in the Cretaceous. For the older lower-grade event, whole-rock and zircon isotope geochemistry of granites within the Fosdick complex are interpreted to record crustal reworking during metamorphism associated with continental arc magmatism along the East Gondwana convergent plate margin. By contrast, the geochemistry of correlative granites suites from along and across the same margin indicates a greater proportion of crustal growth. This suggests prominent arc-parallel and arc-normal variations in the mechanisms of crustal reworking versus growth in continental arc systems. Based on garnet Lu-Hf ages, the timing of peak metamorphism in the younger higher-grade event has been determined as c. 116-111 Ma. U-Pb ages of monazite from migmatites and zircon from anatectic granites suggest that exhumation of the complex as a gneiss dome occurred during the interval c. 107-100 Ma. Contemporaneous exhumation of high-grade metamorphic rocks in the Western Province of New Zealand suggests that intracontinental extension preceded the final breakup of New Zealand from West Antarctica by c. 25 Myr. Melt migration through and emplacement within the Fosdick complex during Cretaceous metamorphism was accomplished via a self-organized melt network controlled by the regional stress field and anisotropy of the host rocks. Granites within this network and in sills at shallower crustal levels have microstructures and chemistry consistent with a cumulate origin, and are interpreted to record fractional crystallization during magma ascent and doming related to exhumation. Phase equilibria modeling of open system melting during prograde metamorphism is used to quantify the reduced fertility of source rocks during high-temperature exhumation and later overprinting orogenic events. Quantitative modelling of the dissolution of zircon and monazite during prograde melting demonstrates that accessory minerals are expected to be partially to completely consumed up to the metamorphic peak. New growth of these minerals in migmatite melanosomes is predicted to be limited during cooling, whereas leucosomes and anatectic granites are predicted to contain new zircon and monazite growth.Item Anomalous 33S in the Lunar Mantle(Wiley, 2023-02-02) Dottin, J. W. III; Kim, S.-T.; Wing, B.; Farquhar, J.; Shearer, C.The origin, evolution, and cycling of volatiles on the Moon are established by processes such as the giant moon forming impact, degassing of the lunar magma ocean, degassing during surface eruptions, and lunar surface gardening events. These processes typically induce mass-dependent stable isotope fractionations. Mass-independent fractionation of stable isotopes has yet to be demonstrated during events that release large volumes of gas on the moon and establish transient lunar atmospheres. We present quadruple sulfur isotope compositions of orange and black glass beads from drive tube 74002/1. The sulfur isotope and concentration data collected on the orange and black glasses confirm a role for magmatic sulfur loss during eruption. The Δ33S value of the orange glasses is homogenous (Δ33S = −0.029‰ ± 0.004‰, 2SE) and different from the isotopic composition of lunar basalts (Δ33S = 0.002‰ ± 0.004‰, 2SE). We link the negative Δ33S composition of the orange glasses to an anomalous sulfur source in the lunar mantle. The nature of this anomalous sulfur source remains unknown and is either linked to (a) an impactor that delivered anomalous sulfur after late accretion, (b) sulfur that was photochemically processed early during lunar evolution and was transported to the lunar mantle, or (c) a primitive sulfur component that survived mantle mixing. The examined black glass preserves a mass-dependent Δ33S composition (−0.008‰ ± 0.006‰, 2SE). The orange and black glasses are considered genetically related, but the discrepancy in Δ33S composition among the two samples calls their relationship into question.Item APPLYING GEODESY TO MODEL POSTSEISMIC SLIP OF THE 2016 MW 6.4 MEINONG EARTHQUAKE(2019) Butcher, Rebecca; Huang, Mong-Han; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)In regions of rapid convergence such as southwest Taiwan, unmapped active structures at multiple depths increase the uncertainty of seismic hazard estimates. The 2016 Mw 6.4 MeiNong earthquake occurred below the main Taiwan detachment, and may have illuminated some preexisting, but undocumented, fault structures. In this study, I use geodetic measurements to constrain afterslip on the main fault for 15 months following the MeiNong earthquake. The inverted afterslip is concentrated around the peak coseismic slip asperity without significant aftershock correlation, which implies heterogeneous frictional properties on the fault. Additionally, slip model misfit indicates shallower faults that are critically stressed before the earthquake creep due to the MeiNong coseismic stress. My results can help identify active faults located at shallower depth as well as their seismic potential in southwest Taiwan.Item ASSESSING FAULT SLIP HAZARD IN TAIWAN USING SPACE GEODESY(2022) Robbins, Kathryn Rose; Huang, Mong-Han; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Taiwan is a geologically complex region due to the continuous collision of the Eurasian Plate and the Philippine Sea Plate. This study aimed to quantify the interseismic crustal deformation of Taiwan and detail the island’s seismic hazard potential using space geodesy. Data were collected between 2016 and 2021 through C-band Copernicus Sentinel-1 synthetic aperture radar imagery and continuous GNSS data from Academia Sinica, Taiwan. I excluded major earthquake events within this time period and generated a dataset consisting of interferometric synthetic aperture radar ground motion velocities with GNSS corrections and interpolated GNSS ground motion velocities. Then, utilizing this dataset, I performed a deformation rate analysis and error analysis. Next, I explored block modeling and used a total variation regularization approach to determine the reference block model that best reduced velocity residuals and minimized the number of independently rotating blocks. Results suggested that the Taipei Basin, Ilan Basin, Western Foothills, and Longitudinal Valley were experiencing increased total strain rate accumulation and, therefore, posed increased seismic hazard.Item Assessing the Oxidative History of Miller Range Martian Meteorites(2016) Dottin III, James Wosley; Farquhar, James; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Miller Range (MIL) Martian meteorites are oxidized nakhlites. Early studies attribute their oxidation to reduction-oxidation reactions involving assimilated sulfate. I utilize the sulfur isotope and major element composition of the MIL pairs to assess their oxidative history. MIL sulfides display an average sulfur isotope composition that is different from Nakhla sulfate and sulfide. The sulfur isotope differences produce a mixing array between juvenile sulfur and mass-independent sulfur signatures, indicating assimilation of anomalous sulfur into the melt. I estimate an fO2 of QFM (+3.5 ± 0.4) and a sulfur content of 360 ppm ± 12 – 1300 ppm ± 50. With these results, I test the hypothesis of sulfate assimilation through models of charge balance, isotope mixing, and degassing of sulfur bearing compounds. I conclude that sulfate assimilation was significant in the oxidation of the MIL pairs but, additional oxidants were assimilated.Item Assessment of Himawari-8 AHI Aerosol Optical Depth Over Land(MDPI, 2019-05-09) Zhang, Wenhao; Xu, Hui; Zhang, LiliThis study conducted the first comprehensive assessment of the aerosol optical depth (AOD) product retrieved from the observations by the Advanced Himawari Imager (AHI) onboard the Himawari-8 satellite. The AHI Level 3 AOD (Version 3.0) was evaluated using the collocated Aerosol Robotic Network (AERONET) level 2.0 direct sun AOD measurements over the last three years (May 2016–December 2018) at 58 selected AERONET sites. A comprehensive comparison between AHI and AERONET AOD was carried out, which yielded a correlation coefficient (R) of 0.82, a slope of 0.69, and a root mean square error (RMSE) of 0.16. The results indicate a good agreement between AHI and AERONET AOD, while revealing that the AHI aerosol retrieval algorithm tends to underestimate the atmospheric aerosol load. In addition, the expected uncertainty of AHI Level 3 AOD (Version 3.0) is ± (0.1 + 0.3 × AOD). Furthermore, the performance of the AHI aerosol retrieval algorithm exhibits regional variation. The best performance is reported over East Asia (R 0.86), followed by Southeast Asia (R 0.79) and Australia (R 0.35). The monthly and seasonal comparisons between AHI and AERONET show that the best performance is found in summer (R 0.93), followed by autumn (R 0.84), winter (R 0.82), and spring (R 0.76). The worst performance was observed in March (R 0.75), while the best performance appeared in June (R 0.94). The variation in the annual mean AHI AOD on the scale of hours demonstrates that AHI can perform continuous (no less than ten hours) aerosol monitoring.Item Assessment of the Reprocessed Suomi NPP VIIRS Enterprise Cloud Mask Product(MDPI, 2021-06-26) Lin, Lin; Hao, Xianjun; Zhang, Bin; Zou, Cheng-Zhi; Cao, ChangyongThe Visible Infrared Imaging Radiometer Suite (VIIRS) onboard the Suomi National Polar-orbiting Partnership (S-NPP) satellite continually provides global observations used to retrieve over 20 VIIRS Environmental Data Record (EDR) products. Among them, the cloud mask product is essential for many other VIIRS EDR products such as aerosols, ocean color, and active fire. The reprocessed S-NPP VIIRS Sensor Data Record (SDR) data produced by NOAA/Center for Satellite Applications and Research (STAR) have shown improved stability and consistency. Recently, the VIIRS Enterprise Cloud Mask (ECM) has been reprocessed using the reprocessed VIIRS SDR data. This study assesses the reprocessed ECM product by comparing the reprocessed cloud mask types and cloud probability with those from the operational VIIRS ECM product. It found that the overall differences are small. Most of the discrepancies occur between neighboring types at the cloud edge. These findings help lay the foundation for the user community to understand the reprocessed ECM product. In addition, due to the better quality of the reprocessed VIIRS SDR data that are utilized to generate the reprocessed ECM product, it is expected that the reprocessed ECM product will have better stability and consistency compared to the operational ECM products. Therefore, the reprocessed ECM product is a useful benchmark for the user community.Item Authigenesis, biomineralization, and carbon-sulfur cycling in the Ediacaran ocean(2015) Cui, Huan; Kaufman, Alan J.; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Fossil record of the Ediacaran Period (635-541 Ma) reveals unprecedented rise of early animal life (metazoan) in Earth history. Coupled with this evolutionary milestone, the Earth’s atmosphere and hydrosphere experienced dramatic redox fluctuations. In order to better constrain the redox architecture of the Ediacaran ocean margin, an integrated chemostratigraphic correlation of the Doushantuo Formation in basin scale was conducted (see Chapter 2). The revised redox model suggests that euxinic conditions on the platforms were mainly restricted in lagoonal settings, which helps us to better understand Ediacaran fossil distributions and fluctuated δ13C records in the Ediacaran strata in South China. One of the most distinct features of the Ediacaran chemostratigraphy is the δ13C negative excursion (i.e. Shuram Excursion, or SE) reported globally, which is the largest known C cycle anomaly in Earth history. In order to understand the biogeochemical processes that gave rise to the SE expressed in the upper Doushantuo Formation, systematic petrographic and geochemical investigations were conducted for the outer shelf sections in the Yangtze block (see Chapter 3). Methane-derived authigenic calcite cements and nodules with extreme 13C-depletion were discovered and interpreted as the first empirical evidence of authigenic mineralization associated with the SE. In light of these novel observations, it is proposed that the globally distributed SE may be formed by widespread syndeposition of authigenic carbonates in a sulfate-methane transitional zone positioned at the sediment-water interface in response to a global seawater sulfate increase. Finally, to provide environmental context for the terminal Ediacaran biomineralization of animals, we conducted a high-resolution elemental and isotopic study of the richly fossiliferous Gaojiashan Member (see Chapter 4). Coincident with the first appearance of Cloudina are significant C-S-Ca-Sr cycle anomalies. It is proposed that the onset of calcarious biomineralization of animals may have coincided with an increase in terrestrial weathering fluxes of sulfate, alkalinity, and nutrients to the depositional basin. Enhanced concentration of Ca ion in seawater may have promoted the calcarious biomineralization of the early animals. Integrated chemo-, bio- and litho-stratigraphy of the Doushantuo and Dengying formations presented in this dissertation emphasized intimate co-evolution of Earth-life system during the Ediacaran Period.Item BRITTLE FAULTING IN POROUS, WATER-SATURATED SANDSTONE DEFORMED UNDER HIGH PORE FLUID PRESSURE(2020) Zega, Zachary; Zhu, Wenlu; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)The effective stress law is widely used to model the deformation of crustal rock. It states that effective pressure, the difference between confining pressure and pore fluid pressure, dictates rock strength. In low-porosity rock, previous work has shown that the stability of faulting is controlled by the magnitude of pore fluid pressure rather than the effective pressure. To understand the effect of pore fluid pressure on porous rocks, I deformed water-saturated samples of Darley Dale Sandstone (~13-15% initial porosity) at strain rates from 10-4 to 10-6 s-1 while using a constant effective pressure of 10 MPa and pore fluid pressures ranging from 2 to 180 MPa. The results show that the shear strength is well-predicted by the effective stress law, but fault growth at Pf = 180 MPa resulted in pervasive grain comminution and stabilized fault propagation compared to all other lower pressure experiments.Item Can Managed Aquifer Recharge Overcome Multiple Droughts?(MDPI, 2021-08-20) Zhao, Mengqi; Boll, Jan; Adam, Jennifer C.; Beall King, AllysonFrequent droughts, seasonal precipitation, and growing agricultural water demand in the Yakima River Basin (YRB), located in Washington State, increase the challenges of optimizing water provision for agricultural producers. Increasing water storage through managed aquifer recharge (MAR) can potentially relief water stress from single and multi-year droughts. In this study, we developed an aggregated water resources management tool using a System Dynamics (SD) framework for the YRB and evaluated the MAR implementation strategy and the effectiveness of MAR in alleviating drought impacts on irrigation reliability. The SD model allocates available water resources to meet instream target flows, hydropower demands, and irrigation demand, based on system operation rules, irrigation scheduling, water rights, and MAR adoption. Our findings suggest that the adopted infiltration area for MAR is one of the main factors that determines the amount of water withdrawn and infiltrated to the groundwater system. The implementation time frame is also critical in accumulating MAR entitlements for single-year and multi-year droughts mitigation. In addition, adoption behaviors drive a positive feedback that MAR effectiveness on drought mitigation will encourage more MAR adoptions in the long run. MAR serves as a promising option for water storage management and a long-term strategy for MAR implementation can improve system resilience to unexpected droughts.Item A carbon and nitrogen isotopic analysis of Pleistocene food webs in North America: implications for paleoecology and extinction(2008-05-05) France, Christine Ann Missell; Kaufman, Alan J; Geology; Digital Repository at the University of Maryland; University of Maryland (College Park, Md.)Carbon and nitrogen isotopic reconstructions of North American Pleistocene trophic relationships were used to examine the extinction within terrestrial mammals ~10,000 years ago and distinguish between two potential causal mechanisms - human over-hunting and climate change. Additionally, individual animals were examined for unique isotopic signatures associated with feeding specializations, digestive strategies, and juveniles. Bones representing a comprehensive set of Pleistocene mammalian genera were obtained from three fossil localities: McKittrick Brea, California; Saltville, Virginia; and several sites in Florida. Collagen, a durable bone protein whose carbon and nitrogen isotopic composition reflects dietary input, was extracted from specimens and analyzed for delta-13C, delta-15N, % collagen, %C, %N, and C:N. Radiocarbon dating and amino acid analyses were performed on select sample sets. Results indicated that several specimens contained well preserved collagen, the isotopic values of which indicated both trophic position and vegetation preference. Those samples that contained residual diagenetic proteinaceous material exhibited increased hydrolysis of collagen with time and leaching of disassociated amino acids. Trophic relationships were reconstructed from well preserved specimens for Aucilla River, Florida and the herbivores of Saltville, Virginia, with a less complete reconstruction established for McKittrick Brea, California. The following notable trends emerged: 1) absence of nitrogen isotopic distinction between ruminants and non-ruminants, 2) enriched juvenile nitrogen isotopic signature, 3) distinction of giant ground sloths as omnivores, 4) C4 grass grazers and open C4 grasslands restricted to southern North American latitudes, 5) generalized and opportunistic feeding habits of herbivores, 6) potential prey specializations of carnivores. A noticeable lack of competition and feeding specialists among herbivores suggested a stable base to these late Pleistocene ecosystems, which argues against climatically induced stress on plants. While carnivore specimens were fewer, the apex trophic levels appeared to exhibit a similar lack of competition, which would be expected in a human-driven extinction where carnivores were stressed due to rapidly over-hunted herbivores. The ultimate cause of the late Pleistocene mammalian extinction in North America can not be exclusively attributed to either of these two mechanisms at this point in time; rather, a combination of factors should be considered.