Exoplanets offer unique physical and chemical laboratories experiencing entirely alien environments compared to the Solar System planets. Their atmospheres, governed by the same laws of physics, display remarkable diversity and complexity. They serve as the most complex planetary phenomena we can directly observe, coupled to the planet's interior processes, formation environment, the properties of the host star, and complex chemical ecosystems. The art of modelling these systems is a rich field of study, and in this work I study the nature of photochemical models and what understanding they can provide for us based on the quality and breadth of their inputs. By characterizing the implicit uncertainty chemical models have without a well-characterized host star, I quantify the importance of host star characterization to chemical modelling, showing their sensitivity under different reaction schemes and microphysical models. I then apply this to recent observations of known exoplanet host stars LHS 3844 and AU Microscopii. Finally, I cover work to model sub-Neptune atmospheres across a wide parameter space aimed at understanding the influence of a planet's environment and unknowns on haze formation and observational prevalence in emission and transmission spectroscopy.