To separate and recover multiple signals in data communications, antenna arrays and acoustic sensor arrays, the impulse responses of multiple-input/multiple-output (MIMO) channels have to be identified explicitly or implicitly. This paper deals with the blind identification of MIMO FIR channels based on second-order statistics of the channel outputs. We first investigate the identifiability of MIMO FIR channels, and obtain a necessary and sufficient condition for MIMO FIR channels to be identifiable up to a unitary matrix using second-order statistics. Then, we extend the identification algorithms for single-input/multiple- output (SIMO) FIR channels, such as the algebraic algorithm and the subspace algorithm to the identification of MIMO FIR channels. We also present the application of the above blind identification algorithms to the separation of multiple signals in digital communication systems. Finally, we demonstrate the effectiveness of the algorithms presented in this paper by computer simulations