The purpose of this study was to extend knowledge regarding the predictors and outcomes associated with work-family conflict and work-family enrichment with a sample of employed mothers. Specifically, grounded in the work of Greenhaus and Powell (2006), this study examined the extent to which employed mothers' personality (neuroticism, agreeableness, and conscientiousness), styles of coping, and employer sensitivity were predictive of work-family conflict (work-to-family and family-to-work), and work-family enrichment (work-to-family and family-to-work), and how these constructs related to psychological functioning (i.e., well-being and depression), satisfaction with life/love (i.e., life and relationship satisfaction), and work satisfaction. Participants included 305 employed mothers. We tested the hypothesis that the indirect effects model would be a better fit to the data than the direct and indirect effects model, which was not supported. The direct and indirect effects model, after modifications (correlated uniqueness terms), was a better fit to the data. Directions for future research and the limitations of this study are discussed.